scholarly journals Tuning Lignin Characteristics by Fractionation: A Versatile Approach Based on Solvent Extraction and Membrane-Assisted Ultrafiltration

Molecules ◽  
2020 ◽  
Vol 25 (12) ◽  
pp. 2893 ◽  
Author(s):  
Chiara Allegretti ◽  
Oussama Boumezgane ◽  
Letizia Rossato ◽  
Alberto Strini ◽  
Julien Troquet ◽  
...  
Keyword(s):  
Solvent Extraction ◽  
Raw Materials ◽  
Scale Up ◽  
Kraft Pulping ◽  
High Variability ◽  
Potential Applicability ◽  
Fractionation Method ◽  
Set Up ◽  
Predictable Characteristics ◽  
Technical Lignins

Technical lignins, typically obtained from the biorefining of lignocellulosic raw materials, represent a highly abundant natural aromatic feedstock with high potential in a sustainable economy scenario, especially considering the huge primary production volumes and the inherently renewable nature of this resource. One of the main drawbacks in their full exploitation is their high variability and heterogeneity in terms of chemical composition and molecular weight distribution. Within this context, the availability of effective and robust fractionation processes represents a key requirement for the effective valorization of lignin. In the present work, a multistep fractionation of two different well known technical lignins obtained from two distinct delignification processes (soda vs. kraft pulping) was described. A comprehensive approach combining solvent extraction in organic or aqueous medium with membrane-assisted ultrafiltration was developed in order to maximize the process versatility. The obtained lignin fractions were thoroughly characterized in terms of their chemical, physical, thermal, and structural properties, highlighting the ability of the proposed approach to deliver consistent and reproducible fractions of well-controlled and predictable characteristics, irrespective of their biomass origin. The results of this study demonstrate the versatility and the reliability of this integrated multistep fractionation method, which can be easily adapted to different solvent media using the same ultrafiltration membrane set up, thereby enhancing the potential applicability of this approach in an industrial scale-up perspective for a large variety of starting raw lignins.

Recovery Value Metals from Mixed Spent Li-Ion Batteries

2014 ◽  
Vol 540 ◽  
pp. 267-271
Author(s):  
Xin Liu ◽  
Lin Yan Li ◽  
Fan Yun Zeng ◽  
Xue Jun Wang ◽  
Sheng Ming Xu
Keyword(s):  
Solvent Extraction ◽  
Raw Materials ◽  
Low Cost ◽  
Rapid Development ◽  
Li Ion Batteries ◽  
Active Materials ◽  
Solid Ratio ◽  
Li Ion ◽  
Leaching Condition ◽  
Addition Amount

With the rapid development and wide application of Li-ion batteries, cathode materials containing value metals Co, Ni and Mn are blended by several kind of metal oxide presently for pursuing high safe stability and low cost. The composition of spent Li-ion batteries has become complicated and optimum leaching condition varied. In this paper, leaching process for the mixture of pure LiCoO2and Li (Ni1/3Co1/3Mn1/3)O2was studied. With an increase in component of LiCoO2in mixed materials, the optimum leaching condition varied as: temperature from 60°C to 90°C, H2O2addition amount from 0.54 to 0.75ml/g and liquid-solid ratio from 10 to 20. According to this result, a real mixed spent batteries materials was recovered by being leached in 2M H2SO4at temperature of 90°C, liquid-solid ratio 20 and 0.6ml/g H2O2added. The leaching efficiencies of Co, Ni, Mn, Li were 96.88%, 93.71%, 92.12%, 99.43% respectively. Cu, Al and Fe in solution were removed by precipitation and solvent extraction. Finally, Ni, Co, Mn were extracted by D2EHPA for separating with Na+and other impurities, which is used as a raw materials for preparation of cathode active materials in batteries.

Synthesis of Eco-friendly Nano-Structured Biosurfactants from Vegetable Oil Sources and Characterization of Their Interfacial Properties for Cosmetic Applications

MRS Advances ◽  
2018 ◽  
Vol 4 (07) ◽  
pp. 377-384 ◽  
Author(s):  
DaNan Yea ◽  
SeonHui Jo ◽  
JongChoo Lim
Keyword(s):  
Raw Materials ◽  
Coconut Oil ◽  
Interfacial Properties ◽  
Interfacial Property ◽  
Solution Stability ◽  
H Nmr ◽  
Wetting Property ◽  
Potential Applicability ◽  
Ft Ir

