scholarly journals Preparation and Hydrogen Storage Characteristics of Surfactant-Modified Graphene

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1220 ◽  
Author(s):  
Tao Xu ◽  
Jiayu Chen ◽  
Wenhui Yuan ◽  
Baoqing Li ◽  
Li Li ◽  
...  

As the depletion of traditional fossil fuels and environmental pollution become serious problems for human society, researchers are actively looking for renewable energy sources. Since hydrogen energy is considered a clean, efficient, and renewable alternative energy source, it is regarded as the most promising option. In this context, how to store hydrogen safely and efficiently has become the major challenge that hinders the actual application. To fill this gap, this paper proposes to utilize surfactant-modified graphene for hydrogen storage. Through a modified Hummers’ method and ultrasonic stripping, this study proposes to prepare graphene from graphite oxide with NaBH4. The surfactant sodium dodecyl benzene sulfonate (SDBS) was used as a dispersant during the reduction process to produce dispersion-stabilized graphene suspensions. Then, to investigate the characteristics of the graphene suspensions, X-ray diffraction (XRD), SEM, TEM, Fourier transform infrared (FT-IR), Raman, XPS, TG, and N2 adsorption–desorption tests were conducted. Finally, analytical models for hydrogen adsorption were investigated with Langmuir and Freundlich fittings. The results show that the application of SDBS can effectively reduce the agglomeration among graphene monolayers and increase the specific surface area of graphene, and that the adsorption behavior is consistent with the Freundlich adsorption model, and is a physical process.

Author(s):  
Moon-Sun Chung ◽  
Jong-Won Kim

There are four R&D programs on hydrogen and fuel cell in Korea. Two of them are supported by MEST (Ministry of Education, Science and Technology) and others are funded by MKE (Ministry of Knowledge Economy). The hydrogen production technologies examined in Korea cover 3 main bases, fossil fuel, renewable energy including photo-catalytic, bio-hydrogen technology, and high temperature gas-cooled reactor. In October 2003, Korean government launched Hydrogen Energy R&D Center (HERC) as a member of the 21st Century Frontier R&D programs supported by the Ministry of Education, Science and Technology (MEST). The HERC has conducted research on the key technologies for the production, storage, and utilization of hydrogen energy for expediting realization of hydrogen economy based on renewable energy sources. The main purposes of this paper are to overview the current status of research programs for hydrogen storage technologies conducted by Hydrogen Energy R&D Center based on the patent applications as well as research topics and to introduce specific achievements in each research program.


Author(s):  
L.S. Plakitkina ◽  
Yu.A. Plakitkin

The damage caused by burning of coal is currently much higher than that produced by using alternative energy sources. This explains the growing urgency to implement the Paris Agreement on Climate Change, which, as of November 2020, has already been signed by more than 170 countries. The study analyzes the volumes of coal production by the world's coal market leaders over the period from 2000 to 2019. Despite an overall increase in global coal production by 1.5% in 2019 as compared to 2018, which reached 7.9 billion tons, there was a decrease in coal mining rates by 3.4% and 3.5% against the previous two years. The rapid decline in the importance of coal-fired power plants in the electric power generation of the European Union and Asia who seek to shift to renewable energy sources and hydrogen power, makes further growth in exports of Russian thermal coal quite problematic in the post-crisis period. Most probably, the declining trend in coal production and consumption will continue and even intensify in the coming years. The fall in coal mining and consumption in 2020 alone can reach 25% in the USA, 5–10% in Japan and South Korea, 20% in the EU countries, and 9% in China. The use of hydrogen fuel will make significant changes in the supply not only of the Russian coal, but also of the Russian natural gas and oil. The demand for these commodities will be decreasing.


2005 ◽  
Vol 20 (12) ◽  
pp. 3180-3187 ◽  
Author(s):  
Jim Ohi

This overview will describe briefly key segments of the hydrogen energy cycle from production using various feedstocks to its end use in fuel cells to generate electrical and thermal energy. The paper will also discuss the larger societal context, the so-called “hydrogen economy,” in which such production and use of hydrogen may take place. Although most of the public attention on hydrogen has been focused on its potential as an alternative energy source to petroleum and other fossil fuels, a hydrogen economy will encompass much more than a substitution of one energy source by another. Widespread use of hydrogen as an energy carrier can transform our society in much the same way that personal computing technologies have. This transforming power arises from the unique capability of hydrogen to link renewable energy resources and zero-emission energy conversion technologies. Hydrogen can be produced from locally available renewable resources, such as solar, wind, biomass, and water, and converted to electricity or fuel at or near the point of use with only heat and water vapor as “emissions.” Hydrogen also lies at the confluence of two emerging trends that will shape our energy future during the first quarter of this century: greater reliance on renewable energy sources and the shift from large, centralized power plants to smaller, decentralized facilities located at or near the point of use. This paper describes these emerging trends and the role of hydrogen in linking them in a way that could transform our society.


