scholarly journals Feasibility Study of Applying Modified Nano-SiO2 Hyperbranched Copolymers for Enhanced Oil Recovery in Low-Mid Permeability Reservoirs

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1483 ◽  
Author(s):  
Nanjun Lai ◽  
Lei Tang ◽  
Na Jia ◽  
Dongyu Qiao ◽  
Jianlin Chen ◽  
...  

To improve oil recovery significantly in low-mid permeability reservoirs, a novel modified nano-SiO2 hyperbranched copolymer (HPBS), consisting of polyacrylamide as hydrophilic branched chains and modified nano-SiO2 as the core, was synthesized via an in situ free radical polymerization reaction. The structure and properties of the hyperbranched copolymer were characterized through a range of experiments, which showed that HBPS copolymers have better stability and enhanced oil recovery (EOR) capacity and also smaller hydrodynamic radius in comparison with hydrolyzed polyacrylamide (HPAM). The flooding experiments indicated that when a 1000 mg/L HPBS solution was injected, the resistance factor (RF) and residual resistance factor (RRF) increased after the injection. Following a 98% water cut after preliminary water flooding, 0.3 pore volume (PV) and 1000 mg/L HPBS solution flooding and extended water flooding (EWF) can further increase the oil recovery by 18.74% in comparison with 8.12% oil recovery when using HPAM. In this study, one can recognize that polymer flooding would be applicable in low-mid permeability reservoirs.

Energies ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 562 ◽  
Author(s):  
Shuang Liang ◽  
Yikun Liu ◽  
Shaoquan Hu ◽  
Anqi Shen ◽  
Qiannan Yu ◽  
...  

With the rapid growth of energy consumption, enhanced oil recovery (EOR) methods are continually emerging, the most effective and widely used was polymer flooding. However, the shortcomings were gradually exposed. A novel decorated polyacrylamide might be a better alternative than polymer. In this work, the molecular structure and the properties reflecting the viscosity of decorated polyacrylamide, interfacial tension, and emulsification were examined. In order to better understand the interactions between decorated polyacrylamide and oil as well as the displacement mechanism, the displacement experiment were conducted in the etched-glass microscale model. Moreover, the coreflooding comparison experiments between decorated polyacrylamide and polymer were performed to investigate the displacement effect. The statistical analysis showed that the decorated polyacrylamide has excellent characteristics of salt tolerance, viscosity stability, and viscosification like polymer. Besides, the ability to reduce the interfacial tension in order 10−1 and emulsification, which were more similar to surfactant. Therefore, the decorated polyacrylamide was a multifunctional polymer. The displacement process captured by camera illustrated that the decorated polyacrylamide flooded oil mainly by means of ‘pull and drag’, ‘entrainment’, and ‘bridging’, based on the mechanism of viscosifying, emulsifying, and viscoelasticity. The results of the coreflooding experiment indicated that the recovery of decorated polyacrylamide can be improved by approximately 11–16% after water flooding when the concentration was more than 800 mg/L, which was higher than that of conventional polymer flooding. It should be mentioned that a new injection mode of ‘concentration reduction multi-slug’ was first proposed, and it obtained an exciting result of increasing oil production and decreasing water-cut, the effect of conformance control was more significant.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Xiaoyan Wang ◽  
Jie Zhang ◽  
Guangyu Yuan ◽  
Wei Wang ◽  
Yanbin Liang ◽  
...  

Surfactant polymer (SP) flooding has become an important enhanced oil recovery (EOR) technique for the high-water cut mature oilfield. Emulsification in the SP flooding process is regarded as a powerful mark for the successful application of SP flooding in the filed scale. People believe emulsification plays a positive role in EOR. This paper uses one-dimensional homogenous core flooding experiments and parallel core flooding experiments to examine the effect of emulsification on the oil recoveries in the SP flooding process. 0.3 pore volume (PV) of emulsions which are prepared using ultralow interface intension (IFT) SP solution and crude oil with stirring method was injected into core models to mimic the emulsification process in SP flooding, followed by 0.35 PV of SP flooding to flood emulsions and remaining oil. The other experiment was preformed 0.65 PV of SP flooding as a contrast. We found SP flooding can obviously enhance oil recovery factor by 25% after water flooding in both homogeneous and heterogeneous cores. Compared to SP flooding, emulsification can contribute an additional recovery factor of 3.8% in parallel core flooding experiments. But there is no difference on recoveries in homogenous core flooding experiments. It indicates that the role of emulsification during SP flooding will be more significant for oil recoveries in a heterogeneous reservoir rather than a homogeneous reservoir.


