scholarly journals Effect of Multiplicity Fluctuation in Cobalt Ions on Crystal Structure, Magnetic and Electrical Properties of NdCoO3 and SmCoO3

Molecules ◽  
2020 ◽  
Vol 25 (6) ◽  
pp. 1301 ◽  
Author(s):  
Vyacheslav A. Dudnikov ◽  
Yuri S. Orlov ◽  
Leonid A. Solovyov ◽  
Sergey N. Vereshchagin ◽  
Sergey Yu. Gavrilkin ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Expansion ◽  
Magnetic Susceptibility ◽  
Rare Earth ◽  
Electrical Resistance ◽  
State Change ◽  
Cobalt Ions ◽  
Comparison Of The Results ◽  
Multiplicity Fluctuation ◽  
Volume Thermal Expansion Coefficient

The structural, magnetic, electrical, and dilatation properties of the rare-earth NdCoO3 and SmCoO3 cobaltites were investigated. Their comparative analysis was carried out and the effect of multiplicity fluctuations on physical properties of the studied cobaltites was considered. Correlations between the spin state change of cobalt ions and the temperature dependence anomalies of the lattice parameters, magnetic susceptibility, volume thermal expansion coefficient, and electrical resistance have been revealed. A comparison of the results with well-studied GdCoO3 allows one to single out both the general tendencies inherent in all rare-earth cobaltites taking into account the lanthanide contraction and peculiar properties of the samples containing Nd and Sm.

MAGNETIC PROPERTIES OF R2In (R=Gd, Tb, Er)

1993 ◽  
Vol 07 (01n03) ◽  
pp. 818-821 ◽  
Author(s):  
D. RAVOT ◽  
O. GOROCHOV ◽  
T. ROISNEL ◽  
G. ANDRE ◽  
F. BOUREE-VIGNERON ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Rare Earth ◽  
Low Temperature ◽  
Neutron Diffraction ◽  
Antiferromagnetic State ◽  
Powder Neutron Diffraction ◽  
Magnetic Transport ◽  
The Rare Earth

For all the Rare-Earth (R) the R2In form in the same crystal structure (P63/mmc). These compounds show a great variety of magnetic behaviors. When the temperature decreases, the magnetic susceptibility of Er2InTb2In and Gd2In increases, passes through a maximum then decreases. For Gd2In this behavior was associated with change from a paramagnetic to a ferromagnetic then to an antiferromagnetic state. We have performed magnetic, transport (Tb, Er), Mössbauer spectroscopy (Er) and powder neutron diffraction experiments (Gd, Tb, Er) on these compounds. Unlike Gd2In the resistivity of Tb2In and Er2In does not reveal any anomaly at the temperature where the susceptibility begins to decrease and the Tb2In and Er2In magnetizations show the same behavior at all temperatures in the ordered region. Neutron diffraction experiments reveal ferromagnetic and antiferromagnetic structures at low temperature.

Preparation and Crystal Structure of the Isotypic Carbides Ln3.67TC6 (Ln = rare earth elements; T = Mn, Fe, Ru) and Eu3,16NiC6

1996 ◽  
Vol 51 (2) ◽  
pp. 249-256 ◽  
Author(s):  
Anne M. Witte ◽  
Wolfgang Jeitschko
Keyword(s):  
Crystal Structure ◽  
Magnetic Susceptibility ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Single Crystal ◽  
Crystal Structures ◽  
Variable Parameters ◽  
X Ray ◽  
Arc Melting ◽  
Structure Factors

Abstract The 14 carbides Ln3.67MnC6 (Ln = La-Nd) and Ln3.67TC6 (Ln = La-Nd, Sm; T = Fe, Ru) were prepared from the elemental components by arc-melting and subsequent annealing. Eu3.16NiC6 was obtained from a lithium flux. The crystal structures of these nearly isotypic, hexagonal compounds (P63/m, Z = 2) were determined from single-crystal X-ray data; La3.67- FeC6: a = 878.7(2), c = 535.1(1) pm, R = 0.052 for 548 structure factors and 25 variable parameters; Eu3.16NiC6: a -860.0(1), c = 548.2(2) pm, R = 0.015 for 606 structure factors and 25 variables. The structures differ from the previously reported Gd3Mn2C6 structure by the occupancy of one manganese position by rare earth atoms. Since the lanthanum atoms are larger than the manganese atoms, only two thirds of these manganese positions can be occupied by the lanthanum atoms in La3.67FeC6. Eu3.16NiC6 has similar atomic positions. The C-C bond distances in the C2 pairs are 130(2) and 126.5(5) pm in the La and Eu compounds, respectively. Magnetic susceptibility measurements with a SQUID magnetometer indicate La3.67FeC6 to be Pauli paramagnetic. A test for superconductivity was negative down to 3 K.

