scholarly journals Cannabis sativa L. Inflorescences from Monoecious Cultivars Grown in Central Italy: An Untargeted Chemical Characterization from Early Flowering to Ripening

Molecules ◽  
2020 ◽  
Vol 25 (8) ◽  
pp. 1908 ◽  
Author(s):  
Cinzia Ingallina ◽  
Anatoly P. Sobolev ◽  
Simone Circi ◽  
Mattia Spano ◽  
Caterina Fraschetti ◽  
...  
Keyword(s):  
Amino Acids ◽  
Chemical Composition ◽  
Biogenic Amines ◽  
Cannabis Sativa ◽  
Central Italy ◽  
Chemical Characterization ◽  
Chemical Characteristics ◽  
Flowering Period ◽  
Lazio Region ◽  
Very High

The chemical composition of the inflorescences from four Cannabis sativa L. monoecious cultivars (Ferimon, Uso-31, Felina 32 and Fedora 17), recently introduced in the Lazio Region, was monitored over the season from June to September giving indications on their sensorial, pharmaceutical/nutraceutical proprieties. Both untargeted (NMR) and targeted (GC/MS, UHPLC, HPLC-PDA/FD and spectrophotometry) analyses were carried out to identify and quantify compounds of different classes (sugars, organic acids, amino acids, cannabinoids, terpenoids, phenols, tannins, flavonoids and biogenic amines). All cultivars in each harvesting period showed a THC content below the Italian legal limit, although in general THC content increased over the season. Citric acid, malic acid and glucose showed the highest content in the late flowering period, whereas the content of proline drastically decreased after June in all cultivars. Neophytadiene, nerolidol and chlorogenic acid were quantified only in Felina 32 cultivar, characterized also by a very high content of flavonoids, whereas alloaromadendrene and trans-cinnamic acid were detected only in Uso-31 cultivar. Naringenin and naringin were present only in Fedora 17 and Ferimon cultivars, respectively. Moreover, Ferimon had the highest concentration of biogenic amines, especially in July and August. Cadaverine was present in all cultivars but only in September. These results suggest that the chemical composition of Cannabis sativa L. inflorescences depends on the cultivar and on the harvesting period. Producers can use this information as a guide to obtain inflorescences with peculiar chemical characteristics according to the specific use.

scholarly journals Chemical characteristics of brown carbon in atmospheric particles at a suburban site near Guangzhou, China

2018 ◽  
Vol 18 (22) ◽  
pp. 16409-16418 ◽  
Author(s):  
Yi Ming Qin ◽  
Hao Bo Tan ◽  
Yong Jie Li ◽  
Zhu Jie Li ◽  
Misha I. Schurman ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Absorption Coefficient ◽  
Light Absorption ◽  
Radiative Forcing ◽  
Chemical Characterization ◽  
Organic Aerosol ◽  
Atmospheric Particles ◽  
Chemical Characteristics ◽  
Brown Carbon ◽  
Suburban Site

Abstract. Light-absorbing organic carbon (or brown carbon, BrC) in atmospheric particles has received much attention for its potential role in global radiative forcing. While a number of field measurement campaigns have differentiated light absorption by black carbon (BC) and BrC, the chemical characteristics of BrC are not well understood. In this study, we present co-located real-time light absorption and chemical composition measurements of atmospheric particles to explore the relationship between the chemical and optical characteristics of BrC at a suburban site downwind of Guangzhou, China, from November to December 2014. BrC and BC contributions to light absorption were estimated using measurements from a seven-wavelength aethalometer, while the chemical composition of non-refractory PM1 was measured with a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). Using the absorption Ångström exponent (AAE) method, we estimated that BrC contributed 23.6 % to the total aerosol absorption at 370 nm, 18.1 % at 470 nm, 10.7 % at 520 nm, 10.7 % at 590 nm, and 10.5 % at 660 nm. Biomass burning organic aerosol (BBOA) has the highest mass absorption coefficient among sources of organic aerosols. Its contribution to total brown carbon absorption coefficient decreased but that of low-volatility oxygenated organic aerosol (LVOOA) increased with increasing wavelength, suggesting the need for wavelength-dependent light absorption analysis for BrC in association with its chemical makeup. Clear correlations of N-containing ion fragments with absorption coefficient were observed. These correlations also depended on their degrees of unsaturation/cyclization and oxygenation. While the current study relates light absorption by BrC to ion fragments, more detailed chemical characterization is warranted to constrain this relationship.

scholarly journals Effect of the Distillation Time on the Chemical Composition, Antioxidant Potential and Antimicrobial Activity of Essential Oils from Different Cannabis sativa L. Cultivars

