scholarly journals Role of Phase-Dependent Dielectric Properties of Alumina Nanoparticles in Electromagnetic-Assisted Enhanced Oil Recovery

Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 1975 ◽  
Author(s):  
Muhammad Adil ◽  
Kean Chuan Lee ◽  
Hasnah Mohd Zaid ◽  
Takaaki Manaka

The utilization of metal-oxide nanoparticles in enhanced oil recovery (EOR) has generated considerable research interest to increase the oil recovery. Among these nanoparticles, alumina nanoparticles (Al2O3-NPs) have proved promising in improving the oil recovery mechanism due to their prominent thermal properties. However, more significantly, these nanoparticles, coupled with electromagnetic (EM) waves, can be polarized to reduce water/oil mobility ratio and create disturbances at the oil/nanofluid interface, so that oil can be released from the reservoir rock surfaces and travelled easily to the production well. Moreover, alumina exists in various transition phases (γ, δ, θ, κ, β, η, χ), providing not only different sizes and morphologies but phase-dependent dielectric behavior at the applied EM frequencies. In this research, the oil recovery mechanism under EM fields of varying frequencies was investigated, which involved parameters such as mobility ratio, interfacial tension (IFT) and wettability. The displacement tests were conducted in water-wet sandpacks at 95 °C, by employing crude oil from Tapis. Alumina nanofluids (Al2O3-NFs) of four different phases (α, κ, θ and γ) and particle sizes (25–94.3 nm) were prepared by dispersing 0.01 wt. % NPs in brine (3 wt. % NaCl) together with SDBS as a dispersant. Three sequential injection scenarios were performed in each flooding scheme: (i) preflushes brine as a secondary flooding, (ii) conventional nano/EM-assisted nanofluid flooding, and (iii) postflushes brine to flush NPs. Compared to conventional nanofluid flooding (3.03–11.46% original oil in place/OOIP) as incremental oil recovery, EM-assisted nanofluid flooding provided an increase in oil recovery by approximately 4.12–12.90% of OOIP for different phases of alumina. It was established from these results that the recovery from EM-assisted nanofluid flooding is itself dependent on frequency, which is associated with good dielectric behavior of NPs to formulate the oil recovery mechanism including (i) mobility ratio improvement due to an electrorheological (ER) effect, (ii) interfacial disturbances by the oil droplet deformation, and (iii) wettability alteration by increased surface-free energy.

Energies ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 2751 ◽  
Author(s):  
Sameer Al-Hajri ◽  
Syed Mahmood ◽  
Hesham Abdulelah ◽  
Saeed Akbari

Polymer flooding is an important enhanced oil recovery technology introduced in field projects since the late 1960s. The key to a successful polymer flood project depends upon proper estimation of polymer retention. The aims of this paper are twofold. First, to show the mechanism of polymer flooding and how this mechanism is affected by polymer retention. Based on the literature, the mobility ratio significantly increases as a result of the interactions between the injected polymer molecules and the reservoir rock. Secondly, to provide a better understanding of the polymer retention, we discussed polymer retention types, mechanisms, factors promoting or inhibiting polymer retention, methods and modeling techniques used for estimating polymer retention.


PLoS ONE ◽  
2020 ◽  
Vol 15 (12) ◽  
pp. e0244738
Author(s):  
Muhammad Adil ◽  
Keanchuan Lee ◽  
Hasnah Mohd Zaid ◽  
M. Fadhllullah A. Shukur ◽  
Takaaki Manaka

Utilization of metal-oxide nanoparticles (NPs) in enhanced oil recovery (EOR) has generated substantial recent research interest in this area. Among these NPs, zinc oxide nanoparticles (ZnO-NPs) have demonstrated promising results in improving oil recovery due to their prominent thermal properties. These nanoparticles can also be polarized by electromagnetic (EM) field, which offers a unique Nano-EOR approach called EM-assisted Nano-EOR. However, the impact of NPs concentrations on oil recovery mechanism under EM field has not been well established. For this purpose, ZnO nanofluids (ZnO-NFs) of two different particle sizes (55.7 and 117.1 nm) were formed by dispersing NPs between 0.01 wt.% to 0.1 wt.% in a basefluid of sodium dodecylbenzenesulfonate (SDBS) and NaCl to study their effect on oil recovery mechanism under the electromagnetic field. This mechanism involved parameters, including mobility ratio, interfacial tension (IFT) and wettability. The displacement tests were conducted in water-wet sandpacks at 95˚C, by employing crude oil from Tapis. Three tertiary recovery scenarios have been performed, including (i) SDBS surfactant flooding as a reference, (ii) ZnO-NFs flooding, and (iii) EM-assisted ZnO-NFs flooding. Compare with incremental oil recovery from surfactant flooding (2.1% original oil in place/OOIP), nanofluid flooding reaches up to 10.2% of OOIP at optimal 0.1 wt.% ZnO (55.7 nm). Meanwhile, EM-assisted nanofluid flooding at 0.1 wt.% ZnO provides a maximum oil recovery of 10.39% and 13.08% of OOIP under EM frequency of 18.8 and 167 MHz, respectively. By assessing the IFT/contact angle and mobility ratio, the optimal NPs concentration to achieve a favorable ER effect and interfacial disturbance is determined, correlated to smaller hydrodynamic-sized nanoparticles that cause strong electrostatic repulsion between particles.


