scholarly journals A Study of the Thermal Degradation and Combustion Characteristics of Some Materials Commonly Used in the Construction Sector

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1833 ◽  
Author(s):  
Javier Arturo Piedrahita Solorzano ◽  
Khalid Abu Mohammad Moinuddin ◽  
Svetlana Tretsiakova-McNally ◽  
Paul Joseph
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Inner Core ◽  
Thermo Gravimetric Analysis ◽  
Gravimetric Analysis ◽  
Combustion Heat ◽  
Internal Core ◽  
Combustion Flow

In the present work, some materials that are commonly used in the construction industry were studied with regard to their thermal degradation characteristics and combustion attributes. These included façade materials for pre-fabricated houses, such as the layers of cross-laminated timber (CLT) and the inner core of aluminium composite panels (ACPs). The relevant investigations were carried out by employing thermo-gravimetric analysis (TGA) and pyrolysis combustion flow calorimetry (PCFC). The Arrhenius parameters and the associated calorimetric quantities, i.e., heat release rates, temperature to the peak heat release rate, heats of combustion, heat release capacities, and char yields, were also evaluated. These parameters showed that CLT is more fire retarded than the polymeric internal core of ACP façade materials. Furthermore, some valuable correlations among the various test quantities were found. For instance, a good correlation exists between the general profiles of the thermograms obtained through TGA runs and the heat release rate (HRR) traces from PCFC measurements. Depending on the nature of the materials, the char yields measured by PCFC can be 4–20 times higher than the ones obtained through TGA.

scholarly journals Flame-Retardant and Thermal Degradation Mechanism of Caged Phosphate Charring Agent with Melamine Pyrophosphate for Polypropylene

2015 ◽  
Vol 2015 ◽  
pp. 1-11 ◽  
Author(s):  
Xuejun Lai ◽  
Jiedong Qiu ◽  
Hongqiang Li ◽  
Xingrong Zeng ◽  
Shuang Tang ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Flame Retardant ◽  
Heat Release Rate ◽  
Release Rate ◽  
Degradation Mechanism ◽  
Limiting Oxygen Index ◽  
Thermal Degradation Mechanism ◽  
Charring Agent ◽  
Ul 94

An efficient caged phosphate charring agent named PEPA was synthesized and combined with melamine pyrophosphate (MPP) to flame-retard polypropylene (PP). The effects of MPP/PEPA on the flame retardancy and thermal degradation of PP were investigated by limiting oxygen index (LOI), vertical burning test (UL-94), cone calorimetric test (CCT), and thermogravimetric analysis (TGA). It was found that PEPA showed an outstanding synergistic effect with MPP in flame retardant PP. When the content of PEPA was 13.3 wt% and MPP was 6.7 wt%, the LOI value of the flame retardant PP was 33.0% and the UL-94 test was classed as a V-0 rating. Meanwhile, the peak heat release rate (PHRR), average heat release rate (AV-HRR), and average mass loss rate (AV-MLR) of the mixture were significantly reduced. The flame-retardant and thermal degradation mechanism of MPP/PEPA was investigated by TGA, Fourier transform infrared spectroscopy (FTIR), TG-FTIR, and scanning electron microscopy-energy dispersive X-ray spectrometry (SEM-EDXS). It revealed that MPP/PEPA could generate the triazine oligomer and phosphorus-containing compound radicals which changed the thermal degradation behavior of PP. Meanwhile, a compact and thermostable intumescent char was formed and covered on the matrix surface to prevent PP from degrading and burning.

The influence of various/different ratios synthetic fiber mixture on the mechanical, thermal, morphological and flammability properties of poly (lactic acid)/polycarbonate blend

2020 ◽  
pp. 002199832096353
Author(s):  
Seda Hazer ◽  
Ayse Aytac
Keyword(s):  
Lactic Acid ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Control Sample ◽  
Synthetic Fiber ◽  
Poly Lactic Acid ◽  
Gravimetric Analysis ◽  
Scanning Calorimetry ◽  
Limiting Oxygen Index