Magnetic susceptibility of liquid heavy rare earth metals

1979 ◽  
Vol 40 (C5) ◽  
pp. C5-260-C5-261 ◽  
Author(s):  
M. Müller ◽  
E. Huber ◽  
H.-J. Güntherodt
Keyword(s):  
Magnetic Susceptibility ◽  
Rare Earth ◽  
Rare Earth Metals ◽  
Heavy Rare Earth

Synthesis and crystal structure of (Ca, R)(Mn, Ti)O3 (R, rare earth)

2006 ◽  
Vol 408-412 ◽  
pp. 1173-1176 ◽  
Author(s):  
Migaku Kobayashi ◽  
Ryouko Katsuraya ◽  
Syou Kurita ◽  
Makoto Yamaguchi ◽  
Hiroshisa Satoh ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Rare Earth ◽  
Synthesis And Crystal Structure

Crystal structure, thermal expansion and fluorescence of Sr3–1.5Eu B2+Si1–O8–/2 phosphors

2021 ◽  
Vol 260 ◽  
pp. 124151
Author(s):  
Maria G. Krzhizhanovskaya ◽  
Sergey N. Volkov ◽  
Alexey V. Povolotskiy ◽  
Rimma S. Bubnova ◽  
Olga L. Belousova ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Thermal Expansion

Crystal structure and magnetic ordering of the rare-earth and Cu moments inRBa2Cu2NbO8(R=Nd,Pr)

1993 ◽  
Vol 47 (22) ◽  
pp. 15256-15264 ◽  
Author(s):  
N. Rosov ◽  
J. W. Lynn ◽  
H. B. Radousky ◽  
M. Bennahmias ◽  
T. J. Goodwin ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Rare Earth ◽  
Magnetic Ordering ◽  
The Rare Earth

High-pressure Syntheses and Characterization of the Rare-earth Fluoride Borates RE2(BO3)F3 (RE=Tb, Dy, Ho)

2013 ◽  
Vol 68 (11) ◽  
pp. 1198-1206 ◽  
Author(s):  
Ernst Hinteregger ◽  
Michael Enders ◽  
Almut Pitscheider ◽  
Klaus Wurst ◽  
Gunter Heymann ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Pressure ◽  
Rare Earth ◽  
Monoclinic Space Group ◽  
Rare Earth Fluoride ◽  
Earth Fluoride ◽  
Structure Determinations ◽  
New Compounds ◽  
Rare Earth Fluorides

The new rare-earth fluoride borates RE2(BO3)F3 (RE=Tb, Dy, Ho) were synthesized under highpressure/ high-temperature conditions of 1:5 GPa=1200 °C for Tb2(BO3)F3 and 3:0 GPa=900 °C for Dy2(BO3)F3 and Ho2(BO3)F3 in a Walker-type multianvil apparatus from the corresponding rareearth sesquioxides, rare-earth fluorides, and boron oxide. The single-crystal structure determinations revealed that the new compounds are isotypic to the known rare-earth fluoride borate Gd2(BO3)F3. The new rare-earth fluoride borates crystallize in the monoclinic space group P21/c (Z = 8) with the lattice parameters a=16:296(3), b=6:197(2), c=8:338(2) Å , b =93:58(3)° for Tb2(BO3)F3, a= 16:225(3), b = 6:160(2), c = 8:307(2) Å , b = 93:64(3)° for Dy2(BO3)F3, and a = 16:189(3), b = 6:124(2), c = 8:282(2) Å , β= 93:69(3)° for Ho2(BO3)F3. The four crystallographically different rare-earth cations (CN=9) are surrounded by oxygen and fluoride anions. All boron atoms form isolated trigonal-planar [BO3]3- groups. The six crystallographically different fluoride anions are in a nearly planar coordination by three rare-earth cations.

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