scholarly journals Enhanced Power Conversion Efficiency of Dye-Sensitized Solar Cells by Band Edge Shift of TiO2 Photoanode

Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1502 ◽  
Author(s):  
Hye Kyeong Sung ◽  
Yeonju Lee ◽  
Wook Hyun Kim ◽  
Sang-Ju Lee ◽  
Shi-Joon Sung ◽  
...  

By simple soaking titanium dioxide (TiO2) films in an aqueous Na2S solution, we could prepare surface-modified photoanodes for application to dye-sensitized solar cells (DSSCs). An improvement in both the open-circuit voltage (Voc) and the fill factor (FF) was observed in the DSSC with the 5 min-soaked photoanode, compared with those of the control cell without any modification. The UV–visible absorbance spectra, UPS valence band spectra, and dark current measurements revealed that the Na2S modification led to the formation of anions on the TiO2 surface, and thereby shifted the conduction band edge of TiO2 in the negative (upward) direction, inducing an increase of 29 mV in the Voc. It was also found that the increased FF value in the surface-treated device was attributed to an elevation in the shunt resistance.

2018 ◽  
Vol 382 ◽  
pp. 369-373
Author(s):  
Usana Mahanitipong ◽  
Preeyapat Prompan ◽  
Rukkiat Jitchati

The four thiocyanate free ruthenium(II) complexes; [Ru(N^N)2(C^N)]PF6were synthesized and characterized for dye sensitized solar cells (DSSCs). The results showed that the broad absorptions covered the visible region from metal to ligand charge transfer (MLCT) were obtained with the main peaks at 560, 490 and 400 nm. The materials were studied DSSC performance under standard AM 1.5. Compound PP1 showed the power conversion efficiency (PCE) at 3.10%, with a short-circuit photocurrent density (Jsc) of 7.99 mA cm-2, an open-circuit photovoltage (Voc) of 563 mV and a high fill factor (ff) of 0.690.


2014 ◽  
Vol 602 (1) ◽  
pp. 111-117 ◽  
Author(s):  
Jong Tae Kim ◽  
Dongyoung Kim ◽  
Hwa-Min Kim ◽  
Chul Gyun Hwang ◽  
Younghwan Kwon ◽  
...  

2011 ◽  
Vol 50 (6) ◽  
pp. 06GF08 ◽  
Author(s):  
Shyam S. Pandey ◽  
Kyung-Young Lee ◽  
Azwar Hayat ◽  
Yuhei Ogomi ◽  
Shuzi Hayase

BIBECHANA ◽  
2015 ◽  
Vol 13 ◽  
pp. 23-28
Author(s):  
Leela Pradhan Joshi

Aluminium doped Zinc Oxide (AZO) seed layers were deposited on Fluorine doped Tin Oxide (FTO) substrates using a spin coating technique. These were then immersed in growth solutions of zinc nitrate, hexamethylenetetramine and distilled water to develop nanoplates of Zinc Oxide (ZnO). The nanostructures of ZnO grown on FTO were studied using x-ray diffraction techniques. Dye-sensitized solar cells (DSSC) were fabricated using two prepared electrodes, one of dye-loaded zinc oxide and another that was platinum coated. The electrolyte used was potassium iodide iodine solution. The performance of the assembled DSCCs was tested by drawing an IV curve. The results showed that the short circuit current and open circuit voltages were about 10 microamperes and 270 millivolts respectively.BIBECHANA 13 (2016) 23-28


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