scholarly journals Incorporation of Ions into Nanostructured Anodic Oxides—Mechanism and Functionalities

Molecules ◽  
2021 ◽  
Vol 26 (21) ◽  
pp. 6378
Author(s):  
Anna M. Brudzisz ◽  
Damian Giziński ◽  
Wojciech J. Stępniowski

Anodic oxidation of metals leads to the formation of ordered nanoporous or nanotubular oxide layers that contribute to numerous existing and emerging applications. However, there are still numerous fundamental aspects of anodizing that have to be well understood and require deeper understanding. Anodization of metals is accompanied by the inevitable phenomenon of anion incorporation, which is discussed in detail in this review. Additionally, the influence of anion incorporation into anodic alumina and its impact on various properties is elaborated. The literature reports on the impact of the incorporated electrolyte anions on photoluminescence, galvanoluminescence and refractive index of anodic alumina are analyzed. Additionally, the influence of the type and amount of the incorporated anions on the chemical properties of anodic alumina, based on the literature data, was also shown to be important. The role of fluoride anions in d-electronic metal anodizing is shown to be important in the formation of nanostructured morphology. Additionally, the impact of incorporated anionic species, such as ruthenites, and their influence on anodic oxides formation, such as titania, reveals how the phenomenon of anion incorporation can be beneficial.

2020 ◽  
Vol 32 ◽  
pp. 209-223
Author(s):  
Adelina Miteva ◽  
Valeria Stoyanova

This brief overview presents an attempt to systematize some of the available historical and recent data on the impact of zeolite science and engineering on the progress of various areas of Earth and Space development. The basic structural and chemical properties of natural and synthetic zeolites are presented. Valuable applications of the zeolites, such as catalysts, gas adsorbers and ion exchangers are also included. The most commonly used methods for the synthesis of zeolites from different materials are presented, as well as some Bulgarian developments for the reuse of waste materials to zeolites. The important role of zeolites as an indispensable material for improving the quality of soil, fuels, water, air, etc., required for the needs of orbiting space stations and spacecrafts has been confirmed by typical examples.


2013 ◽  
Vol 44 (5) ◽  
pp. 311-319 ◽  
Author(s):  
Marco Brambilla ◽  
David A. Butz

Two studies examined the impact of macrolevel symbolic threat on intergroup attitudes. In Study 1 (N = 71), participants exposed to a macrosymbolic threat (vs. nonsymbolic threat and neutral topic) reported less support toward social policies concerning gay men, an outgroup whose stereotypes implies a threat to values, but not toward welfare recipients, a social group whose stereotypes do not imply a threat to values. Study 2 (N = 78) showed that, whereas macrolevel symbolic threat led to less favorable attitudes toward gay men, macroeconomic threat led to less favorable attitudes toward Asians, an outgroup whose stereotypes imply an economic threat. These findings are discussed in terms of their implications for understanding the role of a general climate of threat in shaping intergroup attitudes.


2002 ◽  
Vol 41 (05) ◽  
pp. 208-213 ◽  
Author(s):  
L. M. Haslinghuis-Bajan ◽  
L. Hooft ◽  
A. van Lingen ◽  
M. van Tulder ◽  
W. Devillé ◽  
...  

SummaryAim: While FDG full ring PET (FRPET) has been gradually accepted in oncology, the role of the cheaper gamma camera based alternatives (GCPET) is less clear. Since technology is evolving rapidly, “tracker trials” would be most helpful to provide a first approximation of the relative merits of these alternatives. As difference in scanner sensitivity is the key variable, head-to-head comparison with FRPET is an attractive study design. This systematic review summarises such studies. Methods: Nine studies were identified until July 1, 2000. Two observers assessed the methodological quality (Cochrane criteria), and extracted data. Results: The studies comprised a variety of tumours and indications. The reported GC- and FRPET agreement for detection of malignant lesions ranged from 55 to 100%, but with methodological limitations (blinding, standardisation, limited patient spectrum). Mean lesion diameter was 2.9 cm (SD 1.8), with only about 20% <1.5 cm. The 3 studies with the highest quality reported concordances of 74-79%, for the studied lesion spectrum. Contrast at GCPET was lower than that of FRPET, contrast and detection agreement were positively related. Logistic regression analysis suggested that pre-test indicators might be used to predict FRPET-GCPET concordance. Conclusion: In spite of methodological limitations, “first generation” GCPET devices detected sufficient FRPET positive lesions to allow prospective evaluation in clinical situations where the impact of FRPET is not confined to detection of small lesions (<1.5 cm). The efficiency of head-to-head comparative studies would benefit from application in a clinically relevant patient spectrum, with proper blinding and standardisation of acquisition procedures.


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