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4770
Author(s):  
Sara Palmieri ◽  
Francesca Maggio ◽  
Marika Pellegrini ◽  
Antonella Ricci ◽  
Annalisa Serio ◽  
...  
Keyword(s):  
Antimicrobial Activity ◽  
Chemical Composition ◽  
Essential Oils ◽  
Cannabis Sativa ◽  
Central Italy ◽  
Antioxidant Potential ◽  
Volatile Fraction ◽  
Food Borne ◽  
Spoilage Bacteria ◽  
First Time

Within the unavoidable variability of various origins in the characteristics of essential oils, the aim of this study was to evaluate the effect of the distillation time on the chemical composition and biological activity of Cannabis sativa essential oils (EOs). The dry inflorescences came from Carmagnola, Kompolti, Futura 75, Gran Sasso Kush and Carmagnola Lemon varieties from Abruzzo region (Central Italy), the last two being new cultivar here described for the first time. EOs were collected at 2 h and 4 h of distillation; GC/MS technique was applied to characterize their volatile fraction. The EOs were evaluated for total polyphenol content (TPC), antioxidant capacity (AOC) and antimicrobial activity against food-borne pathogens and spoilage bacteria. The time of distillation particularly influenced EOs chemical composition, extracting more or less terpenic components, but generally enriching with minor sesquiterpenes and cannabidiol. A logical response in ratio of time was observed for antioxidant potential, being the essential oils at 4 h of distillation more active than those distilled for 2 h, and particularly Futura 75. Conversely, except for Futura 75, the effect of time on the antimicrobial activity was variable and requires further investigations; nevertheless, the inhibitory activity of all EOs against Pseudomonas fluorescens P34 was an interesting result.

scholarly journals Chemical characteristics of brown carbon in atmospheric particles at a suburban site near Guangzhou, China

2018 ◽  
Author(s):  
Yi Ming Qin ◽  
Hao Bo Tan ◽  
Yong Jie Li ◽  
Zhu Jie Li ◽  
Misha I. Schurman ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Absorption Coefficient ◽  
Light Absorption ◽  
Radiative Forcing ◽  
Chemical Characterization ◽  
Organic Aerosol ◽  
Atmospheric Particles ◽  
Chemical Characteristics ◽  
Brown Carbon ◽  
Suburban Site

Abstract. Light-absorbing organic carbon (or brown carbon, BrC) in atmospheric particles has received much attention for its potential role in global radiative forcing. While a number of field measurement campaigns have differentiated light absorption by black carbon (BC) and BrC, the chemical characteristics of BrC are not well understood. In this study, we present co-located real-time light absorption and chemical composition measurements of atmospheric particles to explore the relationship between the chemical and optical characteristics of BrC at a suburban site downwind of Guangzhou, China from November to December 2014. BrC and BC contributions to light absorption were estimated using measurements from a seven-wavelength aethalometer, while the chemical composition of non-refractory PM1 was measured with a high resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). Using the Absorption Angstrom Exponent (AAE) method, we estimated that BrC contributed 23.6 % to the total aerosol absorption at 370 nm, 18.1 % at 470 nm, 10.7 % at 520 nm, 10.7 % at 590 nm, and 10.5 % at 660 nm. Biomass burning organic aerosol (BBOA) has the highest mass absorption coefficient among sources of organic aerosols. Its contribution to total brown carbon absorption coefficient decreased but that of low-volatility oxygenated organic aerosol (LVOOA) increased with increasing wavelength, suggesting the need for wavelength-dependent light absorption analysis for BrC in association with its chemical makeup. Clear correlations of N-containing ion fragments with absorption coefficient were observed. These correlations also depended on their degrees of unsaturation/cyclization and oxygenation. While the current study relates light absorption by BrC to ion fragments, more detailed chemical characterization is warranted to constrain this relationship.

scholarly journals New Hybrid Tomato Cultivars: An NMR-Based Chemical Characterization

2020 ◽  
Vol 10 (5) ◽  
pp. 1887 ◽  
Author(s):  
Cinzia Ingallina ◽  
Anatoly P. Sobolev ◽  
Simone Circi ◽  
Mattia Spano ◽  
Anna Maria Giusti ◽  
...  
Keyword(s):  
Amino Acids ◽  
Organic Acids ◽  
Central Italy ◽  
Chemical Characterization ◽  
Fresh Market ◽  
Nmr Data ◽  
National Market ◽  
Metabolite Profiles ◽  
Tomato Cultivars ◽  
Similarities And Differences

