scholarly journals Physico-Chemical Characterization and Antimicrobial Properties of Hybrid Film Based on Saponite and Phloxine B

Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 325
Author(s):  
Nitin Chandra teja Dadi ◽  
Matúš Dohál ◽  
Veronika Medvecká ◽  
Juraj Bujdák ◽  
Kamila Koči ◽  
...  

This research was aimed at the preparation of a hybrid film based on a layered silicate saponite (Sap) with the immobilized photosensitizer phloxine B (PhB). Sap was selected because of its high cation exchange capacity, ability to exfoliate into nanolayers, and to modify different surfaces. The X-ray diffraction of the films confirmed the intercalation of both the surfactant and PhB molecules in the Sap film. The photosensitizer retained its photoactivity in the hybrid films, as shown by fluorescence spectra measurements. The water contact angles and the measurement of surface free energy demonstrated the hydrophilic nature of the hybrid films. Antimicrobial effectiveness, assessed by the photodynamic inactivation on hybrid films, was tested against a standard strain and against methicillin-resistant bacteria of Staphylococcus aureus (MRSA). One group of samples was irradiated (green LED light; 2.5 h) and compared to nonirradiated ones. S. aureus strains manifested a reduction in growth from 1-log10 to over 3-log10 compared to the control samples with Sap only, and defects in S. aureus cells were proven by scanning electron microscopy. The results proved the optimal photo-physical properties and anti-MRSA potential of this newly designed hybrid system that reflects recent progress in the modification of surfaces for various medical applications.

MRS Advances ◽  
2017 ◽  
Vol 2 (49) ◽  
pp. 2689-2694
Author(s):  
Karla A. Gaspar-Ovalle ◽  
Juan V. Cauich-Rodriguez ◽  
Armando Encinas

ABSTRACTNanofibrous mats of poly ε-caprolactone (PCL) were fabricated by electrospinning. The nanofiber structures were investigated and characterized by scanning electron microscope, differential scanning calorimetry, thermogravimetric analysis, dynamic mechanical analysis, static water-contact-angle analysis and mechanical properties. The results showed that the nanofibrous PCL is an ideal biopolymer for cell adhesion, owing to its biocompatibility, biodegradability, structural stability and mechanical properties. Differential scanning calorimetry results showed that the fibrous structure of PCL does not alter its crystallinity. Studies of the mechanical properties, wettability and degradability showed that the structure of the electrospun PCL improved the tensile modulus, tensile strength, wettability and biodegradability of the nanotemplates. To evaluate the nanofibrous structure of PCL on cell adhesion, osteoblasts cells were seeded on these templates. The results showed that both adhesion and proliferation of the cells is viable on these electrospun PCL membranes. Thus electrospinning is a relatively inexpensive and scalable manufacturing technique for submicron to nanometer diameter fibers, which can be of interest in the commodity industry.


2011 ◽  
Vol 65 (4) ◽  
pp. 381-387 ◽  
Author(s):  
Marjan Randjelovic ◽  
Milovan Purenovic ◽  
Aleksandra Zarubica ◽  
Igor Mladenovic ◽  
Jelena Purenovic ◽  
...  

Bentonite is mainly composed of clay minerals from smectite group, therefore it has a well developed and chemically active surface area and high cation exchange capacity. Moreover, an interlayer space of smectite has unusual hydration properties, which manifest as swelling of bentonite in water. These properties make bentonite as a commonly used raw material in chemistry and industry, and it is very important in environmental protection and water treatment as an effective sorbent of heavy metals. The results of X-ray diffraction, a cationic exchange capacity, specific surface area, acid-base properties of the surface and the swelling index showed that the bentonite sample contains mostly montmorillonite. The aim of this study was to test the efficacy of bentonite in the removal of Mn2+ from aqueous systems. The experimental results of Mn2+ adsorption on the bentonite were interpreted by Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherms. The adsorption isotherm studies indicate that the adsorption of Mn2+ follows Langmuir isotherm very well. Theoretical monolayer saturation capacity according to Langmuir model was 12.41 mg/g. The removal of Mn2+ is achieved by ion exchange mechanism with naturally occurring cations in bentonite, as well as by forming the inner- and outer-sphere complexes with bentonite surface.