Author(s):  
Kewen Li ◽  
Changhui Cheng ◽  
Changwei Liu ◽  
Lin Jia

Polymer flooding, as one of the Enhanced Oil Recovery (EOR) methods, has been adopted in many oilfields in China and some other countries. Over 50% oil remains undeveloped in many oil reservoirs after polymer flooding. It has been a great challenge to find approaches to further enhancing oil recovery when polymer flooding is over. In this study, a new method was proposed to increase oil production using gas flooding with wettability alteration to gas wetness when polymer flooding has been completed. The rock wettability was altered from liquid- to gas-wetness during gas flooding. An artificial oil reservoir was constructed and many numerical simulations have been conducted to test the effect of wettability alteration on the oil recovery in reservoirs developed by water flooding and followed by polymer flooding. Production data from different scenarios, water flooding, polymer flooding after water flooding, gas flooding with and without wettability alteration after polymer flooding, were calculated using numerical simulation. The results demonstrate that the wettability alteration to gas wetness after polymer flooding can significantly enhance oil recovery and reduce water cut effectively. Also studied were the combined effects of wettability alteration and reservoir permeability on oil recovery.


2021 ◽  
pp. 79-90
Author(s):  
Т. A. Pospelova

The article discusses ways to increase the oil recovery factor in already developed fields, special attention is paid to the methods of enhanced oil recovery. The comparative structure of oil production in Russia in the medium term is given. The experience of oil and gas companies in the application of enhanced oil recovery in the fields is analyzed and the dynamics of the growth in the use of various enhanced oil recovery in Russia is estimated. With an increase in the number of operations in the fields, the requirements for the selection of candidates inevitably increase, therefore, the work focuses on hydrodynamic modeling of physical and chemical modeling, highlights the features and disadvantages of existing simulators. The main dependences for adequate modeling during polymer flooding are given. The calculation with different concentration of polymer solution is presented, which significantly affects the water cut and further reduction of operating costs for the preparation of the produced fluid. The possibility of creating a specialized hydrodynamic simulator for low-volume chemical enhanced oil recovery is considered, since mainly simulators are applicable for chemical waterflooding and the impact is on the formation as a whole.


2021 ◽  
Vol 874 ◽  
pp. 45-49
Author(s):  
Ihsan Arifin ◽  
Grandprix Thomryes Marth Kadja ◽  
Cynthia L. Radiman

Enhanced Oil Recovery (EOR) is a promising technology for increasing crude oil production, especially from old wells. Polymer flooding is one of the techniques used in EOR in which the water-soluble polymer is added to increase the viscosity of the injected fluid. However, this technique has not been implemented in Indonesia due to the unavailability of locally-synthesized polymers. Therefore, this research aims to synthesize polyacrylamides and their partially-hydrolyzed derivatives and to study the possibility of their utilization for the EOR application. Various polymerization conditions using potassium persulfate (KPS) as initiators have been realized and the resulting polymers were characterized using FTIR spectroscopy and rheology measurement. It was found that higher monomer concentration resulted in higher viscosity-average molecular weight of polyacrylamide. Further study revealed that the hydrolysis of polyacrylamide by alkaline solution significantly increased the viscosity of 1000 ppm solution from 1.5 to 145.40 cP at room temperature, which is comparable to one of the commercial products. These results showed that the simple synthesis and hydrolysis method could be effectively used to produce water-soluble polymers for the EOR application.


2021 ◽  
Author(s):  
Effiong Essien ◽  
Uchenna Onyejiaka ◽  
Stanley Onwukwe ◽  
Nnaemeka Uwaezuoke

Abstract Poor formation permeability and near well bore damage may limit water injectivity into the reservoir in a water injection project. This paper seeks to evaluate the effect of radial drilling technique on water injectivity and oil recovery in water flooding operation. Radial drilling technology utilizes hydraulic energy to create lateral perpendicular small holes through the casing into the reservoir. The holes may extend to 100 m (330 ft) into the reservoir to access fresh formations beyond the near wellbore, and damage zone. A black oil simulator (Eclipse 100) was used to modeling a lateral radial drill from the borehole into the reservoir, and that of a conventional perforation of the wellbore respectively. A simulation study was carried out using various presumed radial drill configurations in determining injectivity index, displacement efficiencies, recovery factor and water cut of the process. The determined results were further compared with that of the conventional perforation process case respectively. The results show a significant improvement in water injectivity in radial drill case with the increasing length and number of radials as compared to the conventional wellbore perforation case. The determined Recovery factor shows a progressive increase with increase in the numbers of radials drilled, irrespective of the radial length. However, it was observed that, the more the number and length of the radials drilled in to the reservoir, the higher the water cut from producer wells. Radial Drilling Technology, therefore, has a promising potential to improving water injectivity into the reservoir and thereby optimizing oil recovery in a water flooding operation.


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