Author(s):  
Molla Asmare ◽  
Mustafa Ilbas

Nowadays, the most decisive challenges we are fronting are perfectly clean energy making for equitable and sustainable modern energy access, and battling the emerging alteration of the climate. This is because, carbon-rich fuels are the fundamental supply of utilized energy for strengthening human society, and it will be sustained in the near future. In connection with this, electrochemical technologies are an emerging and domineering tool for efficiently transforming the existing scarce fossil fuels and renewable energy sources into electric power with a trivial environmental impact. Compared with conventional power generation technologies, SOFC that operate at high temperature is emerging as a frontrunner to convert the fuels chemical energy into electric power and permits the deployment of varieties of fuels with negligible ecological destructions. According to this critical review, direct ammonia is obtained as a primary possible choice and price-effective green fuel for T-SOFCs. This is because T-SOFCs have higher volumetric power density, mechanically stable, and high thermal shocking resistance. Also, there is no sealing issue problem which is the chronic issues of the planar one. As a result, the toxicity of ammonia to use as a fuel is minimized if there may be a leakage during operation. It is portable and manageable that can be work everywhere when there is energy demand. Besides, manufacturing, onboard hydrogen deposition, and transportation infrastructure connected snags of hydrogen will be solved using ammonia. Ammonia is a low-priced carbon-neutral source of energy and has more stored volumetric energy compared with hydrogen. Yet, to utilize direct NH3 as a means of hydrogen carrier and an alternative green fuel in T-SOFCs practically determining the optimum operating temperatures, reactant flow rates, electrode porosities, pressure, the position of the anode, thickness and diameters of the tube are still requiring further improvement. Therefore, mathematical modeling ought to be developed to determine these parameters before planning for experimental work. Also, a performance comparison of AS, ES, and CS- T-SOFC powered with direct NH3 will be investigated and best-performed support will be carefully chosen for practical implementation and an experimental study will be conducted for verification based on optimum parameter values obtained from numerical modeling.


2019 ◽  
Vol 3 (1) ◽  
pp. 1-12
Author(s):  
Lauren K. D’Souza ◽  
William L. Ascher ◽  
Tanja Srebotnjak

Native American reservations are among the most economically disadvantaged regions in the United States; lacking access to economic and educational opportunities that are exacerbated by “energy insecurity” due to insufficient connectivity to the electric grid and power outages. Local renewable energy sources such as wind, solar, and biomass offer energy alternatives but their implementation encounters barriers such as lack of financing, infrastructure, and expertise, as well as divergent attitudes among tribal leaders. Biomass, in particular, could be a source of stable base-load power that is abundant and scalable in many rural communities. This case study examines the feasibility of a biomass energy plant on the Cocopah reservation in southwestern Arizona. It considers feedstock availability, cost and energy content, technology options, nameplate capacity, discount and interest rates, construction, operation and maintenance (O&M) costs, and alternative investment options. This study finds that at current electricity prices and based on typical costs for fuel, O&M over 30 years, none of the tested scenarios is presently cost-effective on a net present value (NPV) basis when compared with an alternative investment yielding annual returns of 3% or higher. The technology most likely to be economically viable and suitable for remote, rural contexts—a combustion stoker—resulted in a levelized costs of energy (LCOE) ranging from US$0.056 to 0.147/kWh. The most favorable scenario is a combustion stoker with an estimated NPV of US$4,791,243. The NPV of the corresponding alternative investment is US$7,123,380. However, if the tribes were able to secure a zero-interest loan to finance the plant’s installation cost, the project would be on par with the alternative investment. Even if this were the case, the scenario still relies on some of the most optimistic assumptions for the biomass-to-power plant and excludes abatement costs for air emissions. The study thus concludes that at present small-scale, biomass-to-energy projects require a mix of favorable market and local conditions as well as appropriate policy support to make biomass energy projects a cost-competitive source of stable, alternative energy for remote rural tribal communities that can provide greater tribal sovereignty and economic opportunities.


