scholarly journals Impact of the Preparation Procedure on the Performance of the Microporous HKUST-1 Metal-Organic Framework in the Liquid-Phase Separation of Aromatic Compounds

Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2648
Author(s):  
Vera I. Isaeva ◽  
Bulat R. Saifutdinov ◽  
Vladimir V. Chernyshev ◽  
Vadim V. Vergun ◽  
Gennady I. Kapustin ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Aromatic Compounds ◽  
High Performance ◽  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Preparation Procedure ◽  
Microwave Assisted Synthesis ◽  
Adsorption Selectivity ◽  
Metal Organic ◽  
Organic Framework

To date, metal-organic frameworks (MOFs) have been recognized as promising solid phases in high-performance liquid chromatography (HPLC). This research aimed to elucidate the role of the physico-chemical characteristics of the microporous HKUST-1 metal-organic framework in its operation as a selective adsorbent in HPLC. For this, the HKUST-1 samples were prepared by microwave-assisted synthesis and a solvothermal procedure. According to the chromatographic examinations, the HKUST-1 material synthesized in the microwave fields shows an efficient performance in the selective adsorption of aromatic compounds with different functionalities. This study revealed a significant impact of the preparation procedure on the mechanism of the liquid-phase adsorption on the HKUST adsorbents under conditions of the HPLC. An effect of the elution solvent with the different coordination ability to the Cu2+ sites in the HKUST-1 structure on the adsorption selectivity was observed.

A binuclear Co-based metal-organic framework towards efficient oxygen evolution reaction

2021 ◽  
Author(s):  
Ning Liu ◽  
Qiaoqiao Zhang ◽  
Jingqi Guan
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Low Cost ◽  
Metal Organic Framework ◽  
Research Interest ◽  
Metal Organic ◽  
Organic Framework

Seeking for low-cost and high-performance electrocatalysts for oxygen evolution reaction (OER) has drawn enormous research interest in the last few years. Reported herein is the topotactic construction of a binuclear...

A new hexagonal porous carbon nanoplate material derived from Al-based metal organic framework for high performance supercapacitors

2021 ◽  
Vol 371 ◽  
pp. 137826
Author(s):  
Xingyu Liu ◽  
Pingyuan Wang ◽  
Cuiping Chang ◽  
Yongmei Chen ◽  
Yanzhi Sun ◽  
...  
Keyword(s):  
Porous Carbon ◽  
High Performance ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Plasma-engineered bifunctional cobalt–metal organic framework derivatives for high-performance complete water electrolysis

Nanoscale ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 6201-6211
Author(s):  
Wenxia Chen ◽  
Wei Wei ◽  
Kefeng Wang ◽  
Nan Zhang ◽  
Guangliang Chen ◽  
...  
Keyword(s):  
High Performance ◽  
Metal Organic Framework ◽  
Water Electrolysis ◽  
Plasma Discharge ◽  
Rf Plasma ◽  
Cobalt Metal ◽  
Simultaneous Oxidation ◽  
Rf Plasma Discharge ◽  
Metal Organic ◽  
Organic Framework

A MOF-derived CoPO hollow polyhedron structure is designed by simultaneous oxidation/phosphatization processes during Ar–N2 RF plasma discharge.

Metal-Organic Framework Derived NiSe2/CeO2 Nanocomposite as a High-Performance Electrocatalyst for Oxygen Evolution Reaction (OER)

2021 ◽  
Author(s):  
Davood Taherinia ◽  
Seyyed Heydar Moravvej ◽  
Mohammad Moazzeni ◽  
Elham Akbarzadeh
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Metal Organic Framework ◽  
Cost Effective ◽  
Clean Technologies ◽  
Metal Organic ◽  
Organic Framework

The development of efficient and cost-effective catalysts for the oxygen evolution reaction is highly desirable for applications that are based on sustainable and clean technologies. In this study, we report...

Metal-organic framework derived FeS/MoS2 composite as a high performance anode for sodium-ion batteries

2021 ◽  
Vol 869 ◽  
pp. 159348
Author(s):  
Likang Fu ◽  
Wenqi Xiong ◽  
Qiming Liu ◽  
Shuyun Wan ◽  
Chenxia Kang ◽  
...  
Keyword(s):  
High Performance ◽  
Metal Organic Framework ◽  
Sodium Ion ◽  
Sodium Ion Batteries ◽  
Metal Organic ◽  
Organic Framework

Selective adsorption and separation of C2 hydrocarbons in a “flexible-robust” metal–organic framework based on a guest-dependent gate-opening effect

2020 ◽  
Vol 56 (41) ◽  
pp. 5520-5523
Author(s):  
Peng-Dan Zhang ◽  
Xue-Qian Wu ◽  
Tao He ◽  
Lin-Hua Xie ◽  
Qiang Chen ◽  
...  
Keyword(s):  
Selective Adsorption ◽  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
C2 Hydrocarbons ◽  
Organic Framework

The selective adsorption and separation of C2 hydrocarbons have been achieved in a “flexible-robust” MOF based on a guest-dependent gate-opening effect.

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