Bamano, King Creole, Sugarland, and DulceMiel hybrid tomato cultivars have been recently introduced in the Lazio area (Central Italy) to expand and valorize the regional/national market. Tomatoes from these cultivars, together with tomatoes from the native Fiaschetta cultivar, were sampled at the proper ripening time for the fresh market and characterized to obtain and compare their metabolite profiles. The Bligh–Dyer extraction protocol was carried out, and the resulting organic and hydroalcoholic fractions were analyzed by high-field Nuclear Magnetic Resonance (NMR) spectroscopy. NMR data relative to quantified metabolites (sugars, amino acids, organic acids, sterols, and fatty acids) allowed to point out similarities and differences among cultivars. DulceMiel hybrid and Fiaschetta native cultivars showed some common aspects having the highest levels of the most abundant amino acids as well as comparable amounts of organic acids, amino acids, stigmasterol, and linoleic and linolenic acids. However, DulceMiel turned out to have higher levels of glucose, fructose, and galactose with respect to Fiaschetta, reflecting the particular taste of the DulceMiel product. King Creole, Bamano, and Sugarland hybrid cultivars were generally characterized by the lowest content of amino acids and organic acids. King Creole showed the highest content of malic acid, whereas Bamano was characterized by the highest levels of glucose and fructose.

scholarly journals Talisia esculenta (A. ST.-HIL.) Radlk: physico-chemical characteristics, antioxidant activity and biological activity

2020 ◽  
Vol 9 (2) ◽  
pp. e53921909
Author(s):  
Layanne Nascimento Fraga ◽  
Izabela Maria Montezano de Carvalho
Keyword(s):  
Antioxidant Activity ◽  
Biological Activity ◽  
Chemical Composition ◽  
Chemical Characterization ◽  
Chemical Characteristics ◽  
Review Of The Literature ◽  
Study Objective ◽  
Wild Fruit ◽  
Physico Chemical ◽  
Bioactive Potential

Talisia esculenta (A. ST.-HIL.) Radlk is a Brazilian wild fruit, known as a pitomba, belonging to the Sapindaceae family. The objective of the present work was to perform a review of the literature in order to identify studies on its physico-chemical characterization, antioxidant activity and biological activity. The articles search was done in PubMed, SciELO, Science Direct and LILACS. We identified 90 publications, 8 in SciELO, 3 in LILACS, 67 in Science Direct and 12 in PubMed. Subsequently, duplication of the articles between the databases was verified, and the triage was done by reading the titles, abstracts and reading in full, to analyze which articles fit the study objective, and only 5 studies were included. The review exposes Talisia esculenta Radlk (A. ST.-HIL.) as a fruit that has a bioactive potential, but there is a shortage of studies that deal with its chemical composition and its biological activity.

scholarly journals Chemical characterization and pharmacological action of Brazilian red propolis

2018 ◽  
Vol 2 (1) ◽  
pp. 34 ◽  
Author(s):  
Marcela Lins Cavalcanti de Pontes ◽  
Inácio Ricardo Alves Vasconcelos ◽  
Margareth de Fátima Formiga De Melo Diniz ◽  
Hilzeth De Luna Freire Pessôa
Keyword(s):  
Biological Activity ◽  
Chemical Composition ◽  
Chemical Characterization ◽  
Pharmacological Action ◽  
Human Organism ◽  
Chemical Characteristics ◽  
Pharmacological Properties ◽  
Review Of The Literature ◽  
Exclusion Criteria ◽  
Brazilian Propolis

Among the natural products, Brazilian propolis stands out because it is considered a source for the discovery of new bioactive compounds. In the last decade, a new Brazilian propolis has been described, known as red propolis due to its reddish pigment. Since then, numerous studies revealing its major components and their pharmacological activity have been described. Thes, this research had the objective of performing an integrative review of the literature on the biological activity of Brazilian red propolis. Scientific studies in the PubMed, SciElo and LILACS database were reviewed and analyzed using an inductive approach and indirect documentation technique. A total 418 publications were found, and onclusion and exclusion criteria were subsequently applied, selecting a total of 18 articles. The Brazilian propolis presents numerous pharmacological properties, especially the antibacterial, antfugal, antoxidant and anti-inflammatory effects. In addition, the chemical composition of this substance is different from other types of propolis already reported in the literature, presenting flavonoids never before reported. In this way, its chemical characteristics suggest probable therapeutic use for the human organism.

scholarly journals Chemical characteristics of grape juices from different cultivar and rootstock combinations

