scholarly journals Polarization and Trap Characteristics Modification of Oil-Impregnated Paper Insulation by TiO2 Nanoparticles

Nanomaterials ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 174
Author(s):  
Meng Huang ◽  
Yupeng Ying ◽  
Bingliang Shan ◽  
Yuzhen Lv ◽  
Chengrong Li
Keyword(s):  
Activation Energy ◽  
Tio2 Nanoparticles ◽  
Low Frequency ◽  
Depolarization Current ◽  
Trap Energy ◽  
Hydrolysis Method ◽  
Performance Variation ◽  
Potential Decay ◽  
Paper Insulation ◽  
Thermally Stimulated Depolarization

Polarization and traps determine the electrical property of oil-paper insulation, but most attention has been paid to the modification of insulating oil with nanoparticles, so there are is little research about oil-impregnated paper, and the origin for performance variation is not understood yet. In this paper, spherical nanoscale titanium dioxide was prepared by the hydrolysis method and nanofluid-impregnated paper (NP) was fabricated through oil-impregnation. The frequency domain spectrum was measured for polarization analysis, and both thermally stimulated depolarization current (TSDC) and isothermal surface potential decay (ISPD) methods were used to reveal trap parameters. Results show that NP’s low frequency permittivity is much larger, and another peak appears in the spectrum even though the content of nanoparticles is very low. With the addition of TiO2 nanoparticles, TSDC’s amplitude and peak temperature increase, and the trap energy becomes shallower. TiO2 nanoparticles’ strong polarization and high activation energy contribute to NP’s larger interface polarization intensity and activation energy. Furthermore, because of oxygen vacancies, TiO2 nanoparticles offer a transfer site for holes and electrons to escape from deep traps; thus, the trap energy is greatly reduced.

On the Possibility to Observe a Compensation Effect around the Glass Transition Temperature

2006 ◽  
Vol 514-516 ◽  
pp. 1462-1466
Author(s):  
Rodica M. Neagu ◽  
José N. Marat-Mendes ◽  
Eugen R. Neagu
Keyword(s):  
Activation Energy ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Compensation Effect ◽  
Depolarization Current ◽  
Exponential Factor ◽  
Relaxation Parameters ◽  
Maximum Current ◽  
Thermally Stimulated Depolarization

Compensation has been reported for the relaxation parameters: the activation energy W and the pre-exponential factor τ0, determined from the Thermal Sampling of Thermally Stimulated Depolarization Current technique. Below the glass transition it is assumed that the relaxation time follows an Arrhenius equation. In the vicinity of glass transition temperature an experimental thermogram may be analyzed using the Vogel-Fulcher-Tamman-Hesse (VFTH) or the Williams- Landel -Ferry equation. In this article we use the VFTH relationship to study the compensation effect in the range of glass transition. For an elementary peak obtained by TS there is a relationship between the activation energy W, the temperature of the maximum current Tm, the VFTH temperature, the compensation temperature Tc and the compensation time τ c. We employ this relationship for a basic analysis of the compensation effect in the temperature range around Tg. By numerical simulations, and assuming parameters similar to those measured experimentally, we show that it is possible to observe a compensation point in some well defined conditions

Dielectric Relaxation Studies of Silver Nanoparticles dispersed Liquid Crystal

2015 ◽  
Vol 8 (3) ◽  
pp. 2176-2188 ◽  
Author(s):  
Keisham Nanao Singh
Keyword(s):  
Activation Energy ◽  
Silver Nanoparticles ◽  
Liquid Crystal ◽  
Dielectric Relaxation ◽  
Relaxation Process ◽  
Relaxation Times ◽  
Low Frequency ◽  
Bulk Liquid ◽  
Molecular Rearrangement ◽  
Relaxation Studies

This article reports on the Dielectric Relaxation Studies of two Liquid Crystalline compounds - 7O.4 and 7O.6 - doped with dodecanethiol capped Silver Nanoparticles. The liquid crystal molecules are aligned homeotropically using CTAB. The low frequency relaxation process occurring above 1 MHz is fitted to Cole-Cole formula using the software Dielectric Spectra fit. The effect of the Silver Nanoparticles on the molecular dipole dynamics are discussed in terms of the fitted relaxation times, Cole-Cole distribution parameter and activation energy. The study indicate a local molecular rearrangement of the liquid crystal molecules without affecting the order of the bulk liquid crystal molecules but these local molecules surrounding the Silver Nanoparticles do not contribute to the relaxation process in the studied frequency range. The observed effect on activation energy suggests a change in interaction between the nanoparticles/liquid crystal molecules.

