scholarly journals Sulfur-Based Copolymeric Polyamidoamines as Efficient Flame-Retardants for Cotton

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1904 ◽  
Author(s):  
Alessandro Beduini ◽  
Federico Carosio ◽  
Paolo Ferruti ◽  
Elisabetta Ranucci ◽  
Jenny Alongi
Keyword(s):  
Flame Retardant ◽  
Flame Spread ◽  
Flame Retardants ◽  
Radical Scavengers ◽  
C 50 ◽  
Sulfur Containing

The polyamidoamine derived from N,N′-methylenebisacrylamide (M) and glycine (G), M-G, has been shown to be an effective flame-retardant (FR) for cotton in horizontal flame spread tests (HFST), extinguishing the flame at 5% add-on. Its activity was attributed to its intrinsic intumescence. In vertical flame spread tests (VFST), M-G failed to extinguish the flame even at 30% add-on. Conversely, in VFST, the polyamidoamine derived from M and cystine (C), M-C, inhibited cotton combustion at 16% add-on, but in HFST failed to extinguish the flame below 12% add-on. Its activity was ascribed to the release of sulfur-containing volatiles acting as radical scavengers. In this work, the FR effectiveness of M–Gm–Cn copolymers with different G/C ratio was compared with that of the M–G and M–C homopolymers and of M–G/M–C blends of the same compositions. In HFST, both copolymers and blends extinguished the flame. In particular, M–G50–C50 and (M–G/M–C)50/50 extinguished the flame, even at 7% add-on. In VFST, the copolymers with ≥50% M–C units, similar to M–C, inhibited cotton combustion at 16% add-on. At the same add-on, the M–G/M–C blends failed to extinguish the flame. It may be concluded that, in contrast to blends, copolymers combined the merits of both homopolymers in all tests.

scholarly journals Flame Retardancy Enhancement of Jute Fabric Using Chemical Treatment

Tekstilec ◽  
2021 ◽  
Vol 64 (1) ◽  
pp. 70-80
Author(s):  
Md. Reazuddin Repon ◽  
◽  
Nure Alam Siddiquee ◽  
Mohammad Abdul Jalil ◽  
Daiva Mikučionienė ◽  
...  
Keyword(s):  
Weight Gain ◽  
Flame Retardant ◽  
Flame Retardancy ◽  
Flame Spread ◽  
Flame Retardants ◽  
Breaking Load ◽  
Diammonium Phosphate ◽  
Jute Fabric ◽  
Jute Fabrics ◽  
Wash Durability

This work aims to improve the flame retardancy of jute fabric. Raw and bleached plain weave jute fabric was used in this work. Flame retardants borax, diammonium phosphate and thiourea were applied in different concentrations in a raw and bleached jute fabric with the padding method. The influences of flame retardant finishing on the vertical flammability behaviour and tensile properties as well as wash resistance were inves¬tigated. Flame spread time was found to significantly increase when these simple flame retardant finishing agents were used. It was found that the borax-treated raw and bleached specimens exhibited higher flame spread time among all. The assessment of physical properties such as weight gain percentage and breaking load along warp and weft direction of the control and treated fabrics revealed that the increase of flame retardant finishing weight gain caused a decrease in breaking load. Furthermore, the specimens treated with borax and diammonium phosphate flame retardant showed better results than thiourea for flame retardancy and wash durability. These flame retardant jute fabrics have industrial protective textile applications as brattice cloth in mines and many other potential fields of application, e.g. flame retardant kitchen apron, furnishings for public hall, theatre and hospital, etc.

scholarly journals Fire-Safe Polymer Composites: Flame-Retardant Effect of Nanofillers

Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 540
Author(s):  
Yukyung Kim ◽  
Sanghyuck Lee ◽  
Hyeonseok Yoon
Keyword(s):  
Organic Matter ◽  
High Temperature ◽  
Flame Retardant ◽  
Flame Retardants ◽  
Combustion Process ◽  
Polymeric Materials ◽  
Fire Performance ◽  
Gaseous Species ◽  
Advantages And Disadvantages ◽  
Temperature Conditions

Currently, polymers are competing with metals and ceramics to realize various material characteristics, including mechanical and electrical properties. However, most polymers consist of organic matter, making them vulnerable to flames and high-temperature conditions. In addition, the combustion of polymers consisting of different types of organic matter results in various gaseous hazards. Therefore, to minimize the fire damage, there has been a significant demand for developing polymers that are fire resistant or flame retardant. From this viewpoint, it is crucial to design and synthesize thermally stable polymers that are less likely to decompose into combustible gaseous species under high-temperature conditions. Flame retardants can also be introduced to further reinforce the fire performance of polymers. In this review, the combustion process of organic matter, types of flame retardants, and common flammability testing methods are reviewed. Furthermore, the latest research trends in the use of versatile nanofillers to enhance the fire performance of polymeric materials are discussed with an emphasis on their underlying action, advantages, and disadvantages.

