scholarly journals Nonstoichiometric Cu0.6Ni0.4Co2O4 Nanowires as an Anode Material for High Performance Lithium Storage

Nanomaterials ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 191
Author(s):  
Junhao Li ◽  
Ningyi Jiang ◽  
Jinyun Liao ◽  
Yufa Feng ◽  
Quanbing Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Electrochemical Performance ◽  
Metal Oxides ◽  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
Anode Materials ◽  
High Performance ◽  
Electronic Conductivity ◽  
Specific Capacity ◽  
Lithium Ion

Transition metal oxide is one of the most promising anode materials for lithium-ion batteries. Generally, the electrochemical property of transition metal oxides can be improved by optimizing their element components and controlling their nano-architecture. Herein, we designed nonstoichiometric Cu0.6Ni0.4Co2O4 nanowires for high performance lithium-ion storage. It is found that the specific capacity of Cu0.6Ni0.4Co2O4 nanowires remain 880 mAh g−1 after 50 cycles, exhibiting much better electrochemical performance than CuCo2O4 and NiCo2O4. After experiencing a large current charge and discharge state, the discharge capacity of Cu0.6Ni0.4Co2O4 nanowires recovers to 780 mAh g−1 at 50 mA g−1, which is ca. 88% of the initial capacity. The high electrochemical performance of Cu0.6Ni0.4Co2O4 nanowires is related to their better electronic conductivity and synergistic effect of metals. This work may provide a new strategy for the design of multicomponent transition metal oxides as anode materials for lithium-ion batteries.

Facile synthesis of vanadyl acetate one-dimensional nanobelts toward a novel anode for lithium storage

2021 ◽  
Author(s):  
Ni Wen ◽  
Siyuan Chen ◽  
xiaolong Li ◽  
Ke Zhang ◽  
Jingjie Feng ◽  
...  
Keyword(s):  
Metal Oxides ◽  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
Anode Materials ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Facile Synthesis ◽  
Lithium Storage ◽  
One Dimensional ◽  
Theoretical Specific Capacity

Transition metal oxides (TMOs) are prospective anode materials for lithium-ion batteries (LIBs) owing to their high theoretical specific capacity. Whereas, the inherent low conductivity of TMOs restricts its application. Given...

Hierarchical bilayered hybrid nanostructural arrays of NiCo2O4 micro-urchins and nanowires as a free-standing electrode with high loading for high-performance lithium-ion batteries

Nanoscale ◽  
2017 ◽  
Vol 9 (39) ◽  
pp. 14979-14989 ◽  
Author(s):  
Yu Wang ◽  
Pengcheng Liu ◽  
Kongjun Zhu ◽  
Jing Wang ◽  
Jinsong Liu
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
High Performance ◽  
Lithium Ion ◽  
High Loading ◽  
Free Standing ◽  
Significant Research

Fabrication of free-standing binary transition metal oxides, especially NiCo2O4, has attracted significant research interests since these metal oxides are promising candidates for free-standing anodes of lithium-ion batteries (LIBs).

scholarly journals Selective Phosphorization Boosting High-Performance NiO/Ni2Co4P3 Microspheres as Anode Materials for Lithium Ion Batteries

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 24
Author(s):  
Ji Yan ◽  
Xin-Bo Chang ◽  
Xiao-Kai Ma ◽  
Heng Wang ◽  
Yong Zhang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Materials ◽  
High Performance ◽  
Electronic Conductivity ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Lithium Storage ◽  
Ion Storage ◽  
Storage Behavior ◽  
Storage Properties

Phosphorization of metal oxides/hydoxides to promote electronic conductivity as a promising strategy has attracted enormous attention for improving the electrochemical properties of anode material in lithium ion batteries. For this article, selective phosphorization from NiCo2O4 to NiO/Ni2Co4P3 microspheres was realized as an efficient route to enhance the electrochemical lithium storage properties of bimetal Ni-Co based anode materials. The results show that varying phosphorizaed reagent amount can significantly affect the transformation of crystalline structure from NiCo2O4 to intermediate NiO, hybrid NiO/Ni2Co4P3, and, finally, to Ni2Co4P3, during which alterated sphere morphology, shifted surface valance, and enhanced lithium-ion storage behavior are detected. The optimized phosphorization with 1:3 reagent mass ratio can maintain the spherical architecture, hold hybrid crystal structure, and improve the reversibly electrochemical lithium-ion storage properties. A specific capacity of 415 mAh g−1 is achieved at 100 mA g−1 specific current and maintains at 106 mAh g−1 when the specific current increases to 5000 mA g−1. Even after 200 cycles at 500 mA g−1, the optimized electrode still delivers 224 mAh g−1 of specific capacity, exhibiting desirable cycling stability. We believe that understanding of such selective phosphorization can further evoke a particular research enthusiasm for anode materials in lithium ion battery with high performances.

