scholarly journals Development of a High-Performance Adhesive with a Microphase, Separation Crosslinking Structure Using Wheat Flour and a Hydroxymethyl Melamine Prepolymer

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 893 ◽  
Author(s):  
Jieyu Zhang ◽  
Yi Zhang ◽  
Jianzhang Li ◽  
Qiang Gao
Keyword(s):  
Shear Strength ◽  
Fracture Surface ◽  
Bond Strength ◽  
Wheat Flour ◽  
High Performance ◽  
Water Resistance ◽  
Microphase Separation ◽  
Low Cost ◽  
Bond Performance ◽  
Effective Manner

The objective of this study is to use wheat flour (WF) and hydroxymethyl melamine prepolymer (HMP) to develop a low cost, highly water-resistant, starch-based bio-adhesive for plywood fabrication. Three-layer plywood was fabricated using the resultant adhesive, and the wet shear strength of the plywood samples was measured under various conditions. After determining that water resistance was significantly improved with the addition of HMP, we evaluated the physical characteristics of the starch-based adhesive and functional groups and analyzed the thermal stability and fracture surface of the cured adhesive samples. Results showed that by adding 20 wt.% HMP into WF adhesive, the sedimentation volume in the resultant adhesive decreased by 11.3%, indicating that the increase of crosslinking in the structure of the adhesives increased the bond strength, and the wet shear strength of the resultant plywood in 63 °C water improved by 375% when compared with the WF adhesive. After increasing the addition of HMP to 40 wt.%, the wet shear strength of the resultant plywood in 100 °C water changed from 0 MPa to 0.71 MPa, which meets the exterior use plywood requirement. This water resistance and bond strength improvement resulted from (1) HMP reacting with functions in WF and forming a crosslinking structure to prevent moisture intrusion; and (2) HMP self-crosslinking and combining with crosslinked WF to form a microphase separation crosslinking structure, which improved both the crosslinking density and the toughness of the adhesive, and subsequently, the adhesive’s bond performance. In addition, the microphase separation crosslinking structure had better thermostability and created a compact ductile fracture surface, which further improved the bond performance of the adhesive. Thus, using a prepolymer to form a microphase separation crosslinking structure within the adhesive improves the rigidity, toughness, and water resistance of the material in a practical and cost-effective manner.

scholarly journals A High-Performance and Low-Cost Soy Flour Adhesive with a Hydroxymethyl Melamine Prepolymer

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 909 ◽  
Author(s):  
Meng Zhang ◽  
Yi Zhang ◽  
Mingsong Chen ◽  
Qiang Gao ◽  
Jianzhang Li
Keyword(s):  
Thermal Stability ◽  
Shear Strength ◽  
High Performance ◽  
Water Resistance ◽  
Low Cost ◽  
Soy Flour ◽  
National Standard ◽  
Interpenetrating Network ◽  
Residual Rate ◽  
Rate Functions

To improve the performance of a soy flour (SF)-based adhesive, a low-cost hydroxymethyl melamine prepolymer (HMP) was synthesized and then used to modify the SF-based adhesive. The HMP was characterized, and the performance of the adhesive was evaluated, including its residual rate, functions, thermal stability, and fracture section. Plywood was fabricated to measure wet shear strength. The results indicated that the HMP preferentially reacted with polysaccharose in SF and formed a cross-linking network to improve the water resistance of the adhesive. This polysaccharose-based network also combined with the HMP self-polycondensation network and soy protein to form an interpenetrating network, which further improved the water resistance of the adhesive. With the addition of 9% HMP, the wet shear strength (63 °C) of the plywood was 1.21 MPa, which was 9.3 times that of the SF adhesive. With the HMP additive increased to 15%, the shear strength (100 °C) of the plywood was 0.79 MPa, which met the plywood requirement for exterior use (≥0.7 MPa) in accordance with Chinese National Standard (GB/T 9846.3-2004). With the addition of 9% and 15% HMP, the residual rates of the adhesive improved by 5.1% and 8.5%, respectively. The dense interpenetrating network structure improved the thermal stability of the resultant adhesive and created a compact fracture to prevent moisture intrusion, which further increased the water resistance of the adhesive.

scholarly journals Chitosan-Based Adhesive: Optimization of Tensile Shear Strength in Dry and Wet Conditions