ABSTRACTIn this study, 3 types of zwitterionic phospholipid biosurfactants LDP(S), CDP(S) and CTDP(S) were prepared from 3 different raw materials such as rapeseed oil, coconut oil and cottonseed oil respectively. The structure of the resulting phospholipid biosurfactants was elucidated by FT-IR, 1H NMR and 13C NMR spectroscopies and their interfacial properties have been examined such as CMC, static surface tension, wetting property, solution stability, and foam property. Interfacial property measurement and prescription test in cosmetic formulation prepared with the newly synthesized biosurfactants revealed that CDP(S) biosurfactant possesses excellent mildness and superior interfacial properties, indicating the potential applicability in cosmetic product formulations.

scholarly journals Reproducibility of suppression of Pythium wilt of cucumber by compost

2014 ◽  
Vol 23 (3) ◽  
pp. 236-245 ◽  
Author(s):  
Mauritz Vilhelm Vestberg ◽  
Sanna Kukkonen ◽  
Päivi Parikka ◽  
Dan Yu ◽  
Martin Romantschuk
Keyword(s):  
Raw Materials ◽  
Dry Weight ◽  
Shoot Height ◽  
Bacterial Diseases ◽  
Sphagnum Peat ◽  
Shoot Dry Weight ◽  
Suppressive Capacity ◽  
The Difference ◽  
Set Up

There is increasing global interest in using compost to suppress soil-borne fungal and bacterial diseases and nematodes. We studied the reproducibility of compost suppressive capacity (SC) against Pythium wilt of cucumber using nine composts produced by the same composting plant in 2008 and 2009. A bioassay was set up in a greenhouse using cucumber inoculated with two strains of Pythium. The composts were used as 20% mixtures (v:v) of a basic steam-sterilized light Sphagnum peat and sand (3:1, v:v). Shoot height was measured weekly during the 5-week experiment. At harvest, the SC was calculated as the % difference in shoot dry weight (DW) between non-inoculated and inoculated cucumbers. The SC was not affected by year of production (2008 or 2009), indicating reproducibility of SC when the raw materials and the composting method are not changed. Differences in shoot height were not as pronounced as those for shoot DW. The results were encouraging, but further studies are still needed for producing compost with guaranteed suppressiveness properties.

scholarly journals A study to set-up a technological process for purification of Zinc scraps by using liquation method

2021 ◽  
Vol 8 (1) ◽  
pp. 36-43
Author(s):  
Ngoc Vuong Tran ◽  
Manh Hung Luong ◽  
Dinh Dang Nguyen
Keyword(s):  
Zinc Oxide ◽  
Raw Materials ◽  
Time Factors ◽  
Pilot Scale ◽  
Raw Material ◽  
Optimal Time ◽  
Fe Content ◽  
Technology Process ◽  
Zn Content ◽  
Set Up

Zinc scrap is a source of raw material for zinc oxide production. However, to qualify the requirement of raw material for zinc oxide (99.5%) production, refining this source is needed. Many methods are considered such as rectification, chemical method, etc., but difficult to apply on an industrial scale. This workfocused on the investigation of the influence of temperature and time factors for asessing the possibility of applying liquation method for the purification of impurities from scrap zinc.The experiment results show that the optimum temperature of liquation to remove Pb,Fe from zinc scrap is in the range of 440-450°C, the optimal time of the process is 8h for the pot with 8cm in height and 6cm in diameter (the quantity of raw zinc sample is about 2kg / batch), then we can obtain about 80% of zinc metal with an average Zn content of about 97, 0%, both Pb and Fe content decreased to a range from 0.35 to 0.4%, and 1.0 to 1.1%, respectively, which meet the requirement of raw materials for the production of high quanlity ZnO ( 99,5 %). Based on the parameters obtained on lab-scale, a trial on pilot scale of 250 kg / batch was conducted, The result confirms that the quality of the products meets the requirement of raw materials for production of high quality ZnO (99.5%) and a technology process for refining zinc scrap by the liquation was proposed.

scholarly journals A new methodology for monitoring P. oceanica meadows in Tavolara Punta Coda Cavallo MPA using GIS

2015 ◽  
Author(s):  
Pieraugusto Panzalis ◽  
Andrea Deiana ◽  
Sarah Caronni ◽  
Augusto Navone
Keyword(s):  
Scale Up ◽  
Continuous Mapping ◽  
Detailed Knowledge ◽  
Regular Grid ◽  
Side Scan Sonar ◽  
Sea Bottom ◽  
The Status ◽  
Square Cells ◽  
Set Up ◽  
The Many