2014 ◽  
Vol 49 (7) ◽  
pp. 540-545 ◽  
Author(s):  
Rita de Cássia Mirela Resende Nassur ◽  
Giuliano Elias Pereira ◽  
Juliana Alvarenga Alves ◽  
Luiz Carlos de Oliveira Lima
Keyword(s):  
Biogenic Amines ◽  
Sugar Content ◽  
Chemical Characterization ◽  
Principal Component ◽  
Soluble Solids ◽  
Chemical Characteristics ◽  
Total Sugar Content ◽  
Solids Content ◽  
Grape Juices ◽  
Grape Cultivars

The objective of this work was to evaluate the influence of different combinations of grape cultivars and rootstocks on chemical characteristics of grape juices. Six treatments were evaluated, consisting of combinations between the Isabel Precoce and BRS Cora grape cultivars and the 'IAC 766', 'IAC 313', and 'IAC 572' rootstocks. Approximately 10 L of juice were obtained per treatment. Analyses of color, total soluble solids content, pH, anthocyanins, total phenolics, total sugars, and quantification and identification of biogenic amines by HPLC were performed. Biogenic amines, such as putrescine, cadaverine, spermidine, and spermine, were found in all evaluated cultivars. By principal component analysis (PCA), treatments can be divided into two groups, according to the cultivar. Juices obtained from 'Isabel Precoce' are characterized by higher levels of total sugar content and soluble solids; however, juices from 'BRS Cora' are positively correlated with phenolic content, anthocyanins, and color and acidity parameters. The differences found by PCA for juices from the Isabel Precoce and BRS Cora cultivars indicate that, regardless of the rootstock used, the most important factor in the chemical characterization of juices is the grape cultivar.

scholarly journals Metabolomic Profiling of Fresh Goji (Lycium barbarum L.) Berries from Two Cultivars Grown in Central Italy: A Multi-Methodological Approach

Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5412
Author(s):  
Mattia Spano ◽  
Alessandro Maccelli ◽  
Giacomo Di Matteo ◽  
Cinzia Ingallina ◽  
Mariangela Biava ◽  
...  
Keyword(s):  
Amino Acids ◽  
Biological Activity ◽  
Methodological Approach ◽  
Waste Product ◽  
Central Italy ◽  
Ion Cyclotron Resonance ◽  
Lycium Barbarum ◽  
Total Carotenoids ◽  
Lazio Region ◽  
Mg63 Cells

The metabolite profile of fresh Goji berries from two cultivars, namely Big Lifeberry (BL) and Sweet Lifeberry (SL), grown in the Lazio region (Central Italy) and harvested at two different periods, August and October, corresponding at the beginning and the end of the maturation, was characterized by means of nuclear magnetic resonance (NMR) and electrospray ionization Fourier transform ion cyclotron resonance (ESI FT-ICR MS) methodologies. Several classes of compounds such as sugars, amino acids, organic acids, fatty acids, polyphenols, and terpenes were identified and quantified in hydroalcoholic and organic Bligh-Dyer extracts. Sweet Lifeberry extracts were characterized by a higher content of sucrose with respect to the Big Lifeberry ones and high levels of amino acids (glycine, betaine, proline) were observed in SL berries harvested in October. Spectrophotometric analysis of chlorophylls and total carotenoids was also carried out, showing a decrease of carotenoids during the time. These results can be useful not only to valorize local products but also to suggest the best harvesting period to obtain a product with a chemical composition suitable for specific industrial use. Finally, preliminary studies regarding both the chemical characterization of Goji leaves generally considered a waste product, and the biological activity of Big Lifeberry berries extracts was also investigated. Goji leaves showed a chemical profile rich in healthy compounds (polyphenols, flavonoids, etc.) confirming their promising use in the supplements/nutraceutical/cosmetic field. MG63 cells treated with Big Lifeberry berries extracts showed a decrease of iNOS, COX-2, IL-6, and IL-8 expression indicating their significant biological activity.

The Amino Acids and Proteins

PEDIATRICS ◽  
1952 ◽  
Vol 10 (1) ◽  
pp. 112-112
Keyword(s):  
Amino Acids ◽  
Chemical Composition ◽  
Chemical Characteristics ◽  
Physical And Chemical Characteristics ◽  
Wide Range ◽  
Physical And Chemical

This excellent and useful book is a worth while successor to the previous book on proteins and amino acids, edited by Carl A. Schmidt. It contains a wide range of information on chemical composition, physical and chemical characteristics of the amino acids and proteins. In addition there is considerable material on the preparation and/or isolation of these substances. There is a good chapter on the criteria of purity of protein which is useful to those interested in any investigative phase of biology.

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