scholarly journals 3D Printing of an Oil/Water Mixture Separator with In Situ Demulsification and Separation

Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 774 ◽  
Author(s):  
Changyou Yan ◽  
Shuanhong Ma ◽  
Zhongying Ji ◽  
Yuxiong Guo ◽  
Zhilu Liu ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Separation Efficiency ◽  
Water Mixture ◽  
Fused Deposition ◽  
Oil In Water ◽  
Wide Range ◽  
Hydrogel Coatings ◽  
Oil Water ◽  
Underwater Superoleophobicity

Currently, many meshes, membranes, and fabrics with extreme wettability of superhydrophobicity/superoleophilicity, or superhydrophilicity and underwater superoleophobicity are promising candidates for oil/water mixture separation. Nevertheless, a facile yet effective way to design and fabricate porous mesh still remains challenging. In this work, fused deposition modeling (FDM) 3D printing of Fe/polylactic acid (PLA) composites was employed to fabricate superhydrophilic and underwater superoleophobic mesh (S-USM) with hydrogel coatings via the surface polymerization of Fe(II)-mediated redox reaction. In addition, salt of aluminum chloride was incorporated within the hydrogel coating, which was attributed to strengthening the demulsification of oil-in-water emulsions, resulting in efficient separation of oil-in-water mixtures. The S-USM was efficient for a wide range of oil-in-water mixtures, such as dodecane, diesel, vegetable oil, and even crude oil, with a separation efficiency of up to 85%. In this study, the flexible design and fabrication of 3D printing were used for the facile creation of spherical oil skimmers with hydrogel coatings that were capable of removing the floating oil. Most importantly, this work is expected to promote post-treatment processes using 3D printing as a new manufacturing technology and, in this way, a series of devices of specific shape and function will be expanded to satisfy desired requirements and bring great convenience to personal life.

scholarly journals Cellulose Nanofibrils Filled Poly(Lactic Acid) Biocomposite Filament for FDM 3D Printing

Molecules ◽  
2020 ◽  
Vol 25 (10) ◽  
pp. 2319 ◽  
Author(s):  
Qianqian Wang ◽  
Chencheng Ji ◽  
Lushan Sun ◽  
Jianzhong Sun ◽  
Jun Liu
Keyword(s):  
Thermal Stability ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
Mechanical Performance ◽  
Cellulose Nanofibrils ◽  
Poly Lactic Acid ◽  
Fused Deposition ◽  
Wide Range ◽  
The Matrix ◽  
Direct Digital Manufacturing

As direct digital manufacturing, 3D printing (3DP) technology provides new development directions and opportunities for the high-value utilization of a wide range of biological materials. Cellulose nanofibrils (CNF) and polylactic acid (PLA) biocomposite filaments for fused deposition modeling (FDM) 3DP were developed in this study. Firstly, CNF was isolated by enzymatic hydrolysis combined with high-pressure homogenization. CNF/PLA filaments were then prepared by melt-extrusion of PLA as the matrix and CNF as the filler. Thermal stability, mechanical performance, and water absorption property of biocomposite filaments and 3D-printed objects were analyzed. Findings showed that CNF increased the thermal stability of the PLA/PEG600/CNF composite. Compared to unfilled PLA FDM filaments, the CNF filled PLA biocomposite filament showed an increase of 33% in tensile strength and 19% in elongation at break, suggesting better compatibility for desktop FDM 3DP. This study provided a new potential for the high-value utilization of CNF in 3DP in consumer product applications.

scholarly journals 3D printing for clothing production

2020 ◽  
Vol 15 ◽  
pp. 155892502094821
Author(s):  
Tatjana Spahiu ◽  
Eriseta Canaj ◽  
Ermira Shehi
Keyword(s):  
3D Printing ◽  
Online Survey ◽  
Fused Deposition Modeling ◽  
Consumer Acceptance ◽  
Fashion Industry ◽  
3D Objects ◽  
Fused Deposition ◽  
Wide Range ◽  
Deposition Modeling ◽  
3D Printed