Poly (Lactic Acid) (PLA)/Polycarbonate (PC) blend has gained much attention as a bio-based polymeric material in various industrial fields. This study aims to improve the properties of PLA/PC blend reinforced with glass fiber (GF) and carbon fiber (CF) mixture to be produced for industrial use. For this purpose, 50PLA/50PC blend was prepared and used as a control sample. Then, 30% by weight CF and 30% GF were added to the matrix separately. To examine the effect of the use of CF and GF together, the composites were prepared as a mixture form of fibers by adding 5-10-15% CF and 5-10-15% GF, respectively, to the control blend in pairs. All composites compounded with the laboratory-scale twin-screw mini extruder and molded by injection molding. The effects of using synthetic fiber mixture were evaluated in terms of the mechanical, thermal and flammability properties. Differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), tensile test, scanning electron microscopy (SEM), limiting oxygen index (LOI), heat release rate (HRR) test were carried for the characterization of composites. The highest tensile strength values ​​and maximum % crystallinity values were obtained for the 15CF/15GF fiber mixture containing PLA/PC composite as 113.7 MPa and 21.4, respectively. CO yield (COY), HRR, and total heat release rate were reduced significantly by using synthetic fibers and fiber mixture.

scholarly journals Non-Chloride in Situ Preparation of Nano-Cuprous Oxide and Its Effect on Heat Resistance and Combustion Properties of Calcium Alginate

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1760 ◽  
Author(s):  
Peiyuan Shao ◽  
Peng Xu ◽  
Lei Zhang ◽  
Yun Xue ◽  
Xihui Zhao ◽  
...  
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Hybrid Materials ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cuprous Oxide ◽  
Calcium Alginate ◽  
Combustion Process ◽  
Protective Layer ◽  
Combustion Properties

With Cu2+ complexes as precursors, nano-cuprous oxide was prepared on a sodium alginate template excluded of Cl− and based on which the calcium alginate/nano-cuprous oxide hybrid materials were prepared by a Ca2+ crosslinking and freeze-drying process. The thermal degradation and combustion behavior of the materials were studied by related characterization techniques using pure calcium alginate as a comparison. The results show that the weight loss rate, heat release rate, peak heat release rate, total heat release rate and specific extinction area of the hybrid materials were remarkably lower than pure calcium alginate, and the flame-retardant performance was significantly improved. The experimental data indicates that nano-cuprous oxide formed a dense protective layer of copper oxide, calcium carbonate and carbon by lowering the initial degradation temperature of the polysaccharide chain during thermal degradation and catalytically dehydrating to char in the combustion process, and thereby can isolate combustible gases, increase carbon residual rates, and notably reduce heat release and smoke evacuation.

scholarly journals Research on Combustion Heat Release Rate Testing Technology Based on TDLAS

2016 ◽  
Vol 135 ◽  
pp. 107-111 ◽  
Author(s):  
Jian-yong Liu ◽  
Xia Zhao ◽  
Shi-jie Gao ◽  
Xiao-qian Ma
Keyword(s):  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Combustion Heat ◽  
Rate Testing ◽  
Testing Technology

scholarly journals Diesel Engine Dynamics Modeling Considering Fuel Injection Period Based on Combustion Heat Release Rate Identification

2013 ◽  
Vol 8 (1) ◽  
pp. 58-73
Author(s):  
Khin Hnin Thu ZAR ◽  
Naoki UCHIYAMA ◽  
Taro UNNO ◽  
Shigenori SANO ◽  
Susumu NODA ◽  
...  
Keyword(s):  
Diesel Engine ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Fuel Injection ◽  
Dynamics Modeling ◽  
Combustion Heat ◽  
Injection Period

scholarly journals Effect of Magnesium Hydroxide and Aluminum Hydroxide on the Thermal Stability, Latent Heat and Flammability Properties of Paraffin/HDPE Phase Change Blends

Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 180 ◽  
Author(s):  
Ru Zhou ◽  
Zhuang Ming ◽  
Jiapeng He ◽  
Yanming Ding ◽  
Juncheng Jiang
Keyword(s):  
Thermal Stability ◽  
Phase Change ◽  
Heat Release ◽  
Flame Retardant ◽  
Latent Heat ◽  
Aluminum Hydroxide ◽  
Heat Release Rate ◽  
Magnesium Hydroxide ◽  
Release Rate ◽  
Gravimetric Analysis

In this study, paraffin was selected as the phase change material (PCM) and high-density polyethylene (HDPE) as the supporting material to prepare a flame-retardant PCM system. The system consisted of paraffin, HDPE, expanded graphite (EG), magnesium hydroxide (MH) and aluminum hydroxide (ATH). The thermal stability and flame retardancy were studied by thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM) and cone calorimeter test (CONE). The SEM proved that the addition of MH and ATH can produce an oxide film on the surface of the composite material and form a “physical barrier” with the char layer, generated by the expansion of EG, preventing the transfer of heat and oxygen. The TGA test showed that, compared with other flame-retardant systems, the materials with added MH and ATH have a higher thermal stability and carbonization ability, and the amount of char residue has increased from 17.6% to 32.9%, which reduces the fire risk of the material. The flame retardant effect is obvious. In addition, the addition of MH and ATH has no significant effect on the phase transition temperature and latent heat value of PCMs. The CONE data further confirmed that MH and ATH can work with EG to prevent heat release, reduce the total heat release rate (THR) value and effectively suppress the generation of smoke, CO and CO2. The peak heat release rate (PHRR) value also decreased, from 1570.2 kW/m2 to 655.9 kW/m2.

