scholarly journals A Review of Characteristics of Bio-Oils and Their Utilization as Additives of Asphalts

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 5049
Author(s):  
Ran Zhang ◽  
Zhanping You ◽  
Jie Ji ◽  
Qingwen Shi ◽  
Zhi Suo
Keyword(s):  
Performance Optimization ◽  
Negative Impact ◽  
Chemical Properties ◽  
Optimization Methods ◽  
Economic Benefits ◽  
Asphalt Binders ◽  
Waste Biomass ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Bio Oil

Transforming waste biomass materials into bio-oils in order to partially substitute petroleum asphalt can reduce environmental pollution and fossil energy consumption and has economic benefits. The characteristics of bio-oils and their utilization as additives of asphalts are the focus of this review. First, physicochemical properties of various bio-oils are characterized. Then, conventional, rheological, and chemical properties of bio-oil modified asphalt binders are synthetically reviewed, as well as road performance of bio-oil modified asphalt mixtures. Finally, performance optimization is discussed for bio-asphalt binders and mixtures. This review indicates that bio-oils are highly complex materials that contain various compounds. Moreover, bio-oils are source-depending materials for which its properties vary with different sources. Most bio-oils have a favorable stimulus upon the low temperature performance of asphalt binders and mixtures but exhibit a negative impact on their high-temperature performance. Moreover, a large amount of oxygen element, oxygen-comprising functional groups, and light components in plant-based bio-oils result in higher sensitivity to ageing of bio-oil modified asphalts. In order to increase the performance of bio-asphalts, most research has been limited to adding additive agents to bio-asphalts; therefore, more reasonable optimization methods need to be proposed. Furthermore, upcoming exploration is also needed to identify reasonable evaluation indicators of bio-oils, modification mechanisms of bio-asphalts, and long-term performance tracking in field applications of bio-asphalts during pavement service life.

scholarly journals Evaluation of Low- and Intermediate-Temperature Performance of Bio Oil-Modified Asphalt Binders

2021 ◽  
Vol 13 (7) ◽  
pp. 4039
Author(s):  
Sara A. Alattieh ◽  
Ghazi G. Al-Khateeb ◽  
Waleed Zeiada
Keyword(s):  
Low Temperature ◽  
Asphalt Binder ◽  
Fatigue Cracking ◽  
Asphalt Binders ◽  
Tensile Stresses ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Bio Oil ◽  
Low Temperature Cracking ◽  
Low Temperature Performance

Fatigue cracking and low-temperature cracking are two major distresses that occur in asphalt pavements. Fatigue cracking is a load-associated distress caused by the tensile stresses at the bottom/top of the asphalt concrete (AC) layer due to repeated traffic loading. On the other hand, low-temperature cracking occurs when tensile stresses built up with in the AC layer at low temperatures exceed the tensile strength of that layer. In this study, the performance of date seeds oil bio-modified asphalt binders (DSO-BMB) is evaluated against fatigue and low-temperature cracking. The DSO-BMBs are prepared using volume ratios of 1.5, 2.5, 3.5, 4.5, and 5.5% date seeds oil-to-asphalt binder. The base asphalt binder used in the study is a 60/70-penetration grade with a Superpave performance grade (PG) of PG 64–16. The dynamic shear rheometer (DSR) standard test was used to assess the fatigue performance of the bio-modified binders (BMBs), while the bending beam rheometer (BBR) test was used to test the BMBs for low-temperature performance. In addition, the DSR linear amplitude sweep (LAS) test was used to evaluate the fatigue tolerance behavior of the DSO-BMBs. The analysis and results of the study showed that the bio-oil enhanced the low-temperature performance. The low PG grade improved from −16 °C for the control asphalt binder to −28 °C for the BMB. Additionally, the fatigue resistance of the BMBs was improved as illustrated by the damage–characteristic curves of the modified asphalt binders from the visco-elastic continuum damage (VECD) analysis and the increase in the number of cycles to fatigue failure (Nf).

