scholarly journals Composite Graphene-Containing Porous Materials from Carbon for Capacitive Deionization of Water

Molecules ◽  
2020 ◽  
Vol 25 (11) ◽  
pp. 2620
Author(s):  
Tamuna Bakhia ◽  
Ruslan Kh. Khamizov ◽  
Zaur R. Bavizhev ◽  
Mukhamed D. Bavizhev ◽  
Magomet A. Konov ◽  
...  

New techniques were developed for the synthesis of monolithic highly porous composite aerogels (hydrogels) from reduced graphene oxide and carbon nanotubes, as well as graphene-containing composites based on mesoporous activated carbon. Simple operations for hydrophilization of synthesized samples were proposed. New electrode materials for electrosorption and deionization of water were fabricated. The resulting materials were investigated and tested in electrochemical cells for membrane capacitive deionization (MCDI).

2015 ◽  
Vol 17 (2) ◽  
pp. 776-780 ◽  
Author(s):  
Barun Kumar Barman ◽  
Karuna Kar Nanda

We demonstrate a Si-mediated environmentally friendly reduction of graphene oxide (GO) and the fabrication of hybrid electrode materials with multiwall carbon nanotubes and nanofibers. The reduction of GO is facilitated by the nascent hydrogen generated by the reaction between Si and KOH. The overall process consumes 10 to 15 μm of Si each time and the same Si substrate can be used multiple times.


2016 ◽  
Vol 18 (43) ◽  
pp. 30068-30078 ◽  
Author(s):  
M. Li ◽  
F. Liu ◽  
X. B. Zhang ◽  
J. P. Cheng

A variety of carbon materials varying from 0D to 2D, i.e. 0D nanoparticles, 1D carbon nanotubes (CNTs) and 2D reduced graphene oxide (rGO) are selected to in situ combine with Ni–Mn layered double hydroxide (LDH) to prepare electrode materials for supercapacitors.


RSC Advances ◽  
2016 ◽  
Vol 6 (64) ◽  
pp. 58907-58915 ◽  
Author(s):  
Helan Zhang ◽  
Peng Liang ◽  
Yanhong Bian ◽  
Yong Jiang ◽  
Xueliang Sun ◽  
...  

Moderately oxidized graphene–carbon nanotubes hybrid can be used as good electrode materials for CDI with enhanced electrosorption capacity.


Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1240
Author(s):  
Olena Okhay ◽  
Alexander Tkach

Thanks to the advanced technologies for energy generation such as solar cells and thermo- or piezo-generators the amount of electricity transformed from light, heat or mechanical pressure sources can be significantly enhanced. However, there is still a demand for effective storage devices to conserve electrical energy which addresses the wide range of large stationary applications from electric vehicles to small portable devices. Among the large variety of energy-storage systems available today, electrochemical energy sources and, in particular, supercapacitors (SC), are rather promising in terms of cost, scaling, power management, life cycle and safety. Therefore, this review surveys recent achievements in the development of SC based on composites of such carbon-derived materials as graphene (G) and reduced graphene oxide (rGO) with carbon nanotubes (CNT). Various factors influencing the specific capacitance are discussed, while specific energy and power as well as cycling stability of SC with G/rGO-CNT composite electrode materials are overviewed.


RSC Advances ◽  
2015 ◽  
Vol 5 (35) ◽  
pp. 27940-27945 ◽  
Author(s):  
Ji Yan ◽  
Gregory Lui ◽  
Ricky Tjandra ◽  
Xiaolei Wang ◽  
Lathankan Rasenthiram ◽  
...  

α-NiS combined with SWNTs and graphene exhibits high specific capacitance, and excellent rate performance and cycling stability.


Nanomaterials ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 2024
Author(s):  
Timotheus Jahnke ◽  
Leila Raafat ◽  
Daniel Hotz ◽  
Andrea Knöller ◽  
Achim Max Diem ◽  
...  

Establishing energy storage systems beyond conventional lithium ion batteries requires the development of novel types of electrode materials. Such materials should be capable of accommodating ion species other than Li+, and ideally, these ion species should be of multivalent nature, such as Al3+. Along this line, we introduce a highly porous aerogel cathode composed of reduced graphene oxide, which is loaded with nanostructured SnO2. This binder-free hybrid not only exhibits an outstanding mechanical performance, but also unites the pseudocapacity of the reduced graphene oxide and the electrochemical storage capacity of the SnO2 nanoplatelets. Moreover, the combination of both materials gives rise to additional intercalation sites at their interface, further contributing to the total capacity of up to 16 mAh cm−3 at a charging rate of 2 C. The high porosity (99.9%) of the hybrid and the synergy of its components yield a cathode material for high-rate (up to 20 C) aluminum ion batteries, which exhibit an excellent cycling stability over 10,000 tested cycles. The electrode design proposed here has a great potential to meet future energy and power density demands for advanced energy storage devices.


Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1090
Author(s):  
Gbenro Folaranmi ◽  
Mikhael Bechelany ◽  
Philippe Sistat ◽  
Marc Cretin ◽  
Francois Zaviska

Capacitive deionization is a second-generation water desalination technology in which porous electrodes (activated carbon materials) are used to temporarily store ions. In this technology, porous carbon used as electrodes have inherent limitations, such as low electrical conductivity, low capacitance, etc., and, as such, optimization of electrode materials by rational design to obtain hybrid electrodes is key towards improvement in desalination performance. In this work, different compositions of mixture of reduced graphene oxide (RGO) and activated carbon (from 5 to 20 wt% RGO) have been prepared and tested as electrodes for brackish water desalination. The physico-chemical and electrochemical properties of the activated carbon (AC), reduced graphene oxide (RGO), and as-prepared electrodes (AC/RGO-x) were characterized by low-temperature nitrogen adsorption measurement, scanning electron microscope (SEM), X-ray diffraction (XRD), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), Fourier transform infra-red (FT-IR), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). Among all the composite electrodes, AC/RGO-5 (RGO at 5 wt%) possessed the highest specific capacitance (74 F g−1) and the highest maximum salt adsorption capacity (mSAC) of 8.10 mg g−1 at an operating voltage ∆E = 1.4 V. This shows that this simple approach could offer a potential way of fabricating electrodes of accentuated carbon network of an improved electronic conductivity that’s much coveted in CDI technology.


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