scholarly journals Ammonium Phosphate as Inhibitor to Mitigate the Corrosion of Steel Rebar in Chloride Contaminated Concrete Pore Solution

Molecules ◽  
2020 ◽  
Vol 25 (17) ◽  
pp. 3785
Author(s):  
Soumen Mandal ◽  
Jitendra Kumar Singh ◽  
Dong-Eun Lee ◽  
Taejoon Park
Keyword(s):  
Passive Film ◽  
Ammonium Phosphate ◽  
Corrosion Current ◽  
Iron Phosphate ◽  
Nacl Solution ◽  
Steel Rebar ◽  
Prolonged Duration ◽  
Corrosion Inhibition Efficiency ◽  
Corrosion Of Steel ◽  
Steel Rebars

In the present study, different amounts, i.e., 1–3 v/v% of 1 M ammonium phosphate monobasic, were used as an eco-friendly corrosion inhibitor to mitigate the corrosion of steel rebar exposed to simulated concrete pore (SCP) + 3.5 wt% NaCl solution at a prolonged duration. Potentiodynamic polarization results show that as the amount of inhibitor is increased, the corrosion resistance of steel rebar is increased. The steel rebar exposed to 3% inhibitor-containing SCP + 3.5 wt% NaCl solution exhibited nobler corrosion potential (Ecorr), the lowest corrosion current density (icorr), and 97.62% corrosion inhibition efficiency after 1 h of exposure. The steel rebars exposed to 3% inhibitor-containing SCP + 3.5 wt% NaCl solution revealed higher polarization resistance (Rp) and film resistance (Ro) with exposure periods compared to other samples owing to the formation of passive film. The scanning electron microscopy (SEM) of steel rebar exposed to 3% inhibitor-containing SCP + 3.5 wt% NaCl solution showed homogenous and uniform dendritic passive film which covers all over the surface, whereas, bare, i.e., SCP + 3.5 wt% NaCl solution exposed samples exhibited pitting and irregular morphology. Raman spectroscopy results confirm the formation of goethite (α-FeOOH), maghemite (γ-Fe2O3), and iron phosphate (FePO4) as a passive film onto the steel rebar surface exposed to 3% inhibitor-containing SCP + 3.5 wt% NaCl solution. These phases are responsible for the corrosion mitigation of steel rebar which are very protective, adherent, and sparingly soluble.

scholarly journals Effect of Phosphate-Based Inhibitor on Corrosion Kinetics and Mechanism for Formation of Passive Film onto the Steel Rebar in Chloride-Containing Pore Solution

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3642
Author(s):  
Soumen Mandal ◽  
Jitendra Kumar Singh ◽  
Dong-Eun Lee ◽  
Taejoon Park
Keyword(s):  
Oxide Film ◽  
Photoelectron Spectroscopy ◽  
Electrochemical Impedance ◽  
Ammonium Phosphate ◽  
Iron Phosphate ◽  
Nacl Solution ◽  
Steel Rebar ◽  
Corrosion Kinetics ◽  
Corrosion Of Steel ◽  
Passive Oxide Film

In the present study, different contents, i.e., 1–3% of 0.5 M ammonium phosphate mono basic (APMB), were used as corrosion inhibitor to reduce the corrosion of steel rebar. Electrochemical impedance spectroscopy (EIS) results showed that up to 24 h of exposure, polarization resistance (Rp) and passive/oxide film resistance (Ro) gradually decreased in simulated concrete pore (SCP) + 3.5 wt.% NaCl solution owing to the reduction in pH of the solution. The steel rebar exposed in 2% inhibitor containing SCP + 3.5 wt.% NaCl solution exhibited 90% inhibition efficiency after 1 h of exposure. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy confirmed the formation of thermodynamically very stable and sparingly soluble goethite (α-FeOOH), maghemite (γ-Fe2O3), and iron phosphate (FePO4) as passive/oxide film onto the steel rebar surface exposed to 2% inhibitor containing SCP + 3.5 wt.% NaCl solution.