Flame Retardant Polyamide 6 Composites Using NMH or NMH/MCA/APP

2011 ◽  
Vol 189-193 ◽  
pp. 1208-1211 ◽  
Author(s):  
Yan Shen ◽  
Shao Guo Wen ◽  
Ji Hu Wang ◽  
Hong Bo Liu ◽  
Hai Liang Qi ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Magnesium Hydroxide ◽  
Flame Retardants ◽  
Polyamide 6 ◽  
X Ray Diffraction ◽  
Upward Trend ◽  
Orthorhombic Crystal ◽  
Orthorhombic Crystal Structure ◽  
Orthogonal Experiments ◽  
Nitrogen Phosphorus

In this paper, flame retardant Polyamide 6 (PA6) composites were prepared by nano-magnesium hydroxide (NMH) or its composites with melamine cyanurate(MCA) and ammonium polyphosphate(APP). Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to analyze the structure of nano-magnesium hydroxide. The properties including tensile properties, molten index (MFI), rockwell hardness and density of flame retardant PA6 were analyzed. Orthogonal experiments were used to study flame retardancy of PA6 with NMH, MCA and APP. The results showed NMH had hexagonal orthorhombic crystal structure with size of 300×200×100nm. Density of polyamide 6 showed an upward trend when the content of NMH was increasing, the mechanical properties and hardness changed little while processing performance serious declined. The flame retardance of nitrogen-phosphorus -inorganic flame retardants was not desirable.

Synthesis and application of a sulfur-containing phosphoric amide flame retardant for nylon fabric

2016 ◽  
Vol 40 (7) ◽  
pp. 959-972 ◽  
Author(s):  
Yingchun Chen ◽  
Bing Sun ◽  
Haixi Zhang ◽  
Xiangdong Zhou
Keyword(s):  
Flame Retardant ◽  
Nylon Fabric ◽  
Sulfur Containing

Surface Addition of Flame Retardants in Acrylic Cast Sheets

1984 ◽  
Vol 2 (1) ◽  
pp. 60-69
Author(s):  
Gaetano Guerra ◽  
Vincenzo Riccio ◽  
Luigi Nicolais
Keyword(s):  
Flame Retardant ◽  
Flame Retardants

A technique for the addition of flame retardants into outer layers of polymeric articles rather than in the whole mass is described. It is pointed out that this technique can be usefully applied in incorporating some flame retardant ad ditives in acrylic cast sheets.

Flame Retardant Epoxy Resins Containing Microcapsules

2011 ◽  
Vol 197-198 ◽  
pp. 1346-1349 ◽  
Author(s):  
Fa Chao Wu
Keyword(s):  
Flame Retardant ◽  
Cone Calorimeter ◽  
Epoxy Resins ◽  
Flame Retardants ◽  
Melamine Resin ◽  
Element Analysis ◽  
Ul 94

Bis(2,6,7-trioxa-l-phosphabicyclo[2.2.2]octane-4-methanol) melaminium salt (Melabis) and microcapsules of Melabis with melamine resin shell as flame retardants (FR), respectively, were synthesized. Their structures were characterized by NMR, IR, SEM, TG and element analysis. 20% weight of microcapsules was doped into epoxy resins (EP) to get 28.5 % of LOI and UL 94 V-0. The heat and smoke release of EP containing microcapsules was valued by cone calorimeter.

Properties of Flame-Retardant Cellulose Fibers Prepared from Cellulose[Amim]Cl Dope Solution

2011 ◽  
Vol 236-238 ◽  
pp. 1152-1155
Author(s):  
Lei Gao ◽  
Bo Wen Cheng ◽  
Jun Song ◽  
Zeng Geng Guo ◽  
Fei Lu ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Flame Retardants ◽  
Simultaneous Thermal Analysis ◽  
Cellulose Fiber ◽  
Cellulose Fibers ◽  
Structure And Properties ◽  
Fiber Structure ◽  
Fiber Degradation ◽  
Dope Solution ◽  
Flame Retardant Properties

This paper has studied the structure and flame-retardant properties of flame-retardant cellulose fiber with DDPSN as flame retardant. The flame retardants was uniformly dispersed in the cellulose /[Amim]Cl Solution to obtain the good spinnable dope, then the dope was wet-spun. Effects of the flame-retardant contention the fiber structure and properties were investigated. The surface of the flame-retardant cellulose fiber was observed using field emission scanning electron microscope (FESEM). Besides, through the Simultaneous thermal analysis, it has been shown that, with the increase of fame retardant, the degree of fame resistance was obviously improved. The flame retardant acted greatly in condensed phase during the fiber degradation and remained mainly in residues after degradation, the experiments show that the flame-retardant properties of flame-retardant cellulose fiber with 20wt% DDPSN was obvious.

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