2021 ◽  
Vol 2 (1) ◽  
pp. 110-120
Author(s):  
Maisa Abdelmoula ◽  
Hajer Ben Hlima ◽  
Frédéric Michalet ◽  
Gérard Bourduche ◽  
Jean-Yves Chavant ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Shear Strength ◽  
Bond Strength ◽  
Water Resistance ◽  
Tensile Shear Strength ◽  
Tensile Shear ◽  
Spread Rate ◽  
Assembly Time ◽  
Deacetylation Degree ◽  
Dry And Wet Conditions

Commercial adhesives present a high bond strength and water resistance, but they are considered non-healthier products. Chitosan can be considered as an interesting biosourced and biodegradable alternative, despite its low water resistance. Here, its wood bonding implementation and its tensile shear strength in dry and wet conditions were investigated depending on its structural characteristics. Firstly, the spread rate, open assembly time, drying pressure, drying temperature, and drying time have been determined for two chitosans of European pine double lap specimens. An adhesive solution spread rate of 1000 g·m−2, an open assembly time of 10 min, and a pressure temperature of 55 °C for 105 min led to a bond strength of 2.82 MPa. Secondly, a comparison between a high molecular weight/low deacetylation degree chitosan and a lower molecular weight/higher deacetylation degree chitosan was conducted. Tests were conducted with beech simple lap specimens in accordance with the implementation conditions and the conditioning treatments in wet and dry environments required for thermoplastic wood adhesive standards used in non-structural applications (EN 204 and EN 205). The results clearly revealed the dependence of adhesive properties and water resistance on the structural features of chitosans (molecular weight and deacetylation degree), explaining the heterogeneity of results published notably in this field.

Experimental Research on Interfacial Bond Performance in Rock Anchor with High-Performance Grouting Medium

2012 ◽  
Vol 517 ◽  
pp. 932-938 ◽  
Author(s):  
Zhi Fang ◽  
Hong Qiao Zhang
Keyword(s):  
Rock Mass ◽  
Bond Strength ◽  
High Performance ◽  
Interfacial Bond ◽  
Interfacial Bond Strength ◽  
Bond Performance ◽  
Pull Out ◽  
Steel Bar ◽  
Reactive Powder ◽  
Ground Anchor

There exist the problems such as low bond strength and bad durability in the ordinary grouting slurry of the ground anchor system at present. The high-performance grouting mediums RPC (Reactive Powder Concrete) and DSP (Densified Systems containing homogeneously arranged ultrafine Particles) would become the potential replacement of grouting medium in ground anchor resulting from their high compressive strength, durability and toughness. Based on a series of pull-out tests on ground anchors with different high-performance grouting medium of RPC and DSP , different bond length in the construction field, the bond performance on the interfaces between anchor bolt (deformed steel bar) and grouted medium as well as between grouted medium and rock mass was studied. The results indicate that the interfacial bond strength between RPC or DSP and deformed steel bolt ranges within 23-31Mpa, far greater than that (about 2-3MPa) between the ordinary cementitious grout and deformed steel bar. Even though the interfacial bond strength between the grouted medium and rock mass of limestone was not obtained in the test since the failure mode was pull-out of those steel bar rather than the interface shear failure between grouted medium and rock mass, the bond stress on the interface reached 6.2-8.38 MPa, also far greater than the bond strength (about 0.1-3MPa) between the ordinary cementitious slurry and rocks.

scholarly journals Virtual Torque Sensor for Low-Cost RC Servo Motors Based on Dynamic System Identification Utilizing Parametric Constraints

Sensors ◽  
2018 ◽  
Vol 18 (11) ◽  
pp. 3856 ◽  
Author(s):  
Yoonkyu Hwang ◽  
Yuki Minami ◽  
Masato Ishikawa
Keyword(s):  
System Identification ◽  
High Performance ◽  
Dynamic Models ◽  
Low Cost ◽  
Human Robot Interaction ◽  
Robot Dynamics ◽  
Internal Dynamic ◽  
Torque Sensor ◽  
Virtual Sensor ◽  
Effective Manner

We propose a novel virtual torque sensor for commercial low-cost radio-controlled (RC) servo motors. The virtual torque sensor has played an important role for conventional robots. It has been used for torque-required control applications such as human–robot interaction and under-actuated robots. However, most virtual torque sensors are based on the inversion of actuators or robot dynamics with the assumption that entire dynamics are known. This is not applicable to the RC servo motors that have unknown control structures. As RC servo motors enable researchers and hobbyists to create lightweight but high performance robots in an easy and cost-effective manner, the development of a virtual torque sensor for these motors is necessary. In this study, we propose a design method of a virtual torque sensor for RC servo motors. First, the virtual sensor is derived mathematically based on internal dynamic models with parametric constraints and compared to the conventional model. Second, a dedicated system identification method is developed for the proposed virtual sensor to implement the sensor in actual experiments. Finally, we compare experimental results with the measurements obtained by an actual sensor.