Corrosion Behavior of Zr53.5Cu26.5Ni5Al12Ag3 Bulk Amorphous Alloy in 3.5% NaCl Solution

2011 ◽  
Vol 299-300 ◽  
pp. 427-431
Author(s):  
Yun Li ◽  
Shi Zhi Shang ◽  
Ming Cheng ◽  
Liang Xu ◽  
Shi Hong Zhang
Keyword(s):  
Corrosion Resistance ◽  
Amorphous Alloy ◽  
Passive Film ◽  
Corrosion Behavior ◽  
Electrochemical Impedance ◽  
Corrosion Current ◽  
Bulk Amorphous Alloy ◽  
Nacl Solution ◽  
Current Densities ◽  
Resistance Decrease

The corrosion behavior of Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy in 3.5% NaCl solution was investigated by using potentiodynamic polarization experiments and electrochemical impedance spectroscopy (EIS). The results show that Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy has the better corrosion resistance than its corresponding crystal alloy. During the bath in the 3.5% NaCl solution at 25°C, Zr53.5Cu26.5Ni5Al12Ag3 alloy has the lower corrosion current density than the corresponding crystal alloy. After 100h, the corrosion current densities of Zr53.5Cu26.5Ni5Al12Ag3 and the corresponding crystal alloy are 3.8415×10-8A/cm2 and 5.2827×10-7A/cm2, respectively. The results of EIS test indicate that Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy has the excellent corrosion resistance because passive film with stable structure formed on the surface in 3.5% NaCl solution. With an increase in the immersion time, the passive film becomes thicker. It leads to impedance resistance and corrosion resistance decrease. The surface of Zr53.5Cu26.5Ni5Al12Ag3 bulk amorphous alloy in 3.5% NaCl solution for 100h was analyzed by SEM and EDS. The results show that the corrosive pitting can be found at both the amorphous alloy and the corresponding crystal alloy. However, the amorphous alloy has the better corrosive pitting resistance than the crystal one because the corrosion products formed by selective dissolving of Zr and Al elements. Moreover, the addition of Ag element helps to improve the corrosion resistance of the amorphous alloy greatly.

scholarly journals Use of ZnAl-Layered Double Hydroxide (LDH) to Extend the Service Life of Reinforced Concrete

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1769 ◽  
Author(s):  
Celestino Gomes ◽  
Zahid Mir ◽  
Rui Sampaio ◽  
Alexandre Bastos ◽  
João Tedim ◽  
...  
Keyword(s):  
Reinforced Concrete ◽  
Layered Double Hydroxide ◽  
External Solution ◽  
Chloride Ions ◽  
Nacl Solution ◽  
The Stability ◽  
Ph Range ◽  
Double Hydroxide ◽  
Corrosion Of Steel ◽  
Steel Rebars

This work investigated the use of ZnAl-layered double hydroxide (LDH) intercalated with nitrate or nitrite ions for controlling the corrosion of steel in reinforced concrete. The work started by analyzing the stability of the powder in the 1–14 pH range and the capacity for capturing chloride ions in aqueous solutions of different pH. The effect of the ZnAl-LDH on the corrosion of steel was studied in aqueous 0.05 M NaCl solution and in mortars immersed in 3.5% NaCl. It was found that the LDH powders dissolved partially at pH > 12. The LDH was able to capture chloride ions from the external solution, but the process was pH-dependent and stopped at high pH due to the partial dissolution of LDH and the preferential exchange of OH– ions. These results seemed to imply that ZnAl-LDH would not work in the alkaline environment inside the concrete. Nonetheless, preliminary results with mortars containing ZnAl-LDH showed lower penetration of chloride ions and higher corrosion resistance of the steel rebars.

scholarly journals An Electrochemical Study to Evaluate the Effect of Calcium Nitrite Inhibitor to Mitigate the Corrosion of Reinforcement in Sodium Chloride Contaminated Ca(OH)2Solution

2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
Hwa-Sung Ryu ◽  
Jitendra Kumar Singh ◽  
Han-Seung Lee ◽  
Won-Jun Park
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Sodium Chloride ◽  
Anodic Polarization ◽  
Open Circuit Potential ◽  
Electrochemical Impedance ◽  
Open Circuit ◽  
Nacl Solution ◽  
Steel Rebar ◽  
Calcium Nitrite ◽  
Corrosion Of Steel