3D printing is a well-known technology for creating 3D objects by laying down successive layers of various materials. Among the wide range of applications, fashion industry has adapted these technologies to revolutionize their brands. But due to the unique characteristics of textiles like comfort, flexibility, and so on, attempts have been made to create similar structures as textiles. The work presented here is part of a project to create garments using fused deposition modeling as 3D printing technology. Structures with various geometries are designed and tested with different materials starting from rigid to flexible. As a result, a fully 3D printed dress is created. Selecting this dress as a model, consumer acceptance for 3D printed garments is evaluated realizing an online survey containing 100 respondents. The data gathered show that respondents have knowledge of 3D printing, its advantages and the majority of them would accept wearing a 3D printed dress.

scholarly journals Classification of X-Ray Attenuation Properties of Additive Manufacturing and 3D Printing Materials Using Computed Tomography From 70 to 140 kVp

2021 ◽  
Vol 9 ◽  
Author(s):  
Xiangjie Ma ◽  
Martin Buschmann ◽  
Ewald Unger ◽  
Peter Homolka
Keyword(s):  
Adipose Tissue ◽  
Additive Manufacturing ◽  
3D Printing ◽  
Energy Dependence ◽  
Fused Deposition Modeling ◽  
Soft Tissues ◽  
Diagnostic Image Quality ◽  
X Ray ◽  
Fused Deposition ◽  
Wide Range

Additive manufacturing and 3D printing is particularly useful in the production of phantoms for medical imaging applications including determination and optimization of (diagnostic) image quality and dosimetry. Additive manufacturing allows the leap from simple slab and stylized to (pseudo)-anthropomorphic phantoms. This necessitates the use of materials with x-ray attenuation as close as possible to that of the tissues or organs mimicked. X-ray attenuation properties including their energy dependence were determined for 35 printing materials comprising photocured resins and thermoplastic polymers. Prior to measuring x-ray attenuation in CT from 70 to 140 kVp, printing parameters were thoroughly optimized to ensure maximum density avoiding too low attenuation due to microscopic or macroscopic voids. These optimized parameters are made available. CT scanning was performed in a water filled phantom to guarantee defined scan conditions and accurate HU value determination. The spectrum of HU values covered by polymers printed using fused deposition modeling reached from −258 to +1,063 at 120 kVp (−197 to +1,804 at 70 kVp, to −266 to +985 at 140 kVp, respectively). Photocured resins covered 43 to 175 HU at 120 kVp (16–156 at 70, and 57–178 at 140 kVp). At 120 kVp, ASA mimics water almost perfectly (+2 HU). HIPS (−40 HU) is found close to adipose tissue. In all photocurable resins, and 17 printing filaments HU values decreased with increasing beam hardness contrary to soft tissues except adipose tissue making it difficult to mimic water or average soft tissue in phantoms correctly over a range of energies with one single printing material. Filled filaments provided both, the HU range, and an appropriate energy dependence mimicking bone tissues. A filled material with almost constant HU values was identified potentially allowing mimicking soft tissues by reducing density using controlled under-filling. The measurements performed in this study can be used to design phantoms with a wide range of x-ray contrasts, and energy dependence of these contrasts by combining appropriate materials. Data provided on the energy dependence can also be used to correct contrast or contrast to noise ratios from phantom measurements to real tissue contrasts or CNRs.

scholarly journals Experimental Investigation of Copper Mesh Substrate with Selective Wettability to Separate Oil/Water Mixture

Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4564
Author(s):  
Yuan ◽  
Cui ◽  
Qi ◽  
Wei ◽  
Qaisrani
Keyword(s):  
Separation Efficiency ◽  
Copper Substrate ◽  
Water Mixture ◽  
Oxidative Reaction ◽  
Liquid Flux ◽  
Oil Water ◽  
Low Efficiency ◽  
Underwater Superoleophobicity ◽  
Copper Mesh