2018 ◽  
Vol 1 (2) ◽  
pp. 40-51 ◽  
Author(s):  
Muhammad Burhan ◽  
Muhammad Wakil Shahzad ◽  
Kim Choon Ng

Standalone power systems have vital importance as energy source for remote area. On the other hand, a significant portion of such power production is used for cooling purposes. In this scenario, renewable energy sources provide sustainable solution, especially solar energy due to its global availability. Concentrated photovoltaic (CPV) system provides highest efficiency photovoltaic technology, which can operate at x1000 concentration ratio. However, such high concentration ratio requires heat dissipation from the cell area to maintain optimum temperature. This paper discusses the size optimization algorithm of sustainable cooling system using CPVT. Based upon the CPV which is operating at x1000 concentration with back plate liquid cooling, the CPVT system size is optimized to drive a hybrid mechanical vapor compression (MVC) chiller and adsorption chiller, by utilizing both electricity and heat obtained from the solar system. The electrolysis based hydrogen is used as primary energy storage system along with the hot water storage tanks. The micro genetic algorithm (micro-GA) based optimization algorithm is developed to find the optimum size of each component of CPVT-Cooling system with uninterrupted power supply and minimum cost, according to the developed operational strategy. The hybrid system is operated with solar energy system efficiency of 71%.


Author(s):  
Александр Григорьевич Комков ◽  
Александр Константинович Сокольский

В статье рассмотрено современное состояние энергоснабжения и перспективы развития альтернативных источников энергии на территории Крайнего Севера. Отмечено, что несмотря на острую потребность во внедрении возобновляемых источников энергии, установленные мощности всех ветряных и солнечных электростанций в регионе не превышают 7-8 МВт. Также в работе рассчитаны технический и экономический потенциал ветровой энергии региона, на основании которых подобрана наиболее эффективная установка. The article discusses the current state of energy supply and the prospects for the development of alternative energy sources in the Far North. It is noted that despite the urgent need for the introduction of renewable energy sources, the installed capacities of all wind and solar power plants in the region do not exceed 7-8 MW. Also, the technical and economic potential of the region’s wind energy was calculated based on which the most efficient installation was selected.


Author(s):  
Almas Heshmati ◽  
Shahrouz Abolhosseini

This chapter reviews relevant literature on the current state and effectiveness of developing renewable energy on energy security in general, and on energy security in the European Union (EU) in particular. The chapter elaborates on primary energy import sources, possible alternatives, and how energy security is affected by the sources of supply. It also gives an analysis of the effects of the Ukrainian crisis, the isolation of Iran on diversification sources, and on European energy security. It examines EU’s energy policy, analyses the best motivation for a new energy policy direction within Europe, and suggests alternative solutions for enhanced energy supply security. The aim is to suggest suitable solutions for energy security in Europe through energy supply diversification. Supply diversification includes alternative energy corridors for reducing dependency on Russia as a supplier and enhancing the power generated by renewable energy sources under the European Union 2020 strategy.


Author(s):  
Kuo-Wei Huang ◽  
Sudipta Chatterjee ◽  
Indranil Dutta ◽  
Yanwei Lum ◽  
Zhiping Lai

Formic acid has been proposed as a hydrogen energy carrier because of its many desirable properties, such as low toxicity and flammability, and a high volumetric hydrogen storage capacity of...


2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Xiaobin Wen ◽  
Aoqi Zhang ◽  
Xiaoyan Zhu ◽  
Lin Liang ◽  
Yan Huo ◽  
...  

Abstract Background Predatory flagellates and ciliates are two common bio-contaminants which frequently cause biomass losses in Chlorella mass culture. Efficient and targeted ways are required to control these contaminations in Chlorella mass cultivation aiming for biofuel production especially. Results Five surfactants were tested for its ability to control bio-contaminations in Chlorella culture. All five surfactants were able to eliminate the contaminants at a proper concentration. Particularly the minimal effective concentrations of sodium dodecyl benzene sulfonate (SDBS) to completely eliminate Poterioochromonas sp. and Hemiurosomoida sp. were 8 and 10 mg L−1, respectively, yet the photosynthesis and viability of Chlorella was not significantly affected. These results were further validated in Chlorella mass cultures in 5, 20, and 200 m2 raceway ponds. Conclusions A chemical method using 10 mg L−1 SDBS as pesticide to control predatory flagellate or ciliate contamination in Chlorella mass culture was proposed. The method helps for a sustained microalgae biomass production and utilization, especially for biofuel production.


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