The Storing Properties of Electric Energy in Bone

2011 ◽  
Vol 493-494 ◽  
pp. 170-174
Author(s):  
Rumi Hiratai ◽  
Miho Nakamura ◽  
Akiko Nagai ◽  
Kimihiro Yamashita
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Electric Fields ◽  
Electric Energy ◽  
Depolarization Current ◽  
Thermally Stimulated Depolarization Current ◽  
High Temperature And Pressure ◽  
Temperature And Pressure ◽  
Thermally Stimulated Depolarization ◽  
Inorganic Components

We have shown that hydroxyapatite (HA), which characteristics were similar to those of bone’s inorganic components, had polarization capability and was possible to accumulate electricity under high temperature and pressure. Then, we presumed that bones had polarization capability which enabled electrical storage and conducted the experiment to measure the polarization capability of bones using rabbit’s femurs. After preparing and polarizing bone samples using KOH treatment (koh), KOH and baking treatment (koh+bake) and decalcification treatment (decalcification) as well as the bone without any treatment (untreat), quantitative amounts of stored charge in samples were determined by thermally stimulated depolarization current (TSDC) measurement of these samples. Under the condition of 400 °C for 1 h with the electric fields of 5kV/cm, samples of koh, koh+bake, and untreat showed polarization capability. In addition, under the polarization condition of 37 °C for 1 hour with the electric fields of 5kV/cm, all samples showed polarization capability. Those findings can be summarized that bones have the polarization capability which enables electrical storage and polarization of bones is possible even under the low temperature condition, which was at 37 °C in our experiment, where polarization is impossible for HA.

Effect of Electrical Polarization on the Behavior of Bioactive Glass Containing MgO and B2O3 in SBF

2006 ◽  
Vol 309-311 ◽  
pp. 333-336
Author(s):  
Emiko Amaoka ◽  
Erik Vedel ◽  
Satoshi Nakamura ◽  
Yusuke Moriyoshi ◽  
Jukka I. Salonen ◽  
...  
Keyword(s):  
Calcium Phosphate ◽  
Simulated Body Fluid ◽  
Bioactive Glass ◽  
Body Fluid ◽  
Charged Surface ◽  
Depolarization Current ◽  
Electrical Polarization ◽  
Thermally Stimulated Depolarization Current ◽  
Thermally Stimulated Depolarization ◽  
Calcium Phosphate Precipitation

We investigated the electrical polarizability of MgO and B2O3 containing bioactive glass (MBG). The MBG material with good manufacturing properties but low bioactivity was electrically polarized at a high dc field. The electrical polarizability of MBG was evaluated by thermally stimulated depolarization current (TSDC) measurements and immersion in simulated body fluid (SBF). The early precipitation of calcium phosphate on the negatively charged surface of the treated MBG demonstrated the increased bioactivity of the material and confirmed its polarizability. It is suggested that the electrical interactions between the polarized MBG and ions in SBF promoted the formation of the calcium phosphate precipitation. Accordingly, the increased bioactivity of the MBG in SBF is suggested to demonstrate the conversion of MBG into electrovector ceramics by the polarization treatment.

Theory of the ferroelectric Mott-Hubbard phase in organic conductors

2002 ◽  
Vol 12 (9) ◽  
pp. 149-152
Author(s):  
S. Brazovskii
Keyword(s):  
Activation Energy ◽  
Phase Transitions ◽  
Low Frequency ◽  
Frequency Dispersion ◽  
Organic Conductors ◽  
The State ◽  
Charge Disproportionation ◽  
Subsequent Phase

Recently the ferroelectric FE anomaly (Nad, Monceau, et al.) followed by the charge disproportionation CD (Brown, et al) have been discovered in ($TMTTF)_2X$ compounds. A theory of the combined Mott-Hubbard state describes both effects by interference of the build-in nonequivalence of bonds and the spontaneous one of sites. The state gives rise to three types of solitons: $\pi -$ solitons (holons) are observed via the activation energy A in conductivity G; noninteger $\alpha -$ solitons provide the frequency dispersion of the FE response; combined spin-charge solitons determine $G(T)$ below subsequent phase transitions. The optical edge lies well below the conductivity gap 2A; the critical FE mode coexists with a combined electron-phonon resonance and a phonon antiresonance. The CD and the FE can exists hiddenly even in the Se subfamily giving rise to the unexplained yet low frequency optical peak, the enhanced pseudogap and traces of phonons activation.

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