Marine Protected Areas (MPAs) are acknowledged globally as effective tools for the protection and management of the marine environment; however, to get effective results it is necessary to set up a proper and continuous mapping of the marine territory, in order to gain detailed knowledge of its different aspects. Therefore, the implementation and maintenance of a modern GIS (Geographic Information System) has become an indispensable task for the MPA of Tavolara - Punta Coda Cavallo to collect, aggregate, classify, and track the conducted mapping activities. Between 2011 and 2012 the sea bottom of the MPA was surveyed using different methods: by means of a multi-beam echo sounder and of a side scan sonar, as well as conducting fast scientific scuba divings with re-breathers and underwater position system technologies. High resolution geodatasets, characterized by a significantly high quality in representing and describing the sea bottom and its habitats, were produced in both feature (scale up to 1:1.250) and raster formats (up to 30cm/pixel for sonar images and 1m/pixel for bathymetry) and they currently constitute the basis of the MPA's GIS, including its 3D applications and its web map services for desktop and mobile devices (iPhone & Android). To update the above described geodatasets during time, acquiring new data on the conservation targets considered in monitoring activities, among which the status of P. oceanica meadows is of the most important ones, a long term mapping plan was realized on the basis of an innovative methodology elaborated by the MPA considering both the wideness of the area and the limited funds available at present. The whole MPA was divided in territorial units by means of a regular grid of square cells having a 100m side with the logic of starting the mapping activities from the mainly important areas and then to spread the surveys up to fill the whole mosaic. All the new data acquired with this methodology could then be mixed, compared and indexed within the same cell and/or in the many already available geodatases, starting from those dated 2006 having a regular grid with square cells of 500m per side.

scholarly journals State and prospects of competition, communications and logistics of agro-food products

2021 ◽  
Vol 262 ◽  
pp. 03017
Author(s):  
Hadis Rakhaev ◽  
Anzor Gyatov ◽  
Zalina Ivanova ◽  
Elvira Kokova ◽  
Akhmat Chochaev
Keyword(s):  
Communication Systems ◽  
Raw Materials ◽  
Agricultural Products ◽  
Real Situation ◽  
The Real ◽  
Logistics Networks ◽  
Chemical Products ◽  
The Government ◽  
Set Up ◽  
New Criteria

Communication and logistics are one of the most important features of the markets; they permeate and constitute its content. Communication and logistics for commodity producers are also as important attribute as production itself, and sometimes even more. For this reason, commodity producers themselves directly and explicitly, but more often through other institutions (including the government), tend to set up stable exclusive communication systems and logistics. This article analyzes the state of the prospects for the formation of communications and logistics networks for agricultural products. The correlation of existing communications and logistics of agricultural products and other types of products (including finished industrial products of various purposes: from machinery, equipment, chemical products to defense, hydrocarbon, carbon and other raw materials, timber and other goods) is analyzed. The established linkages are revealed. They were quantified, calibrated and classified. The existing principles (comparative and absolute advantages) are reviewed and new principles are formulated (marginal player, marginal linkages), which describe the real situation in the markets of agricultural products more correctly. New criteria for grouping and reformatting existing communication and logistics networks, which make it possible to increase the competitiveness of domestic agricultural products are proposed.

scholarly journals WEEE collection and CRM recovery trials: piloting a holistic approach for Scotland

2018 ◽  
Vol 20 (4) ◽  
pp. 712-718
Keyword(s):  
Raw Materials ◽  
Scale Up ◽  
Holistic Approach ◽  
Extraction Methods ◽  
Social Enterprises ◽  
Raw Material ◽  
Household Waste ◽  
Sustainable Supply Chain ◽  
Gold Silver ◽  
Critical Raw Materials

<p>Re-Tek UK and its partners, Enscape Consulting and the University of West of Scotland commenced trials for the collection and recovery of critical raw materials from waste electrical and electronic (WEEE) products in July 2016. Sponsored by the EU LIFE funded project ‘Critical Raw Material Closed Loop Recovery’ coordinated by WRAP with EARN, ERP UK Ltd, KTN Ltd and Wuppertal Institute as beneficiaries. The trials are aimed at boosting the recovery of critical raw materials (CRMs) from household waste electrical and electronic products (WEEE) and Information Communications Technology (ICT) in particular, after functioning equipment is separated out for re-use. The new collection models provided residents with the opportunity to drop-off unwanted electrical and electronic appliances at a time and place that suits them, through a collaborative approach which encourages local authorities, educational establishments, businesses, and Social Enterprises, etc to act as hub sites. Hubs were designed to minimize product damage and encourage drop-off, rather than hoarding. Extraction methods developed after the collection phase of the trial looked at the opportunity to recover cobalt, gold and silver from ICT products, with the potential to inform how a more sustainable supply chain could be developed in Scotland. The elements studied were selected to demonstrate financial opportunity (gold/silver) and a strategic priority material (cobalt) for long term supply. These are based on bioleaching and electrochemical recovery using novel carbon based electrode systems, and chemical processing methods using extraction techniques with an assessment of pilot performance and scale up challenges. Our report is on the state of progress towards practical solutions to WEEE and CRM recovery.</p>

