scholarly journals Formation Features of Hybrid Nanocomposites Based on Polydiphenylamine-2-Carboxylic Acid and Single-Walled Carbon Nanotubes

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1181 ◽  
Author(s):  
Sveta Zhiraslanovna Ozkan ◽  
Galina Petrovna Karpacheva ◽  
Aleksandr Ivanovich Kostev ◽  
Galina Nikolaevna Bondarenko
Keyword(s):  
Carbon Nanotubes ◽  
Carboxylic Acid ◽  
Carbon Nanomaterials ◽  
Oxidative Polymerization ◽  
Ammonium Hydroxide ◽  
Single Walled Carbon Nanotubes ◽  
Hybrid Nanocomposites ◽  
Heterophase System ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Hybrid nanocomposites based on electroactive polydiphenylamine-2-carboxylic acid (PDPAC) and single-walled carbon nanotubes (SWCNTs) were obtained for the first time. Polymer-carbon nanomaterials were synthesized via in situ oxidative polymerization of diphenylamine-2-carboxylic acid (DPAC) in the presence of SWCNTs by two different ways. Hybrid SWCNT/PDPAC nanocomposites were prepared both in an acidic medium and in the heterophase system in an alkaline medium. In the heterophase system, the monomer and the SWCNTs are in the organic phase (chloroform) and the oxidant (ammonium persulfate) is in an aqueous solution of ammonium hydroxide. The chemical structure, as well as the electrical and thermal properties of the developed SWCNT/PDPAC nanocomposite materials were investigated.

scholarly journals Preparation of Bulk13C-Enriched Graphene Materials

2010 ◽  
Vol 2010 ◽  
pp. 1-5 ◽  
Author(s):  
Leilei Tian ◽  
Xin Wang ◽  
Li Cao ◽  
Mohammed J. Meziani ◽  
Chang Yi Kong ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Convenient Method ◽  
Carbon Nanomaterials ◽  
Arc Discharge ◽  
Single Walled Carbon Nanotubes ◽  
Production Technique ◽  
Graphene Oxides ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes ◽  
Bulk Production

Arc-discharge has been widely used in the bulk production of various carbon nanomaterials, especially for structurally more robust single-walled carbon nanotubes. In this paper, the same bulk-production technique was applied to the synthesis of significantly13C-enriched graphitic materials, from which graphene oxides similarly enriched with13C were prepared and characterized. The results demonstrate that arc-discharge is a convenient method to produce bulk quantities of13C-enriched graphene materials from relatively less expensive precursors (largely amorphous13C powders).

Sidewall Carboxylic Acid Functionalization of Single-Walled Carbon Nanotubes

2003 ◽  
Vol 125 (49) ◽  
pp. 15174-15182 ◽  
Author(s):  
Haiqing Peng ◽  
Lawrence B. Alemany ◽  
John L. Margrave ◽  
Valery N. Khabashesku
Keyword(s):  
Carbon Nanotubes ◽  
Carboxylic Acid ◽  
Single Walled Carbon Nanotubes ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Patterning of Single-Walled Carbon Nanotubes Using Wet Chemical Self-Assembling and Photolithographic Technique

2005 ◽  
Vol 901 ◽  
Author(s):  
Myung-Sup Jung ◽  
Sung-Ouk Jung ◽  
Hee-Tae Jung ◽  
Do Yun Kim ◽  
Seok Gwang Doo
Keyword(s):  
Carbon Nanotubes ◽  
Carboxylic Acid ◽  
High Surface ◽  
Single Walled Carbon Nanotubes ◽  
High Density ◽  
Amino Groups ◽  
Patterned Substrate ◽  
Single Walled Carbon ◽  
Carboxylic Acid Groups ◽  
Walled Carbon Nanotubes

AbstractSingle-walled carbon nanotubes (SWNTs) have been chemically attached with high density onto a patterned substrate. To form the SWNT pattern, the substrate was treated with acid-labile group protected amine, and an amine prepattern was formed using a photolithographic process with a polymeric photo acid generator. The SWNT monolayer pattern was then formed through the amidation reaction between the carboxylic acid groups of carboxylated SWNTs (ca-SWNTs) and the prepatterned amino groups. A high-density multilayer was fabricated via further repeated reaction between the carboxylic acid groups of the ca-SWNTs and the amino groups of the linker with the aid of a condensation agent. Scanning electron microscopy results show that the patterned SWNT films have uniform coverage with high surface density.

Enhanced Thermoelectric Performance of Single-Walled Carbon Nanotubes/Polyaniline Hybrid Nanocomposites

ACS Nano ◽  
2010 ◽  
Vol 4 (4) ◽  
pp. 2445-2451 ◽  
Author(s):  
Qin Yao ◽  
Lidong Chen ◽  
Wenqing Zhang ◽  
Shengcong Liufu ◽  
Xihong Chen
Keyword(s):  
Carbon Nanotubes ◽  
Single Walled Carbon Nanotubes ◽  
Hybrid Nanocomposites ◽  
Thermoelectric Performance ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

scholarly journals Detection of a CO and NH3 gas mixture using carboxylic acid-functionalized single-walled carbon nanotubes

2013 ◽  
Vol 8 (1) ◽  
pp. 12 ◽  
Author(s):  
Ki-Young Dong ◽  
Jinnil Choi ◽  
Yang Doo Lee ◽  
Byung Hyun Kang ◽  
Youn-Yeol Yu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Carboxylic Acid ◽  
Single Walled Carbon Nanotubes ◽  
Gas Mixture ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Conducting Polymer Functionalized Single-Walled Carbon Nanotubes: Synthesis, Morphological Characteristics and Thermal Stability

2011 ◽  
Vol 306-307 ◽  
pp. 1182-1185
Author(s):  
Hong Mei Niu
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Stability ◽  
Electrical Conductivity ◽  
Weight Loss ◽  
Oxidative Polymerization ◽  
Morphological Characteristics ◽  
Morphological Structure ◽  
Single Walled Carbon Nanotubes ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Nanocomposites of single-walled carbon nanotubes modified polypyrrole (PPy/SWNTs) were synthesized successfully by in situ oxidative polymerization method in the FeCl3·6H2O solution. The morphological structure, electrical conductivity and thermal stability of the nanocomposites were characterized by TEM, SEM, FTIR and TGA. The PPy/SWNTs were 50-100 nm in diameter of PPy coating uniformly on the surface of the SWNTs. FTIR spectra revealed the presence of covalently interaction between the PPy and the carbon nanotubes. The electrical conductivity of PPy/SWNTs composite and pure PPy were 93 and 8.0×10-3 S/cm, respectively. Meanwhile, the PPy/SWNTs composites possessed higher thermal stability (65.9 wt. % weight loss at 600 °C) compared to pure PPy (81.2 wt. % weight loss at 600°C), the content of SWNTs was 15.3 wt. %.

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