The Rejuvenating and Aging Performances of Aged SBS Modified Asphalt Treated by Different Rejuvenator Sealer Materials

2013 ◽  
Vol 753-755 ◽  
pp. 734-740 ◽  
Author(s):  
Li Wan ◽  
Shao Peng Wu ◽  
Min Lei ◽  
Kim Jenkins
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Economic Benefits ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Low Performance ◽  
Aged Binder ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

Currently, rejuvenator seal which is one of the preventive maintenance methods is more widely used due to its economic benefits and convenience. This paper described the chemical and rheological evaluation of the aged styrene butadiene styrene modified asphalt (ASMA) treated by two rejuvenator sealer materials (RSMs). First the ASMA was rejuvenated by mixing with the RSMs. Then the ASMA and two rejuvenated binders were re-aged by 10h PAV test. At last, the new binder, ASMA, rejuvenated ASMAs, re-aged binders were tested by Dynamic shear rheometer (DSR) and Fourier Transform Infrared Spectroscopy (FTIR). The results showed that the first aging of the new binder had a significant decrease of the low temperature performance and slight improvement of the high temperature performance. In addition, the high temperature performance increased obviously after 10h PAV test. Two RSMs could significantly soften the aged binder due to increase of maltene content existing in the RSMs, and the rejuvenated binder exhibited a better low performance after the 10h PAV test. However they cannot restore the low temperature completely because that RSMs cannot remedy the degradation of SBS modifier and remove the carbonyl produced in the aging progress.

scholarly journals Laboratory Investigation of Carbon Black/Bio-Oil Composite Modified Asphalt

Materials ◽  
2021 ◽  
Vol 14 (17) ◽  
pp. 4910
Author(s):  
Ping Zhang ◽  
Lan Ouyang ◽  
Lvzhen Yang ◽  
Yi Yang ◽  
Guofeng Lu ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Carbon Black ◽  
Influencing Factors ◽  
Asphalt Mixture ◽  
Asphalt Mixtures ◽  
Test Results ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Bio Oil

As environmentally friendly materials, carbon black and bio-oil can be used as modifiers to effectively enhance the poor high-temperature and low-temperature performance of base asphalt and its mixture. Different carbon black and bio-oil contents and shear time were selected as the test influencing factors in this work. Based on the Box–Behnken design (BBD), carbon black/bio-oil composite modified asphalt was prepared to perform the softening point, penetration, multiple stress creep and recovery (MSCR), and bending beam rheometer (BBR) tests. The response surface method (RSM) was used to analyze the test results. In addition, the base asphalt mixtures and the optimal performance carbon black/bio-oil composite modified asphalt mixtures were formed for rutting and low-temperature splitting tests. The results show that incorporating carbon black can enhance the asphalt’s high-temperature performance by the test results of irrecoverable creep compliance (Jnr) and strain recovery rate (R). By contrast, the stiffness modulus (S) and creep rate (M) test results show that bio-oil can enhance the asphalt’s low-temperature performance. The quadratic function models between the performance indicators of carbon black/bio-oil composite modified asphalt and the test influencing factors were established based on the RSM. The optimal performance modified asphalt mixture’s carbon black and bio-oil content was 15.05% and 9.631%, and the shear time was 62.667 min. It was revealed that the high-temperature stability and low-temperature crack resistance of the carbon black/bio-oil composite modified asphalt mixture were better than that of the base asphalt mixture because of its higher dynamic stability (DS) and toughness. Therefore, carbon black/bio-oil composite modified asphalt mixture can be used as a new type of choice for road construction materials, which is in line with green development.

scholarly journals Effect of Recycled Shell Waste as a Modifier on the High- and Low-Temperature Rheological Properties of Asphalt

2021 ◽  
Vol 13 (18) ◽  
pp. 10271
Author(s):  
Yuchen Guo ◽  
Xuancang Wang ◽  
Guanyu Ji ◽  
Yi Zhang ◽  
Hao Su ◽  
...  
Keyword(s):  
High Temperature ◽  
Low Temperature ◽  
Rheological Properties ◽  
Low Temperatures ◽  
High Speed ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance

The deteriorating ecological environment and the concept of sustainable development have highlighted the importance of waste reuse. This article investigates the performance changes resulting from the incorporation of shellac into asphalt binders. Seashell powder-modified asphalt was prepared with 5%, 10%, and 15% admixture using the high-speed shear method. The microstructure of the seashell powder was observed by scanning electron microscope test (SEM); the physical-phase analysis of the seashell powder was carried out using an X-ray diffraction (XRD) test; the surface characteristics and pore structure of shellac were analyzed by the specific surface area Brunauer-Emmett-Teller (BET) test; and Fourier infrared spectroscopy (FTIR) qualitatively analyzed the composition and changes of functional groups of seashell powder-modified asphalt. The conventional performance index of seashell powder asphalt was analyzed by penetration, softening point, and ductility (5 °C) tests; the effect of seashell powder on asphalt binder was studied using a dynamic shear rheometer (DSR) and bending beam rheometer (BBR) at high and low temperatures, respectively. The results indicate the following: seashell powder is a coarse, porous, and angular CaCO3 bio-material; seashell powder and the asphalt binder represent a stable physical mixture of modified properties; seashell powder improves the consistency, hardness, and high-temperature performance of the asphalt binder but weakens the low-temperature performance of it; seashell powder enhances the elasticity, recovery performance, and permanent deformation resistance of asphalt binders and improves high-temperature rheological properties; finally, seashell powder has a minimal effect on the crack resistance of asphalt binders at very low temperatures. In summary, the use of waste seashells for recycling as bio-modifiers for asphalt binders is a practical approach.

