scholarly journals Actinide and Lanthanide Adsorption onto Hierarchically Porous Carbons Beads: A High Surface Affinity for Pu

Nanomaterials ◽  
2019 ◽  
Vol 9 (10) ◽  
pp. 1464 ◽  
Author(s):  
Vittorio Luca ◽  
Devlet G. Sizgek ◽  
Erden Sizgek ◽  
Guilhem Arrachart ◽  
Cyrielle Rey ◽  
...  

Structured carbon adsorbents were prepared by carbonizing macroporous polyacrylonitrile beads whose pores were lined with a mesoporous phenolic resin. After activation, the beads were tested for minor actinide (Np and Am), major actinide (Pu and U) and lanthanide (Gd) adsorption in varying acidic media. The activation of the carbon with ammonium persulfate increased the surface adsorption of the actinides, while decreasing lanthanide adsorption. These beads had a pH region where Pu could be selectively extracted. Pu is one of the longest lived, abundant and most radiotoxic components of spent nuclear fuel and thus, there is an urgent need to increase its security of storage. As carbon has a low neutron absorption cross-section, these beads present an affordable, efficient and safe means for Pu separation from nuclear waste.

Alloy Digest ◽  
1961 ◽  
Vol 10 (9) ◽  

Abstract Carpenter Stainless 304+B is similar to conventional Type 304 with the addition of boron to give it a much higher thermal neutron absorption cross-section than other austenitic stainless steels. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on corrosion resistance as well as forming, heat treating, machining, joining, and surface treatment. Filing Code: SS-121. Producer or source: Carpenter.


Author(s):  
Márcia Andrade ◽  
Andrew J. Parnell ◽  
Gabriel Bernardo ◽  
Adélio Mendes

1959 ◽  
Vol 37 (5) ◽  
pp. 531-536 ◽  
Author(s):  
H. R. Fickel ◽  
R. H. Tomlinson

The effective neutron absorption cross section of Xe135 has been measured with a mass spectrometer by observing the variation in the Cs135/Cs137 fission yield ratio obtained at various thermal neutron fluxes. Values of 3.15 ± 0.06 megabarns and 3.27 ± 0.11 megabarns have been determined for neutron temperatures of 120 °C and 137 °C respectively.


Carbon ◽  
2002 ◽  
Vol 40 (3) ◽  
pp. 277-284 ◽  
Author(s):  
Shaobin Yang ◽  
Haoquan Hu ◽  
Guohua Chen

1983 ◽  
pp. 143-151
Author(s):  
J.A. CZUBEK ◽  
K. DROZDOWICZ ◽  
E. KRYNICKA-DROZDOWICZ ◽  
A. IGIELSKI ◽  
U. WOźNICKA

Geophysics ◽  
2017 ◽  
Vol 82 (1) ◽  
pp. EN13-EN24 ◽  
Author(s):  
Christopher van der Hoeven ◽  
Matthew Montgomery ◽  
Gregory Sablan ◽  
Erich Schneider ◽  
Carlos Torres-Verdín

Borehole neutron measurements are routinely used for in situ rock assessment in hydrocarbon reservoirs. We have used gadolinium oxide nanoparticles for enhancing the sensitivity of macroscopic thermal neutron absorption cross-section (Sigma) measurements of rocks. The gadolinium-based doping agent is used due to its exceptionally high neutron absorption cross section, low cost, and availability; it is also shown to preserve or enhance the differentiation between pore fluids. Injected from a pilot well, the doping agent could thus substantially improve the precision of Sigma-derived saturation measurements. Computational modeling verifies that modest gadolinium concentrations in the rock’s pore volume give rise to significant enhancement of reported Sigma: A concentration of 1750 weight ppm is shown to offer superior contrast enhancement across a wide range of rock solid and fluid compositions. Preliminary experimental work confirms the reported effects obtained with computational modeling of gadolinium doping in simulated porous rocks.


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