scholarly journals New Pyridinium Type Poly(Ionic Liquids) as Membranes for CO2 Separation

Polymers ◽  
2018 ◽  
Vol 10 (8) ◽  
pp. 912 ◽  
Author(s):  
Aristofanis Vollas ◽  
Thanasis Chouliaras ◽  
Valadoula Deimede ◽  
Theophilos Ioannides ◽  
Joannis Kallitsis
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Main Chain ◽  
Co2 Separation ◽  
Minimum Thickness ◽  
Free Standing ◽  
Excellent Thermal Stability ◽  
High Co2 ◽  
Weight Percentage ◽  
Ideal Selectivity

New pyridinium based PILs have been prepared by modification of their precursors based on high molecular weight aromatic polyethers bearing main chain pyridine units. The proposed methodology involves the conversion of the precursors to their ionic analogues via N-methylation reaction, followed by anion exchange methathesis reaction to result in PILs with the desirable anions (tetrafluoroborate and bis(trifluoromethylsulfonyl)imide). These PILs show excellent thermal stability, excellent mechanical properties, and most importantly can form very thin, free standing films with minimum thickness of 3 μm. As expected, the PIL containing the TFSI− anion showed improved CO2 and CH4 permeabilities compared to its analogue containing the BF4−. PIL-IL composites membranes have also been prepared using the same PIL and different percentages of pyridinium based IL where it was shown that the membrane with the highest IL weight percentage (45 wt %) showed the highest CO2 permeability (11.8 Barrer) and a high CO2/CH4 ideal selectivity of 35 at room temperature.

Effect of Moisture on the Mechanical Properties of Additively Manufactured PLA, ABS and PLA/SiC Composites

2019 ◽  
Author(s):  
Padmalatha Kakanuru ◽  
Kishore Pochiraju
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Moisture Absorption ◽  
Failure Strain ◽  
Acrylonitrile Butadiene Styrene ◽  
Distilled Water ◽  
Weight Percentage ◽  
Lower Volume ◽  
Sic Composites ◽  
Butadiene Styrene

Abstract In this study the tensile properties of additively manufactured Polylactic Acid (PLA), Acrylonitrile Butadiene Styrene (ABS) and Silicon Carbide (SiC) particulate filled PLA composites were assessed after aging for 4.5 months at 50°C in distilled water. The maximum moisture gain in PLA was about 16% by weight, and ABS gained 0.65%. In PLA/SiC composites, the weight gain due to moisture absorption was inversely proportional to the weight percentage of SiC loading. The PLA specimens degraded completely during aging without measurable residual strength. While the addition of SiC to PLA increased the room temperature tensile strength at lower volume fractions of SiC, the degradation of aged strength was similar to that of the pure PLA. The PLA/SiC composites had no measurable strength after aging. The ABS specimens retained their strength and failure strain after aging.

Effect of Long-Term Aging on Microstructure and Mechanical Properties of a Wrought Ni-Base Superalloy

2015 ◽  
Vol 816 ◽  
pp. 546-550
Author(s):  
Chao Yuan ◽  
Huan Wang ◽  
Jian Ting Guo ◽  
He Yong Qin
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Room Temperature ◽  
Excellent Thermal Stability ◽  
Good Thermal Stability ◽  
Increasing Trend ◽  
Size And Morphology ◽  
Strength And Plasticity ◽  
Base Superalloy

During long-term and high temperature service, microstructures of superalloys may change and then have an adverse impact on mechanical properties, so the stabilities of a wrought Ni-base superalloy aging without stress at 650°C were investigated in this paper. The results showed that the size and morphology of γ' precipitates in the alloy were not obviously influenced with the increase of exposure time, and primary MC carbides present excellent thermal stability. Moreover, almost no detrimental phase was found. Tensile strength and plasticity at room temperature after aging remained steady. Under the condition of 650°C/823MPa, the stress ruptures life presented increasing trend overall and plasticity decreases slightly. In conclusion, the experiment alloy presents a good thermal stability at 650°C.

TEA incorporated CS blend composite membrane for high CO2 separation performance

RSC Advances ◽  
2016 ◽  
Vol 6 (32) ◽  
pp. 27016-27019 ◽  
Author(s):  
Miao Yu ◽  
Yan Dai ◽  
Kai Yang ◽  
Hao Li ◽  
Huimin Guo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Composite Membrane ◽  
Co2 Separation ◽  
Separation Performance ◽  
High Co2 ◽  
Blend Membrane ◽  
Chitosan Membrane

A novel triethanolamine–chitosan blend membrane exhibits better CO2/N2 separation performance and mechanical properties than pristine chitosan membrane.

