scholarly journals MAPbI3 Incorporated with Carboxyl Group Chelated Titania for Planar Perovskite Solar Cells in Low-Temperature Process

Nanomaterials ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 908 ◽  
Author(s):  
Pei-Shan Li ◽  
Rathinam Balamurugan ◽  
Bo-Tau Liu ◽  
Rong-Ho Lee ◽  
Hsueh-Tao Chou

Low-temperature, solution-processed, highly efficient hybrid organic/inorganic perovskite planar heterojunction solar cells were fabricated by incorporating reactive crystalline titania (h-TAc) into MAPbI3 layers. The h-TAc was prepared by the sol-gel reaction at low temperature followed by solvothermal treatment. The photoelectrical properties of the solar cells with h-TAc were analyzed. The incorporation with 0.85-wt% h-TAc showed the highest power conversion efficiency (PCE, 15.9%), increasing 69% compared to the pristine cell. The enhancement arose from large-grained microstructures, leading to a low rate of charge recombination. The carboxyl groups chelated on the surface of h-TAc revealed a strong attraction to lead ions, which are significantly helpful to MAPbI3 crystal growth.

Solar RRL ◽  
2018 ◽  
Vol 2 (2) ◽  
pp. 1700209 ◽  
Author(s):  
Chunhua Wang ◽  
Chujun Zhang ◽  
Shitan Wang ◽  
Gang Liu ◽  
Huayan Xia ◽  
...  

2016 ◽  
Vol 45 (18) ◽  
pp. 7856-7865 ◽  
Author(s):  
Weidong Zhu ◽  
Chunxiong Bao ◽  
Yangrunqian Wang ◽  
Faming Li ◽  
Xiaoxin Zhou ◽  
...  

The remarkable grain coarsening in one-step deposited OTP films for high efficiency planar-heterojunction perovskite solar cells.


2014 ◽  
Vol 2 (43) ◽  
pp. 9087-9090 ◽  
Author(s):  
Ling Wang ◽  
Weifei Fu ◽  
Zhuowei Gu ◽  
Congcheng Fan ◽  
Xi Yang ◽  
...  

Power conversion efficiency up to 11.7% was achieved with a CdSe nanocrystal acting as an electron transport/extraction layer for perovskite solar cells under standard AM1.5G conditions in air.


2016 ◽  
Vol 52 (52) ◽  
pp. 8099-8102 ◽  
Author(s):  
Haocheng Sun ◽  
Xiaomeng Hou ◽  
Qiulong Wei ◽  
Huawei Liu ◽  
Kecheng Yang ◽  
...  

A low-temperature solution-processed inorganic p-type contact material of vanadium oxide (VOx) is developed to fabricate planar-heterojunction perovskite solar cells.


2015 ◽  
Vol 3 (23) ◽  
pp. 12133-12138 ◽  
Author(s):  
Liu Qi Zhang ◽  
Xing Wang Zhang ◽  
Zhi Gang Yin ◽  
Qi Jiang ◽  
Xin Liu ◽  
...  

By combining the slow growth of the perovskite film and the introduction of a ZnO interlayer, highly efficient and stable perovskite solar cells with an efficiency of 16.8% were obtained.


2019 ◽  
Vol 26 (02) ◽  
pp. 1850137
Author(s):  
JINFENG WANG ◽  
BENGUANG ZHAO ◽  
LEI ZHU ◽  
JIAN SONG

A series of CH3NH3PbI[Formula: see text]BrxCly mixed-halide perovskite were fabricated as light harvesters for organic–inorganic planar heterojunction perovskite solar cells (PSCs). This paper aimed at investigating the morphology and structural properties of Br doped mixed-halide perovskites and the influence on the corresponding photovoltaic performances. We found that Br incorporation in an I/Cl-based structure dramatically improved the charge transport within the perovskite layer. The average efficiency of the planar device was 13.6% with a minimal standard deviation of [Formula: see text] 1.53% and best efficiency as high as 15.13% was achieved. Moreover, the device showed superior stability over 20 days with little degradation [Formula: see text]9% when stored under ambient conditions, indicating the outstanding performances of planar heterojunction solar cells based on this material. The results highlight the crucial role of the Br doping on the performance of the PSCs and pave the way for further progress on this field.


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