2018 ◽  
Vol 20 ◽  
pp. 121-148 ◽  
Author(s):  
K. Jacinth Mispa ◽  
K. Anusiya ◽  
P. Subramaniam ◽  
R. Murugesan

Polyaniline-Zr(IV) tungstovanadate and Polyaniline-Zirconium oxide nanocomposite ion -exchangers were synthesized and physico-chemical characterization done by FT-IR-UV spectral studies, XRD, SEM and TGA. These composites are having high mechanical strength, good electrical conductivity and stability than their individual components. The organic polymeric component of the composites provides mechanical as well as chemical stability whereas the inorganic component supports the ion-exchange behavior and thermal stability. Both the inorganic and organic parts are jointly responsible for their improved electrical conductivity. They have more promising ion exchange capacity towards alkali metal halides and have selective adsorption towards Pb(II) ion and these can be used as powerful candidates for water softening


2020 ◽  
Vol 45 (1) ◽  
pp. 7771-7782
Author(s):  
AKEDRIN Tetchi Nicaise ◽  
AKOTTO Odi Faustin ◽  
COULIBALY Kiyinlma ◽  
COULIBALY Siendou ◽  
AKE Sévérin

En Côte d’Ivoire, la pratique des cultures continues ont entrainé la pauvreté des sols en éléments nutritifs. Pour y remédier, des espèces biofertilisantes en occurrence des légumineuses subligneuses susceptibles d’influer sur la disponibilité des éléments nutritifs du sol sont plantées dans les jachères pour la restauration de la fertilité. Cette étude sur le recensement et les caractérisations physicochimiques du sol et des légumineuses utilisées comme biofertilisants dans les jachères a été conduite à Daloa. La caractérisation chimique de ces végétaux réalisée sur la biomasse racinaire fraîche séchée au four à 65 ° C pendant 72 heures puis broyée et tamisée à une taille de 0,5 mm, a porté sur les compositions totales en N, P, K, Ca, Mg, C. Quant à la caractérisation du sol prélevé à 0-20 cm de profondeur, le pH, la taille des particules, l'azote total, le carbone organique, la capacité d'échange de cations, le P disponible et le K ont été analysés. Les prospections réalisées dans ces jachères ont permis de recenser six légumineuses comme culture principale. Ces légumineuses sont majoritairement lianescentes (50 %) contre 33 % des herbacées et 17 % d’arbustes. Les caractéristiques chimiques des racines ont montré une différence de variation de l’azote du témoin (13 g kg-1) à Mimosa invisa (28 g kg-1). Les concentrations en N, P, K ont été maximales chez toutes les espèces à l’exception de Mimosa invisa et Crotalaria retusa. Cependant, chez Mimosa invisa , les fortes concentrations de CEC (13,8 cmolc kg-1) et de C (27 g kg-1) ont été enregistrées. Les concentrations de phosphores (3,9 g kg-1) et de potassiums (53 g kg-1 de K) sont maximales respectivement chez Crotalaria goreensis et Crotalaria retusa. L’usage de ces légumineuses semble indispensable à la reconstitution de l’horizon humifère donc susceptible de restaurer la fertilité du sol et d’influencer la croissance des cultures non fixatrice d’azote. Akedrin et al., 2020 Journal of Animal & Plant Sciences (J.Anim.Plant Sci. ISSN 2071-7024) Vol.45 (1): 7771-7782 https://doi.org/10.35759/JAnmPlSci.v45-1.2 7772 Monograph of subligneous legumes used for the biofertilization of improved fallow soils in Daloa (Côte d'Ivoire). ABSTRACT In Côte d'Ivoire, the practice of continuous cultivation has resulted in poor nutrient soils. To remedy this, biofertilizing species in the form of subligneous legumes likely to influence the availability of soil nutrients are planted in fallows to restore fertility. This study on the inventory and the physico-chemical characterization of the legume species used as biofertilizers in fallows was conducted in Daloa. The chemical characterization of these plants was carried out from fresh root biomass dried in an oven at 65 ° C for 72 hours then crushed and sieved to a size of 0.5 mm. The analyses related to the total compositions in N, P, K, Ca, Mg, and C. As for the characterization of the soil sampled at 0-20 cm depth, the pH, the size of the particles, Total nitrogen, the organic carbon, cation exchange capacity, available P and K were analyzed. Surveys carried out in these fallows have identified six legumes as the main crop. These legumes are mostly creeping (50%) compared to herbaceous (33%) and shrubs (17%). The chemical characteristics of the roots showed a difference in the variation of nitrogen from the control (13 g kg-1) to Mimosa invisa (28 g kg-1). Concentrations of N, P, and K were highest in all species except Mimosa invisa and Crotalaria retusa. However, in Mimosa invisa, high concentrations of CEC (13.8 cmolc kg-1) and C (27 g kg-1) were recorded. Similarly, the concentrations of phosphorus (3.9 g kg-1) and potassium (53 g kg-1 K) are maximum in Crotalaria goreensis and Crotalaria retusa respectively. The use of these legumes seems essential to the reconstruction of the humiferous horizon, therefore likely to restore soil fertility and influence the growth of crops that do not fix nitrogen.


Alergologia ◽  
2020 ◽  
Vol 1 (4) ◽  
pp. 7
Author(s):  
Mariana Vieru ◽  
Florin-Dan Popescu ◽  
Laura Haidar ◽  
Carmen Bunu-Panaitescu

2010 ◽  
Vol 35 (5) ◽  
pp. 261-267 ◽  
Author(s):  
Wissemn Gallala ◽  
Mohamed Essghaier Gaied ◽  
Borhen Kchaou

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