The effect of calcium nitrite (Ca(NO2)2) was assessed by electrochemical means such as open circuit potential (OCP), electrochemical impedance spectroscopy (EIS), and potentiodynamic studies in saturated Ca(OH)2solution contaminated with 0.99 and 7.91 g/L NaCl. The preliminary results of OCP showed that the potential is shifted towards positive (noble) side as content of inhibitor increased. The EIS results indicate that Ca(NO2)2works effectively in reduction and initiation of corrosion of steel rebar in NaCl contaminated Ca(OH)2solution. Potentiodynamic studies revealed the pitting tendency of steel rebar exposed in 0.99 g/L NaCl at [Cl−/NO2-] = 1.2 attributed to low conductivity of passive film which causes interference for Cl−ions attack during anodic polarization. The 85.75% efficiency is found in 0.99 g/L at [Cl−/NO2-] = 1.2. The Ca(NO2)2inhibitor transformed the unstable iron oxides/hydroxides into stable and protective oxides/hydroxides due to its strong oxidizing nature. Therefore, this inhibitor is sufficiently and significantly reducing the corrosion of steel rebar at even its low concentration with 0.99 and 7.91 g/L NaCl solution.

Inhibition Activities of Sorbitol on the Corrosion of Steel Rebar

2015 ◽  
Vol 1090 ◽  
pp. 69-74
Author(s):  
Li Juan Feng ◽  
Xin Cui ◽  
Jian Hua Wang ◽  
Huai Yu Yang ◽  
Fu Hui Wang
Keyword(s):  
Corrosion Inhibition ◽  
Concrete Structure ◽  
Corrosion Current ◽  
Inhibition Mechanism ◽  
Protective Film ◽  
Cell Potential ◽  
Steel Rebar ◽  
Simulated System ◽  
The Fourier Transform ◽  
Corrosion Of Steel

The corrosion inhibition activities of sorbitol on the corrosion of steel rebar were studied via potentialdynamic polarization, electrochemical impendence spectroscopy (EIS) techniques as well as the Fourier transform infrared spectroscopy (FTIR) in simulated concrete pore solution. In order to determine its corrosion inhibition effect in the concrete structure, concrete specimens with steel rebar inside were prepared and wet /dry cycles method was used to simulate the service environment of steel rebar in marine region as well as to accelerate rebar corrosion. The inhibition performances of sorbitol were investigated by half cell potential and corrosion current density measurements. The results indicate that sorbitol can effectively inhibit the corrosion of steel rebar both in simulated system and concrete structure. Its inhibition mechanism involves a chelating effect of the molecule with the iron ions and a protective film formed on the metal surface.

scholarly journals Corrosion of Steel Rebars in Anoxic Environments. Part I: Electrochemical Measurements

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2491
Author(s):  
Elena Garcia ◽  
Julio Torres ◽  
Nuria Rebolledo ◽  
Raul Arrabal ◽  
Javier Sanchez
Keyword(s):  
Corrosion Rate ◽  
Electrochemical Impedance ◽  
Electrochemical Techniques ◽  
Chloride Content ◽  
Offshore Platforms ◽  
Anoxic Conditions ◽  
Current Limit ◽  
Anoxic Environments ◽  
Corrosion Of Steel ◽  
Steel Rebars

The number of reinforced concrete structures subject to anoxic conditions such as offshore platforms and geological storage facilities is growing steadily. This study explored the behaviour of embedded steel reinforcement corrosion under anoxic conditions in the presence of different chloride concentrations. Corrosion rate values were obtained by three electrochemical techniques: Linear polarization resistance, electrochemical impedance spectroscopy, and chronopotenciometry. The corrosion rate ceiling observed was 0.98 µA/cm2, irrespective of the chloride content in the concrete. By means of an Evans diagram, it was possible to estimate the value of the cathodic Tafel constant (bc) to be 180 mV dec−1, and the current limit yielded an ilim value of 0.98 µA/cm2. On the other hand, the corrosion potential would lie most likely in the −900 mVAg/AgCl to −1000 mVAg/AgCl range, whilst the bounds for the most probable corrosion rate were 0.61 µA/cm2 to 0.22 µA/cm2. The experiments conducted revealed clear evidence of corrosion-induced pitting that will be assessed in subsequent research.

scholarly journals Effect of Electrical Injection of Corrosion Inhibitor on the Corrosion of Steel Rebar in Chloride-Contaminated Repair Mortar