Modelling Flue Gas Desulfurization Using Pyrolusite Pulp in a Jet Bubbling Reactor

2009 ◽  
Vol 610-613 ◽  
pp. 85-96 ◽  
Author(s):  
Jing Dong Zhao ◽  
Shi Jun Su ◽  
Nan Shan Ai ◽  
Xiao Fan Zhu
Keyword(s):  
Flue Gas ◽  
Ph Value ◽  
Scale Up ◽  
Absorption Efficiency ◽  
Flue Gas Desulfurization ◽  
Process Conditions ◽  
Gas Temperature ◽  
Transfer Coefficients ◽  
Set Up ◽  
So2 Absorption

A mathematical model for flue gas desulfurization using pyrolusite pulp in jet bubbling reactor (JBR) was described. Firstly, based on the concept of two stages mass balance with chemical reaction, two models were set up, for jet bubbling zone and rising bubble zone, respectively, according to the construction of JBR. The models consist of two coupling differential equations and were solved simultaneously by integral and separation of the variables. Then the SO2 absorption efficiency expression was developed, considering the great discrepancy existing between the gas-side mass transfer coefficients of the jet bubbling zone and gas bubble rising zone. The final expression associates SO2 absorption efficiency with process conditions and JBR structure parameters, which can give some instruction and guidance for the study of reactor operation process. Predicted results from the theoretical model, including effect of pH value of the pulp, flue gas temperature and inlet SO2 concentration of flue gas on SO2 absorption efficiency, were found to be in good agreement with experimental data obtained in a jet bubbling reactor. The model provides a basis for the process scale up and operating guide.

scholarly journals Scale-up of Caustic-Side Solvent Extraction Process for Removal of Cesium at Savannah River Site

2008 ◽  
Vol 43 (9-10) ◽  
pp. 2786-2796 ◽  
Author(s):  
M.W. Geeting ◽  
E.A. Brass ◽  
S.J. Brown ◽  
S.G. Campbell
Keyword(s):  
Solvent Extraction ◽  
Scale Up ◽  
Extraction Process ◽  
Savannah River Site ◽  
Savannah River ◽  
River Site

Commercial production of Nile tilapia on Lake Kariba, Zimbabwe.

2020 ◽  
Author(s):  
Keyword(s):  
Private Equity ◽  
Production Management ◽  
Raw Materials ◽  
Fish Farm ◽  
Sub Saharan Africa ◽  
Net Income ◽  
Manufacturing Companies ◽  
Lake Kariba ◽  
Sub Saharan ◽  
Set Up

Abstract Lake Harvest Aquaculture (Pvt) Ltd was first developed into a freshwater tilapia fish farm business in 1996 on premises that originally farmed freshwater prawns owned by one of Zimbabwe's food companies, Cairns Foods Ltd. The farm was set up in 1997 and, ten years later, has grown to a 3000-tonne fish farm where tilapia are produced primarily for processing and export to European and regional markets. The original targeted projections for production and net income of the farm were proving accurate until 2001 when the macro-economy began to shrink. Low production on crop farms due to inadequate resources and drought brought a shortage of raw materials to the feed manufacturing companies. The continuous downward trend in feed production affected the company as it failed to support its growing fish biomass. The feed and economy problems resulted in a decision by the board to stop expansion of the business in 2002. Lake Harvest business was set up at a cost of US $10,000,000. The business was externally funded by the Commonwealth Development Corporation (CDC Group plc) and Comafin, a pan-African private equity fund, before the share holding structure changed in 2002. The major costs were encountered on the installation and mooring of cages, and the construction of a fish processing factory. Six sites were installed, each costing around US $350,000, including boats. The processing factory cost around US $4,000,000. The objectives of this case study are to: * Provide a scenario and overview of Lake Harvest Aquaculture as a company growing tilapia in cages in Lake Kariba, Zimbabwe. * Provide a means of assessment and learning for those considering developing cage-based aquaculture in sub-Saharan Africa. All of the main activities carried out at Lake Harvest will be described in the same sequence as followed on-farm; production, management, and sale of the final product: * Breeding * Feeding * Sampling * Diving * Harvesting * Processing * Marketing.

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