scholarly journals Crystal-seeds induced construction of ZnO–ZnFe2O4 micro-cubic composites as excellent anode materials for lithium ion battery

RSC Advances ◽  
2018 ◽  
Vol 8 (29) ◽  
pp. 16187-16192 ◽  
Author(s):  
Pei Pan ◽  
Ting Wang ◽  
Lihui Chen ◽  
Feng Wang ◽  
Xiong Yang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Electrochemical Performance ◽  
Metal Oxides ◽  
Band Gap ◽  
Transition Metal Oxides ◽  
Anode Materials ◽  
Lithium Ion ◽  
Band Gap Energy ◽  
Hetero Structure ◽  
Gap Energy

This work aims at designing a fine assembly of two different transition metal oxides with a distinct band-gap energy into a bi-component-active hetero-structure to improve electrochemical performance.

scholarly journals Nanostructured anode materials for lithium-ion batteries: principle, recent progress and future perspectives

2017 ◽  
Vol 5 (37) ◽  
pp. 19521-19540 ◽  
Author(s):  
Wen Qi ◽  
Joseph G. Shapter ◽  
Qian Wu ◽  
Ting Yin ◽  
Guo Gao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
Anode Materials ◽  
Recent Progress ◽  
Lithium Ion ◽  
Nanostructured Carbon ◽  
Future Perspectives

Recent progress in nanostructured carbon, alloys, transition metal oxides and silicon as anode materials for LIBs has been reviewed.

scholarly journals Plate-to-Layer Bi2MoO6/MXene-Heterostructured Anode for Lithium-Ion Batteries

2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Peng Zhang ◽  
Danjun Wang ◽  
Qizhen Zhu ◽  
Ning Sun ◽  
Feng Fu ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
Anode Materials ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Lithium Storage ◽  
Conductive Substrate ◽  
High Theoretical Capacity

Abstract Bi2MoO6 is a potentially promising anode material for lithium-ion batteries (LIBs) on account of its high theoretical capacity coupled with low desertion potential. Due to low conductivity and large volume expansion/contraction during charge/discharge cycling of Bi2MoO6, effective modification is indispensable to address these issues. In this study, a plate-to-layer Bi2MoO6/Ti3C2Tx (MXene) heterostructure is proposed by electrostatic assembling positive-charged Bi2MoO6 nanoplates on negative-charged MXene nanosheets. MXene nanosheets in the heterostructure act as a highly conductive substrate to load and anchor the Bi2MoO6 nanoplates, so as to improve electronic conductivity and structural stability. When the mass ratio of MXene is optimized to 30%, the Bi2MoO6/MXene heterostructure exhibits high specific capacities of 692 mAh g−1 at 100 mA g−1 after 200 cycles and 545.1 mAh g−1 with 99.6% coulombic efficiency at 1 A g−1 after 1000 cycles. The results provide not only a high-performance lithium storage material, but also an effective strategy that could address the intrinsic issues of various transition metal oxides by anchoring them on MXene nanosheets to form heterostructures and use as anode materials for LIBs.

scholarly journals The influence of different Si : C ratios on the electrochemical performance of silicon/carbon layered film anodes for lithium-ion batteries

RSC Advances ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 6660-6666 ◽  
Author(s):  
Jun Wang ◽  
Shengli Li ◽  
Yi Zhao ◽  
Juan Shi ◽  
Lili Lv ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Lithium Ions ◽  
High Specific Capacity ◽  
Silicon Carbon ◽  
Silicon Based

With a high specific capacity (4200 mA h g−1), silicon based materials have become the most promising anode materials in lithium-ions batteries.

Enhanced electrochemical performance of lithium ion batteries using Sb2S3 nanorods wrapped in graphene nanosheets as anode materials

Nanoscale ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 3159-3165 ◽  
Author(s):  
Yucheng Dong ◽  
Shiliu Yang ◽  
Zhenyu Zhang ◽  
Jong-Min Lee ◽  
Juan Antonio Zapien
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Materials ◽  
Graphene Nanosheets ◽  
Specific Capacity ◽  
Lithium Ion ◽  
Lithium Insertion ◽  
Insertion Reactions ◽  
Theoretical Specific Capacity ◽  
Enhanced Electrochemical Performance

Antimony sulfide can be used as a promising anode material for lithium ion batteries due to its high theoretical specific capacity derived from sequential conversion and alloying lithium insertion reactions.

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