To solve the problem of low efficiency and poor adaptability during complex oil/water mixtures separation, two types of membranes with superhydrophilicity/underwater-superoleophobicity were successfully fabricated by oxidative reaction and in situ displacement reaction methods. A nanoneedle Cu(OH)2 structure was generated on the copper mesh substrate by oxidative reaction and feathery micro/nanoscale composite, while Ag structure was constructed at the surface of copper mesh substrate through in-situ replacement, then, membranes with superhydrophilic/underwater-superoleophobic properties were separated. The influence of microstructure, wettability of the surface of prepared membranes and the liquid constituents in the separation experiment were studied and the liquid flux and permeation pressure at the membrane were later experimentally investigated. The experimental results show that separation efficiency of both membranes for separating different oil/water mixtures was above 99.8%. However, the separation efficiency of the Ag-CS (Ag on the copper substrate) membrane was obviously higher than that of the Cu(OH)2-CS (Cu(OH)2 on the copper substrate) membrane after 10 instances of separation because of the micro/nanocomposite structures. By comparison, it was found that the Ag-CS membrane showed a relatively higher permeation pressure but lower liquid flux as compared to Cu(OH)2-CS membrane, due to the influence of microscale structure and the wettability of the surface combined. In addition, the outcome for separating the multicomponent oil/water mixture illustrate that the result of TOC (the Total Organic Carbon) test for the Cu(OH)2-CS membrane and Ag-CS membrane were 31.2% and 17.7%, respectively, higher than the average of the two oils probably because some oil droplets created due to mutual dissolution passed through the membranes. However, these two fabricated membranes still retained higher separation efficiencies and good adaptability after 10 instances of separation. It was concluded that based on the good performances of the prepared membranes, especially the modified membrane, they have a vast application prospect and can be widely used.

Robust superhydrophobic attapulgite coated polyurethane sponge for efficient immiscible oil/water mixture and emulsion separation

2016 ◽  
Vol 4 (40) ◽  
pp. 15546-15553 ◽  
Author(s):  
Jian Li ◽  
Changcheng Xu ◽  
Yan Zhang ◽  
Rongfang Wang ◽  
Fei Zha ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Water Mixture ◽  
Water Emulsion ◽  
Oil In Water ◽  
Emulsion Separation ◽  
Polyurethane Sponge ◽  
Oil Water ◽  
Oil In Water Emulsion

The superhydrophobic PU sponges separated oils from immiscible oil/water mixture and oil-in-water emulsion with the separation efficiency over 99.8%.

Biodegradable 3D Printed Polymer Microneedles for Transdermal Drug Delivery

2018 ◽  
Author(s):  
Michael A. Luzuriaga ◽  
Danielle R. Berry ◽  
John C. Reagan ◽  
Ronald A. Smaldone ◽  
Jeremiah J. Gassensmith
Keyword(s):  
Drug Delivery ◽  
3D Printing ◽  
Transdermal Drug Delivery ◽  
Fused Deposition Modeling ◽  
Fused Deposition ◽  
Modeling Software ◽  
Deposition Modeling ◽  
3D Printed ◽  
Microfabrication Technique ◽  
Mechanical Strengths

Biodegradable polymer microneedle (MN) arrays are an emerging class of transdermal drug delivery devices that promise a painless and sanitary alternative to syringes; however, prototyping bespoke needle architectures is expensive and requires production of new master templates. Here, we present a new microfabrication technique for MNs using fused deposition modeling (FDM) 3D printing using polylactic acid, an FDA approved, renewable, biodegradable, thermoplastic material. We show how this natural degradability can be exploited to overcome a key challenge of FDM 3D printing, in particular the low resolution of these printers. We improved the feature size of the printed parts significantly by developing a post fabrication chemical etching protocol, which allowed us to access tip sizes as small as 1 μm. With 3D modeling software, various MN shapes were designed and printed rapidly with custom needle density, length, and shape. Scanning electron microscopy confirmed that our method resulted in needle tip sizes in the range of 1 – 55 µm, which could successfully penetrate and break off into porcine skin. We have also shown that these MNs have comparable mechanical strengths to currently fabricated MNs and we further demonstrated how the swellability of PLA can be exploited to load small molecule drugs and how its degradability in skin can release those small molecules over time.

scholarly journals 3D Printing of Mini Tablets for Pediatric Use

2021 ◽  
Vol 14 (2) ◽  
pp. 143
Author(s):  
Julius Krause ◽  
Laura Müller ◽  
Dorota Sarwinska ◽  
Anne Seidlitz ◽  
Malgorzata Sznitowska ◽  
...  
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Dosage Forms ◽  
Small Scale ◽  
Fused Deposition ◽  
On Demand ◽  
Pediatric Diseases ◽  
Deposition Modeling ◽  
Manufacturing Techniques ◽  
Pediatric Use