Fire performance properties of commonly used South African hardwood

2020 ◽  
Vol 38 (5) ◽  
pp. 415-432
Author(s):  
Tebogo Maake ◽  
Joseph Asante ◽  
Bonex Mwakikunga
Keyword(s):  
Heat Release ◽  
South African ◽  
Thermal Performance ◽  
Heat Release Rate ◽  
Release Rate ◽  
Thermal Response ◽  
Growth Index ◽  
Gravimetric Analysis ◽  
Fire Hazards ◽  
Response Parameter

The effect of fire or heat and the associated fire hazards of South African hardwoods had been minimally researched. Quantitative investigations on fire performances of selected and common South African hardwood species that include Leadwood ( Combretum imberbe), Mopani ( Colophospermum mopane), Tamboti ( Spirostachys Africana), Stinkwood ( ocotea bullata), and Real Yellowwood ( Podocarpus latifolius) were undertaken using the cone calorimeter and the thermal gravimetric analysis instrument. The results indicated that Leadwood has the superior thermal performance. It has the lowest peak heat release rate (first peak at 156 kW/m2) at external heat irradiation flux of 75 kW/m2, highest thermal response parameter (376.2 kW s1/2/m2), highest thermal inertial (11.5 kW2 s/K2 m4), highest [Formula: see text], lowest fire growth index (derived from first heat release rate peak at 3120 W/s) and lowest smoke growth index (derived from first smoke production rate peaks at 0.760 m2/s2), and lowest smoke release (toxicity) 446.5 kg/kg. Bad thermal performance wood species are Mopani and Real Yellowwood. Stinkwood on the other hand has the best thermal stability from activation energy measurements.

scholarly journals Cone calorimetric fire properties and thermal analysis of polyester-banana peduncle fibre composite fused with bio-fire retardant additive

2021 ◽  
Vol 45 (1) ◽  
Author(s):  
Ernest Mbamalu Ezeh
Keyword(s):  
Thermal Degradation ◽  
Heat Release ◽  
Heat Release Rate ◽  
Release Rate ◽  
Cone Calorimeter ◽  
Research Work ◽  
Fire Retardant ◽  
Total Heat ◽  
Total Heat Release ◽  
Reinforcement Material

Abstract Background Lately, thermoplastic and thermoset polymers are integrated with natural fillers to harvest composites. Due to an excellent property profile, these composites find wide applications in engineering fields. This research work aimed to investigate the parameters that influence the thermal degradation of Polyester-Banana peduncle fibre-reinforced composite incorporated with cow horn ash particle (CHAp) as a fire retardant additive and optimize the total heat produced for the smaller the better. The major instruments used in this study were cone calorimeter and the thermogravimetric analyser. Result The parameters considered were time, reinforcement type, and weight per cent of reinforcement material. The composites were made by varying the ratios of CHAp and BPF in the polyester matrix from 0:0, 2.5:2.5, 5:5 and 7.5:7.5 and 10:10 weight per cent. The flammability properties of the developed composites were examined, using a cone calorimeter. The controlling parameters were analysed using the Taguchi robust design method. The ANOVA showed that time had the greatest influence on the total heat release rate (81.72%). The weight per cent reinforcement type (10.37%) and reinforcement type (5.28%) had smaller influences on the heat release rate. The S/N ratio obtained, using optimal testing shows that time had the greatest influence on the total heat release rate, followed by weight per cent of reinforcement type, while reinforcement type had the least influence. The corresponding multiple regression models for total heat released revealed that the total heat release rate increased with an increase in time and reinforcement type and decreased with an increase in weight per cent of the fire retardant additive material. Conclusion This work indicated that the parameter design of the Taguchi method provided an efficient methodology for the analyses of the effects of thermal degradation parameters of composites. The controlling parameters of time, the weight of reinforcement material and the type of reinforcement material had significant contributions to the value of heat production during composites thermal decomposition. Time had the greatest contribution, followed by the weight of reinforcement type, and type of reinforcement material.

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