scholarly journals Effect of Internal Curing with Superabsorbent Polymers on Bond Behavior of High-Strength Concrete

2020 ◽  
Vol 2020 ◽  
pp. 1-13
Author(s):  
Xiao Lei ◽  
Rui Wang ◽  
Hanwan Jiang ◽  
Faxiang Xie ◽  
Yanni Bao
Keyword(s):  
Bond Strength ◽  
High Strength Concrete ◽  
High Performance ◽  
High Performance Concrete ◽  
High Strength ◽  
Internal Curing ◽  
Superabsorbent Polymers ◽  
Strength Concrete ◽  
Bond Performance ◽  
Pull Out

High-strength concrete (HSC) is widely used in engineering due to its high strength and durability. However, because of its low water-to-cement ratio, external curing water hardly enters the dense internal structure of HSC so that high self-desiccation shrinkage often takes place. As a result, superabsorbent polymers (SAP) are added as an internal curing material to effectively reduce the shrinkage of high-performance concrete. Meanwhile, the bond performance between reinforcing steel and SAP HSC concrete remains unknown. In this paper, the bond performance of HSC mixed with SAP is studied by pull-out tests, and the results were obtained as follows: (1) the bond strength of HSC mixed with SAP increased first and then decreased with the increase of SAP content; (2) the slip at ultimate bond strength of HSC with SAP decreased with the increase of compressive strength; (3) a prediction model of the stress-slip relationship between steel rebars and HSC was established.

Comparison of UV- and Derivative-Spectrophotometric and HPTLC UVDensitometric Methods for the Determination of Amrinone and Milrinone in Bulk Drugs

2020 ◽  
Vol 16 (3) ◽  
pp. 246-253
Author(s):  
Marcin Gackowski ◽  
Marcin Koba ◽  
Stefan Kruszewski
Keyword(s):  
Thin Layer ◽  
Thin Layer Chromatography ◽  
High Performance ◽  
Low Cost ◽  
Uv Spectra ◽  
Derivative Spectrophotometry ◽  
Therapeutic Monitoring ◽  
Bulk Drug ◽  
Layer Chromatography ◽  
Standard Solutions

Background: Spectrophotometry and thin layer chromatography have been commonly applied in pharmaceutical analysis for many years due to low cost, simplicity and short time of execution. Moreover, the latest modifications including automation of those methods have made them very effective and easy to perform, therefore, the new UV- and derivative spectrophotometry as well as high performance thin layer chromatography UV-densitometric (HPTLC) methods for the routine estimation of amrinone and milrinone in pharmaceutical formulation have been developed and compared in this work since European Pharmacopoeia 9.0 has yet incorporated in an analytical monograph a method for quantification of those compounds. Methods: For the first method the best conditions for quantification were achieved by measuring the lengths between two extrema (peak-to-peak amplitudes) 252 and 277 nm in UV spectra of standard solutions of amrinone and a signal at 288 nm of the first derivative spectra of standard solutions of milrinone. The linearity between D252-277 signal and concentration of amironone and 1D288 signal of milrinone in the same range of 5.0-25.0 μg ml/ml in DMSO:methanol (1:3 v/v) solutions presents the square correlation coefficient (r2) of 0,9997 and 0.9991, respectively. The second method was founded on HPTLC on silica plates, 1,4-dioxane:hexane (100:1.5) as a mobile phase and densitometric scanning at 252 nm for amrinone and at 271 nm for milrinone. Results: The assays were linear over the concentration range of 0,25-5.0 μg per spot (r2=0,9959) and 0,25-10.0 μg per spot (r2=0,9970) for amrinone and milrinone, respectively. The mean recoveries percentage were 99.81 and 100,34 for amrinone as well as 99,58 and 99.46 for milrinone, obtained with spectrophotometry and HPTLC, respectively. Conclusion: The comparison between two elaborated methods leads to the conclusion that UV and derivative spectrophotometry is more precise and gives better recovery, and that is why it should be applied for routine estimation of amrinone and milrinone in bulk drug, pharmaceutical forms and for therapeutic monitoring of the drug.

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