scholarly journals On the Origins of Some Spectroscopic Properties of “Purple Iron” (the Tetraoxoferrate(VI) Ion) and Its Pourbaix Safe-Space

Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5266
Author(s):  
Philip C.W. Cheung ◽  
Daryl R. Williams ◽  
Jack Barrett ◽  
James Barker ◽  
Donald W. Kirk
Keyword(s):  
Inorganic Chemistry ◽  
Water Treatment ◽  
Raman Spectra ◽  
Rayleigh Scattering ◽  
Mossbauer Spectroscopy ◽  
Spectroscopic Properties ◽  
Safe Space ◽  
Infrared And Raman Spectra ◽  
Methods Of Analysis ◽  
Instrumental Methods

In this work, the authors attempt to interpret the visible, infrared and Raman spectra of ferrate(VI) by means of theoretical physical-inorganic chemistry and historical highlights in this field of interest. In addition, the sacrificial decomposition of ferrate(VI) during water treatment will also be discussed together with a brief mention of how Rayleigh scattering caused by the decomposition of FeVIO42− may render absorbance readings erroneous. This work is not a compendium of all the instrumental methods of analysis which have been deployed to identify ferrate(VI) or to study its plethora of reactions, but mention will be made of the relevant techniques (e.g., Mössbauer Spectroscopy amongst others) which support and advance this overall discourse at appropriate junctures, without undue elaboration on the foundational physics of these techniques.

The Vibrational Spectra of VPO5 Crystal Phases and Related Glasses

1977 ◽  
Vol 31 (3) ◽  
pp. 230-236 ◽  
Author(s):  
R. N. Bhargava ◽  
R. A. Condrate
Keyword(s):  
Raman Spectra ◽  
Infrared Spectra ◽  
Vibrational Spectra ◽  
Rayleigh Scattering ◽  
Physical Adsorption ◽  
Group Analysis ◽  
Phosphate Glasses ◽  
Infrared And Raman Spectra ◽  
Vanadium Phosphate ◽  
Space Groups

Infrared and Raman spectra were measured and interpreted for two crystalline VPO5 phases (α- and β-VPO5) and several related vanadium phosphate glasses. The spectral results for the crystalline phases were consistent with those predicted by factor group analysis using the previously determined space groups. Empirical band assignments were made for the observed bands on the basis of the bands observed earlier for related phosphate and oxyvanadium compounds. Also, the band assignments made for the infrared spectra of the glasses were consistent with the assignments for crystalline V2O5 and the two crystalline VPO5 phases. No Raman spectra were observed for the glasses because processes involving adsorption and Rayleigh scattering dominated over Raman scattering. The infrared spectra of vanadium phosphate glasses with high P2O5 concentrations possessed many features resembling those observed in the infrared spectra of α-VPO5, suggesting similarities in the short range order for the two materials. Analyses of the vibrational spectra of hydrated α-VPO5 samples suggests that the water molecules are adsorbed in the interlamellar spaces of the crystals, complexing to vanadium ions. Initial steps in the hydration of vanadium phosphate glasses apparently involve physical adsorption of water on their surfaces. No water adsorption could be detected for β-VPO5 under normal conditions from its infrared and Raman spectra.

Vibrational Spectra of the Layered Compound [(VO2)2(4,4-bipy)0.5(4,4′- Hbipy)(PO4)]·H2O

2003 ◽  
Vol 58 (5) ◽  
pp. 485-488 ◽  
Author(s):  
Enrique J Baran ◽  
Kwang-Hwa Lii
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Active Site ◽  
Spectroscopic Properties ◽  
Title Complex ◽  
Layered Compound ◽  
Infrared And Raman Spectra

The infrared and Raman spectra of the title complex were recorded and assignments for the VO+2 , PO3-4 and V-O and V-N skeletal vibrations are proposed. The results are of interest in relation to the vibrational-spectroscopic properties of the active site of vanadium haloperoxidases.

Comparative Analytical Study of Dhutturadi Taila prepared in two different media

2017 ◽  
Vol 2 (06) ◽  
Author(s):  
Bibin K. B.
Keyword(s):  
Physicochemical Parameters ◽  
Analytical Study ◽  
Analytical Techniques ◽  
Therapeutic Practice ◽  
Methods Of Analysis ◽  
Instrumental Methods ◽  
Existing Result

Background: Sneha Kalpana is one among the several highly established Kalpana of Ayurvedic system of medicine. Many types of Taila Kalpana are mentioned in Ayurvedic classics and used effectively in therapeutic practice. Tila Taila is the most commonly using Taila. However Narikelataila, Erandataila, Sarshapataila, etc, are also used in special conditions. It is interesting to note that certain preparations are available in the market based on both TilaTaila and Narikela Taila. This is an attempt to comparatively evaluate the formulation Dhutturadi Taila prepared in Tila Taila and Narikela Taila as the bases. Dhutturadi Taila mentioned in Sahasrayogam is taken for the present study. Objectives: To comparatively analyse Dhutturadi Taila samples with classical and advanced analytical techniques. Materials and Methods: Dhutturadi Taila was prepared using two media i.e. Narikela Taila and Tila Taila. Both Taila samples were comparatively analysed with suitable physicochemical parameters and advanced instrumental methods of analysis. Conclusion: As per the existing result it seems that more amount of marker components are extracted into Tila Taila medium when compared with Narikela Taila.

Vibration spectra of sulphur tetranitride

1981 ◽  
Vol 46 (11) ◽  
pp. 2613-2619 ◽  
Author(s):  
Jiří Toužín
Keyword(s):  
Solid State ◽  
Raman Spectra ◽  
Normal Coordinate Analysis ◽  
Infrared And Raman Spectra ◽  
Normal Coordinate ◽  
Vibration Spectra

Available data on infrared and Raman spectra of S4N4 in solid state and solutions have been verified and completed. On the basis of normal coordinate analysis an attempt has been made to define with more precision the interpretation of vibration spectra of this compound given in earlier reports.

Vibrational spectra of aquadioxotetra; peroxodivanadates(V) M2[V2O2(O2)4(H2O)]·xH2O (M = N(CH3)4, Cs)

1990 ◽  
Vol 55 (6) ◽  
pp. 1485-1490 ◽  
Author(s):  
Peter Schwendt ◽  
Milan Sýkora
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Normal Coordinate Analysis ◽  
Force Constants ◽  
Infrared And Raman Spectra ◽  
Empirical Correlations ◽  
Normal Coordinate ◽  
Bond Lengths ◽  
Stretching Vibrations

The infrared and Raman spectra of M2[V2O2(O2)4(H2O)]·xH2O and M2[V2O2(O2)4(D2O)]·xD2O (M = N(CH3)4, Cs) were measured. In the region of the vanadium-oxygen stretching vibrations, the spectra were interpreted based on normal coordinate analysis, employing empirical correlations between the bond lengths and force constants.

Infrared and Raman Spectra, conformations,ab initio calculations and spectral assignments of 1,3-disilabutane (SiH3CH2SiH2CH3)

2007 ◽  
Vol 38 (9) ◽  
pp. 1159-1173 ◽  
Author(s):  
Gamil A. Guirgis ◽  
Paul M. Mazzone ◽  
Daniel N. Pasko ◽  
Peter Klaeboe ◽  
Anne Horn ◽  
...  
Keyword(s):  
Ab Initio Calculations ◽  
Ab Initio ◽  
Raman Spectra ◽  
Infrared And Raman Spectra
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