Mechanical Properties and Dislocation Structure of Single Crystal Cdte Deformed in Compression at 300°C

1976 ◽  
Vol 34 ◽  
pp. 592-593
Author(s):  
Ernest L. Hall ◽  
J. B. Vander Sande
Keyword(s):  
Mechanical Properties ◽  
Single Crystal ◽  
Dislocation Structure ◽  
Room Temperature ◽  
Elevated Temperatures ◽  
Strain Curve ◽  
Optical Devices ◽  
Semiconductor Compound ◽  
Wide Range ◽  
Sample Orientation

The present paper describes research on the mechanical properties and related dislocation structure of CdTe, a II-VI semiconductor compound with a wide range of uses in electrical and optical devices. At room temperature CdTe exhibits little plasticity and at the same time relatively low strength and hardness. The mechanical behavior of CdTe was examined at elevated temperatures with the goal of understanding plastic flow in this material and eventually improving the room temperature properties. Several samples of single crystal CdTe of identical size and crystallographic orientation were deformed in compression at 300°C to various levels of total strain. A resolved shear stress vs. compressive glide strain curve (Figure la) was derived from the results of the tests and the knowledge of the sample orientation.

Autonomous self-healing polyisoprene elastomers with high modulus and good toughness based on the synergy of dynamic ionic crosslinks and highly disordered crystals

2020 ◽  
Vol 11 (41) ◽  
pp. 6549-6558
Author(s):  
Yohei Miwa ◽  
Mayu Yamada ◽  
Yu Shinke ◽  
Shoichi Kutsumizu
Keyword(s):  
Mechanical Properties ◽  
Room Temperature ◽  
Self Healing ◽  
High Modulus ◽  
Disordered Crystals ◽  
Ionic Crosslinks

We designed a novel polyisoprene elastomer with high mechanical properties and autonomous self-healing capability at room temperature facilitated by the coexistence of dynamic ionic crosslinks and crystalline components that slowly reassembled.

Cytocompatibility and Material Properties of Poly-carbonate Urethane/Carbon Nanofiber Composites for Neural Applications

2003 ◽  
Vol 774 ◽  
Author(s):  
Janice L. McKenzie ◽  
Michael C. Waid ◽  
Riyi Shi ◽  
Thomas J. Webster
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanofibers ◽  
Material Properties ◽  
Carbon Nanofiber ◽  
Scar Tissue ◽  
Tissue Response ◽  
Positive Interactions ◽  
Weight Percentage ◽  
Poly Carbonate

AbstractCarbon nanofibers possess excellent conductivity properties, which may be beneficial in the design of more effective neural prostheses, however, limited evidence on their cytocompatibility properties exists. The objective of the present in vitro study was to determine cytocompatibility and material properties of formulations containing carbon nanofibers to predict the gliotic scar tissue response. Poly-carbonate urethane was combined with carbon nanofibers in varying weight percentages to provide a supportive matrix with beneficial bulk electrical and mechanical properties. The substrates were tested for mechanical properties and conductivity. Astrocytes (glial scar tissue-forming cells) were seeded onto the substrates for adhesion. Results provided the first evidence that astrocytes preferentially adhered to the composite material that contained the lowest weight percentage of carbon nanofibers. Positive interactions with neurons, and, at the same time, limited astrocyte functions leading to decreased gliotic scar tissue formation are essential for increased neuronal implant efficacy.

Ultrastrong, Free-Standing and Large Nanofilms of Pyrenearamid

2019 ◽  
Author(s):  
Amalia Rapakousiou ◽  
Alejandro López-moreno ◽  
Belén Nieto-Ortega ◽  
M. Mar Bernal ◽  
Miguel A. Monclús ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Building Block ◽  
Aromatic Polyamide ◽  
Free Standing ◽  
Spatial Confinement ◽  
Polymeric Structure ◽  
Reduced Modulus ◽  
Organizational Arrangement ◽  
Polycyclic Aromatic ◽  
Nanoscale Building Block

We introduce poly(1,6-pyrene terephthalamide) polymer (PPyrTA) as an aromatic polyamide analogue of poly(p-phenylene terephthalamide) (PPTA), also known as Kevlar®. This work shows that the incorporation of polycyclic aromatic pyrene moieties improves drastically the mechanical properties of the polymeric structure, increasing elastic nanoindentation-determined modulus and hardness by factors of 1.9 and 4.3, respectively. Liquid deprotonated dispersions of PPyrTA nanofibers were used as nanoscale building block for producing large-surface, free-standing polymer macroscopic nanofilms. This 2D assembly leads to further significant improvements in reduced modulus and hardness (more than twice) compared to the starting polymer macroscale fibres, due to a better re-organizational arrangement of the PPyrTA nanofibers in the nanofilms, formed under 2D spatial confinement.

HASTELLOY ALLOY S

Alloy Digest ◽  
1973 ◽  
Vol 22 (1) ◽  
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Heat Treating ◽  
High Temperature Alloy ◽  
Excellent Thermal Stability ◽  
Cabot Corporation ◽  
High Temperature Mechanical Properties ◽  
Temperature Performance ◽  
Resistance To Oxidation ◽  
Nickel Base

Abstract HASTELLOY alloy S is a nickel-base high-temperature alloy having excellent thermal stability, good high-temperature mechanical properties and excellent resistance to oxidation up to 2000 F. This datasheet provides information on composition, physical properties, elasticity, and tensile properties as well as creep. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, machining, and joining. Filing Code: Ni-184. Producer or source: Stellite Division, Cabot Corporation.

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