scholarly journals High-Temperature Performance of Asphalt Mixtures: Preliminary Analysis for the Standard Technical Index Based on Gray Relational Analysis Method

2020 ◽  
Vol 2020 ◽  
pp. 1-13
Author(s):  
Jian Xu ◽  
Yan Gong ◽  
Li-Biao Chen ◽  
Tao Ma ◽  
Jun-Cheng Zeng ◽  
...  
Keyword(s):  
Performance Evaluation ◽  
High Temperature ◽  
Asphalt Mixture ◽  
Asphalt Mixtures ◽  
Asphalt Binders ◽  
Gray Relational Analysis ◽  
Low Grade ◽  
Modified Asphalt ◽  
Relational Analysis ◽  
Temperature Performance

Aiming to evaluate the high-temperature performance of asphalt binders and asphalt mixtures and to investigate the reliability of the standard technical indexes to evaluate the performance of the asphalt, six typically used asphalt types were employed in this study. The standard high-temperature rheological test, the multiple stress creep recovery (MSCR) test, and the zero-shear viscosity (ZSV) test were employed to characterize the high-temperature performance and non-Newtonian fluid properties of the asphalt. Meanwhile, the high-temperature performance of the asphalt mixture was evaluated through the rutting tests based on the mixture design of AC-13. In general, the modified asphalt performed better than the unmodified asphalt according to the high-temperature rheological properties tests. The ranking of the six kinds of asphalt was confirmed to be different in various laboratory tests. The test results of the asphalt binders showed that the Tafpack Super- (TPS-) modified asphalt performed best in the MSCR and ZSV tests, while the low-grade asphalt PEN20 had the best technical indexes in the dynamic shear rheometer (DSR) test. Besides, the relation between the asphalt and the asphalt mixture was analyzed by gray relational analysis (GRA) method. The present rutting indicator G ∗ / sin   δ  and  G ∗ / 1 − sin   δ ⋅   tan   δ − 1 for evaluating the asphalt mixtures’ high-temperature performance might no longer be suitable. The Cross/Williamson model was the most suitable for calculating and fitting the ZSV, which could be used as the key indicator of the high-temperature performance evaluation of the asphalt. This work lays a foundation for the further study of the high-temperature performance evaluation of asphalt binders.

Evaluation of the effect of bio-oil on the high-temperature performance of rubber modified asphalt

2018 ◽  
Vol 191 ◽  
pp. 692-701 ◽  
Author(s):  
Yong Lei ◽  
Hainian Wang ◽  
Ellie H. Fini ◽  
Zhanping You ◽  
Xu Yang ◽  
...  
Keyword(s):  
High Temperature ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Bio Oil

Experimental Study on Polyphosphoric Acid (PPA) Modified Asphalt Binders

2010 ◽  
Vol 152-153 ◽  
pp. 288-294 ◽  
Author(s):  
Wei Dong Cao ◽  
Shu Tang Liu ◽  
Hong Lu Mao
Keyword(s):  
Low Temperature ◽  
Softening Point ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Modified Asphalt ◽  
Temperature Performance ◽  
Point Test ◽  
Low Temperature Performance ◽  
Four Levels ◽  
Temperature Susceptibility

Polyphosphric acid (PPA) modified asphalt binders were produced in the laboratory using one base asphalt and four levels of PPA contents (0.6%, 1.0%, 1.5% and 2.0% by weight of base asphalt). Penetration test, softening point test, rotation viscosity test, creep test with bending beam rheometer (BBR) and four components test were carried out to study the performance of PPA modified asphalt binders and possible modification mechanism. The results indicate that the high-temperature performance of PPA modified asphalt binders are obviously improved and temperature susceptibility are decreased, but the low-temperature performance slightly decline compared with base asphalt. The PPA content has a very significant effect on softening point whereas it has no significant influence on low-temperature performance according to variance analysis (ANOVA). Finally, four components test reveals that the primary modification mechanism of PPA is the change of chemical composition of asphalt binder.

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