2012 ◽  
Vol 1473 ◽  
Author(s):  
Ernesto Lopez-Chavez ◽  
Luis Silvestre Zamudio-Rivera ◽  
Jose Manuel Martinez-Magadan ◽  
Eduardo Buenrostro-Gonzalez ◽  
Raúl Hernández-Altamirano

ABSTRACTZwitterionic liquid (ZL) molecules are considered among the surfactant molecular species used in enhanced oil recovery (EOR). The surface activity of asphaltenes (ASP) is crucial for establishing reservoir rock wettability, which impacts enhanced oil recovery (EOR) process. The key to a successful EOR formulation is to carefully select the components that provide ultra-low interfacial tension (IFT) under reservoir conditions. Achieving ultra-low IFT greatly reduces capillary forces that trap oil. The objective of this work is the theoretical study of the influence of a class of germinal zwitterionic liquid on interfacial tension or changes on wettability of the oil-rock system under reservoir conditions. The ZL molecule used in this study was designed by Zamudio et al; while the asphaltene model was originally proposed by Buenrostro-González. Methods of molecular mechanics and dynamics were used in order to calculate interaction energies of all systems. The results indicate that the ZL molecule adheres more strongly to the limestone-rock than the asphaltene molecule does. In addition, our results suggest that the ion-pair formation is the dominant wettability alteration mechanism.


2017 ◽  
Vol 2017 ◽  
pp. 1-15 ◽  
Author(s):  
Muhammad Shahzad Kamal ◽  
Ahmad A. Adewunmi ◽  
Abdullah S. Sultan ◽  
Mohammed F. Al-Hamad ◽  
Umer Mehmood

Chemically enhanced oil recovery methods are utilized to increase the oil recovery by improving the mobility ratio, altering the wettability, and/or lowering the interfacial tension between water and oil. Surfactants and polymers have been used for this purpose for the last few decades. Recently, nanoparticles have attracted the attention due to their unique properties. A large number of nanoparticles have been investigated for enhanced oil recovery applications either alone or in combination with surfactants and/or polymers. This review discusses the various types of nanoparticles that have been utilized in enhanced oil recovery. The review highlights the impact of nanoparticles on wettability alteration, interfacial tension, and rheology. The review also covers the factors affecting the oil recovery using nanoparticles and current challenges in field implementation.


2021 ◽  
Author(s):  
Tinuola Udoh

Abstract In this paper, the enhanced oil recovery potential of the application of nanoparticles in Niger Delta water-wet reservoir rock was investigated. Core flooding experiments were conducted on the sandstone core samples at 25 °C with the applications of nanoparticles in secondary and tertiary injection modes. The oil production during flooding was used to evaluate the enhanced oil recovery potential of the nanoparticles in the reservoir rock. The results of the study showed that the application of nanoparticles in tertiary mode after the secondary formation brine flooding increased oil production by 16.19% OIIP. Also, a comparison between the oil recoveries from secondary formation brine and nanoparticles flooding showed that higher oil recovery of 81% OIIP was made with secondary nanoparticles flooding against 57% OIIP made with formation brine flooding. Finally, better oil recovery of 7.67% OIIP was achieved with secondary application of nanoparticles relative to the tertiary application of formation brine and nanoparticles flooding. The results of this study are significant for the design of the application of nanoparticles in Niger Delta reservoirs.


Author(s):  
Chun Huh ◽  
Hugh Daigle ◽  
Valentina Prigiobbe ◽  
Maša Prodanović

2020 ◽  
Vol 8 (4) ◽  
pp. 986-998 ◽  
Author(s):  
Wenhai Lei ◽  
Tong Liu ◽  
Chiyu Xie ◽  
Haien Yang ◽  
Tianjiang Wu ◽  
...  

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