scholarly journals Dynamic Self-Assembly of Polyelectrolyte Composite Nanomaterial Film

Polymers ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 1258
Author(s):  
Qiupeng Hou ◽  
Xiwen Wang ◽  
Arthur J. Ragauskas
Keyword(s):  
Silver Nanoparticles ◽  
Self Assembly ◽  
Composite Films ◽  
Nanofibrillated Cellulose ◽  
Multilayer Films ◽  
Layer By Layer ◽  
Composite Nanomaterial ◽  
Polyallylamine Hydrochloride ◽  
Alignment Structure ◽  
Degradation Properties

The aim of this study is not only to investigate the feasibility of using PAH (polyallylamine hydrochloride) and PSS (poly styrene-4-sulfonic acid sodium salt) to prepare a film via a layer by layer self-assembly process entrained with silver nanoparticles, but also to show that the silver nanoparticles crystalline structure can be defined and deposited on the surface of the substrate in the desired alignment structure and manner, which is of great help to research on the LBL method in the cellulose field. The effect of outermost layer variation, assembly layers, and composition of multilayers on the formation of the LBL structure on a nanofibrillated cellulose (NFC)/polyvinyl alcohol (PVA) substrate was investigated. The deposition of PAH and PSS was monitored by Fourier-transform infrared spectroscopy (FT-IR). The morphology of the LBL film layers was observed by scanning electron microscope (SEM) and atomic force microscope (AFM). Furthermore, thermal degradation properties were investigated by thermogravimetric analysis (TGA), and physical properties of multilayer films were tested by a universal mechanical tester. The results reveal that PAH and PSS can be readily deposited on a NFC/PVA substrate by using LBL methodology to prepare self-assembled polyelectrolyte multilayer films. The surface morphology of the LBL composite changed from negative to positive charged depending on the final LBL treatment. Also, according to SEM and AFM analysis, silver nanoparticles were well dispersed in the (PAH/PSS) film, which significantly improved the thermal stability of the composite films.

Preparation of the Layer-by-Layer Deposited Silver Nanoparticles Multilayer Films on Poly(ethylene Terephalate) Substrate

2011 ◽  
Vol 189-193 ◽  
pp. 1362-1365
Author(s):  
De Shan Cheng ◽  
Xiao Yan Liu ◽  
Ji Hong Wu ◽  
Wei Dong Yu
Keyword(s):  
Silver Nanoparticles ◽  
Self Assembly ◽  
Inductively Coupled Plasma ◽  
Multilayer Films ◽  
Layer By Layer ◽  
Inductively Coupled ◽  
Assembly Technology ◽  
Poly Ethylene ◽  
Pet Film ◽  
Pet Substrate

This research presented the preparation of multilayer films on poly(ethylene terephalate) (PET) Substrate by electrostatic self-assembly technology. The silver nanoparticles were characterized by UV–vis spectrometry and scanning electron microscopy (SEM). The sequential dipping of hydrolyzed PET substrate in dilute solutions of poly(diallyldimethyl ammonium chloride)(PDDA) and silver nanoparticles to fabricate multilayer films. The multilayer films were monitored by UV–vis spectrometry, the surface plasmon resonance (SPR) obtained at 420 nm confirmed the existence of nanosilver on the PET film. The silver nanoparticles were also verified by the Inductively Coupled Plasma Spectrometry (ICP) and thermogravimetric analysis of the multilayer film. The transmission spectra indicated that the PET films contained silver nanoparticles have better UV protection property.

Layer-by-layer self-assembly of multilayer films based on humic acid

2011 ◽  
Vol 519 (13) ◽  
pp. 4324-4328 ◽  
Author(s):  
Zhengxia Xu ◽  
Chenyang Hu ◽  
Hu Guoxin
Keyword(s):  
Humic Acid ◽  
Self Assembly ◽  
Multilayer Films ◽  
Layer By Layer

Preparation of CPC-Fe3O4-MMT/PEG Magnetic Films via Layer-by-Layer Assembly under the Assistance of Magnetic Field

2016 ◽  
Vol 852 ◽  
pp. 1034-1038
Author(s):  
Li Nan Xu ◽  
Shu Chen Tu ◽  
Feng Zhu Lv ◽  
Qi An ◽  
Yi He Zhang
Keyword(s):  
Magnetic Field ◽  
Self Assembly ◽  
Present Method ◽  
Multilayer Film ◽  
Composite Films ◽  
Deposition Efficiency ◽  
Magnetic Films ◽  
Layer By Layer ◽  
Film Fabrication ◽  
Layer Assembly

Polyethylene glycol (PEG), which was not a traditional building block of layer by layer (LBL) self-assembly, was used to fabricate multilayer films by the combination of LBL and magnetic field induction. The UV-abs absorbance of the composite films increases linearly with the number of bilayers, indicating uniform fabrication of each layer. By this method, the multilayers can consist of up to 15 bilayers. The applied magnetic field not only enhances the compactness of the CPC-Fe3O4-MMT, but also improves the deposition efficiency of the films. The present method can be an effective method for multilayer film fabrication from non polyelectrolyte.

Construction of multilayer films with bactericidal and long-term antitumor drug release properties as a non-vascular stent coating for therapy in obstruction

2019 ◽  
Vol 7 (32) ◽  
pp. 4963-4972 ◽  
Author(s):  
Xiao-yan Xu ◽  
Yan-fang Chen ◽  
Qing-gang Tan ◽  
Zhi-jie Chen ◽  
Yan Li ◽  
...  
Keyword(s):  
Drug Release ◽  
Self Assembly ◽  
Multilayer Films ◽  
Antitumor Drug ◽  
Layer By Layer ◽  
Vascular Stent ◽  
Assembly Method ◽  
Stent Coating

An antibacterial and antitumor coating for non-vascular stent was constructed via the layer-by-layer electrostatic self-assembly method.

scholarly journals Fabrication and Characterization of Antibacterial-active Multilayer Films Based on Keggin Polyoxometalates and Methylene Blue

2010 ◽  
Vol 65 (2) ◽  
pp. 140-146 ◽  
Author(s):  
Dan Chen ◽  
Jun Peng ◽  
Haijun Pang ◽  
Pengpeng Zhang ◽  
Yuan Chen ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Self Assembly ◽  
Multilayer Films ◽  
Photoelectron Spectra ◽  
Layer By Layer ◽  
Force Microscopy ◽  
Atomic Force ◽  
Assembly Technique ◽  
Lbl Films ◽  
Cv Measurements

Two kinds of multilayer films based on Keggin polyoxometalates α-[SiW12O40]4−/α- [PMo12O40]3− and methylene blue have been prepared via the layer-by-layer (LBL) self-assembly technique. The multilayer films were characterized by UV/Vis spectra, atomic force microscopy (AFM) and X-ray photoelectron spectra (XPS). The cyclic voltammetry (CV) measurements have demonstrated that the electrochemical properties of POMs are maintained in the LBL films. The antibacterial activity of the LBL films has also been investigated, which shows a distinct antibacterial effect against Escherichia coli.

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