2015 ◽  
Vol 2015 ◽  
pp. 1-10 ◽  
Author(s):  
The Huyen Nguyen ◽  
Tuan Anh Nguyen ◽  
Thien Vuong Nguyen ◽  
Van Khu Le ◽  
Thi Mai Thanh Dinh ◽  
...  
Keyword(s):  
Current Density ◽  
Cement Mortar ◽  
Tetrabutylammonium Bromide ◽  
Electrical Current ◽  
Corrosion Current ◽  
Sodium Borate ◽  
Apparent Diffusion Coefficients ◽  
Steel Rebar ◽  
Repair Mortar ◽  
Vis Spectroscopy

The electrical rehabilitation treatments of repair mortar were performed with tetrabutylammonium bromide salt (TBAB) at an electrical current density of 5 A/m2, using two electrolytes (0.1 M NaOH and 0.1 M Na3BO3solutions), and for two time periods (1 and 4 weeks), respectively. The average organic cation-based inhibitor’s concentration in cement mortars before and after this treatment was quantified using the UV-Vis spectroscopy. The experimental results reveal that the EICI treatment with 0.1 M Na3BO3was more effective in injecting the inhibitor and in improving the chloride penetration resistance and compressive strength of the mortar, relative to using 0.1 M NaOH as electrolyte. In this case, after the 4-week EICI treatment, [TBA+] contents were 2.3 % and 2.4% by mass of cement mortar for uncontaminated and salt-contaminated mortars, respectively. After the 4-week EICI treatment, the apparent diffusion coefficients of chloride anion in cement mortar were decreased by 40% from 1.52 × 10−10 m2/s. The EICI treatment was able to halt the chloride-induced corrosion of the steel rebar by promoting its passivation. The 2-week EICI treatment using sodium hydroxide and sodium borate solutions decreased the corrosion current density of the rebar by 77.8% and 78.5%, respectively, approximately two months after the treatment.

Inspection of Concrete-Metal Rod Interface Using Guided Waves

2000 ◽  
Author(s):  
Won-Bae Na ◽  
Tribikram Kundu ◽  
Mohammad R. Ehsani
Keyword(s):  
Lamb Wave ◽  
Guided Waves ◽  
Lamb Waves ◽  
Guided Wave ◽  
Ultrasonic Transducers ◽  
Interface Debonding ◽  
Long Distance ◽  
Steel Rebar ◽  
Steel Bars ◽  
Steel Rebars

Abstract The feasibility of detecting interface degradation and separation of steel rebars in concrete beams using Lamb waves is investigated in this paper. It is shown that Lamb waves can easily detect these defects. A special coupler between the steel rebar and ultrasonic transducers has been used to launch non-axisymmetric guided waves in the steel rebar. This investigation shows that the Lamb wave inspection technique is an efficient and effective tool for health monitoring of reinforced concrete structures because the Lamb wave can propagate a long distance along the reinforcing steel bars embedded in concrete as the guided wave and is sensitive to the interface debonding between the steel rebar and concrete.

Effect of the Sintering Atmosphere on the Corrosion Resistance of Titanium for Application as Biomaterial

2012 ◽  
Vol 727-728 ◽  
pp. 85-89
Author(s):  
Luzinete P. Barbosa ◽  
Elki C. Souza ◽  
Lucio Salgado ◽  
I. Costa
Keyword(s):  
Corrosion Resistance ◽  
Oxygen Content ◽  
Passive Film ◽  
Titanium Surface ◽  
Sintered Titanium ◽  
Nacl Solution ◽  
Low Oxygen ◽  
Sintering Atmosphere ◽  
Corrosion Tests ◽  
Vacuum Atmosphere

In this work, the effect of sintering atmosphere on the corrosion resistance of sintered titanium has been evaluated in 0.9 % aqueous NaCl solution to simulate physiological environment. Corrosion tests were performed on titanium porous sintered under vacuum and vacuum plus dynamic argon. The results showed better passive properties associated to the titanium sintered under argon plus vacuum atmosphere than to the vacuum sintered titanium. The better corrosion resistance of the argon plus vacuum sintered titanium was attributed to the formation of a thin passive film on the titanium surface during sintering due the low oxygen content present in this atmosphere.

Sign in / Sign up

Export Citation Format

Share Document