In the treatment of pediatric diseases, suitable dosages and dosage forms are often not available for an adequate therapy. The use of innovative additive manufacturing techniques offers the possibility of producing pediatric dosage forms. In this study, the production of mini tablets using fused deposition modeling (FDM)-based 3D printing was investigated. Two pediatric drugs, caffeine and propranolol hydrochloride, were successfully processed into filaments using hyprolose and hypromellose as polymers. Subsequently, mini tablets with diameters between 1.5 and 4.0 mm were printed and characterized using optical and thermal analysis methods. By varying the number of mini tablets applied and by varying the diameter, we were able to achieve different release behaviors. This work highlights the potential value of FDM 3D printing for the on-demand production of patient individualized, small-scale batches of pediatric dosage forms.

scholarly journals Mechanical Characterization and Thermodynamic Analysis of Laser-Polished Landscape Design Products Using 3D Printing

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2601
Author(s):  
Yue Ba ◽  
Yu Wen ◽  
Shibin Wu
Keyword(s):  
Surface Roughness ◽  
3D Printing ◽  
Fused Deposition Modeling ◽  
High Surface ◽  
Landscape Design ◽  
Laser Polishing ◽  
Fused Deposition ◽  
Design Structure ◽  
3D Printed ◽  
Stability And Accuracy

Recent innovations in 3D printing technologies and processes have influenced how landscape products are designed, built, and developed. In landscape architecture, reduced-size models are 3D-printed to replicate full-size structures. However, high surface roughness usually occurs on the surfaces of such 3D-printed components, which requires additional post-treatment. In this work, we develop a new type of landscape design structure based on the fused deposition modeling (FDM) technique and present a laser polishing method for FDM-fabricated polylactic acid (PLA) mechanical components, whereby the surface roughness of the laser-polished surfaces is reduced from over Ra 15 µm to less than 0.25 µm. The detailed results of thermodynamics and microstructure evolution are further analyzed during laser polishing. The stability and accuracy of the results are evaluated based on the standard deviation. Additionally, the superior tensile and flexural properties are examined in the laser-polished layer, in which the ultimate tensile strength (UTS) is increased by up to 46.6% and the flexural strength is increased by up to 74.5% compared with the as-fabricated components. Finally, a real polished landscape model is simulated and optimized using a series of scales.

scholarly journals 3D Printed Clamps for In Vitro Tensile Tests of Human Gracilis and the Superficial Third of Quadriceps Tendons

2021 ◽  
Vol 11 (6) ◽  
pp. 2563
Author(s):  
Ivan Grgić ◽  
Vjekoslav Wertheimer ◽  
Mirko Karakašić ◽  
Željko Ivandić
Keyword(s):  
3D Printing ◽  
Fused Deposition Modeling ◽  
Tensile Tests ◽  
Biomechanical Properties ◽  
Testing Procedure ◽  
Laboratory Equipment ◽  
Fused Deposition ◽  
Custom Made ◽  
3D Printed

Recent soft tissue studies have reported issues that occur during experimentation, such as the tissue slipping and rupturing during tensile loads, the lack of standard testing procedure and equipment, the necessity for existing laboratory equipment adaptation, etc. To overcome such issues and fulfil the need for the determination of the biomechanical properties of the human gracilis and the superficial third of the quadriceps tendons, 3D printed clamps with metric thread profile-based geometry were developed. The clamps’ geometry consists of a truncated pyramid pattern, which prevents the tendons from slipping and rupturing. The use of the thread application in the design of the clamp could be used in standard clamping development procedures, unlike in previously custom-made clamps. Fused deposition modeling (FDM) was used as a 3D printing technique, together with polylactic acid (PLA), which was used as a material for clamp printing. The design was confirmed and the experiments were conducted by using porcine and human tendons. The findings justify the usage of 3D printing technology for parts manufacturing in the case of tissue testing and establish independence from the existing machine clamp system, since it was possible to print clamps for each prepared specimen and thus reduce the time for experiment setup.

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