scholarly journals Recent Modification Strategies of MoS2 for Enhanced Electrocatalytic Hydrogen Evolution

Molecules ◽  
2020 ◽  
Vol 25 (5) ◽  
pp. 1136
Author(s):  
Chao Meng ◽  
Xiaodong Chen ◽  
Yuanfeng Gao ◽  
Qianqian Zhao ◽  
Deqiang Kong ◽  
...  

Molybdenum disulfide (MoS2) has been recognized as one of the most promising catalysts to replace Pt for hydrogen evolution reaction (HER) electrocatalysis because of the elemental abundance, excellent catalytic potential, and stability. However, its HER efficiency is still below that of Pt. Recent research advances have revealed that the modification of pristine MoS2 is a very effective approach to boost its HER performance, including improving the intrinsic activity of sites, increasing the number of edges, and enhancing the electrical conductivity. In this review, we focus on the recent progress on the modification strategies of MoS2 for enhanced electrocatalytic hydrogen evolution. Moreover, some urgent challenges in this field are also discussed to realize the large-scale application of the modified-MoS2 catalysts in industry.

2019 ◽  
Vol 7 (36) ◽  
pp. 20579-20583 ◽  
Author(s):  
Xuewei Lang ◽  
Muhammad Abdul Qadeer ◽  
Guoqiang Shen ◽  
Rongrong Zhang ◽  
Sichao Yang ◽  
...  

Co–Mo2N@NC exhibits comparable hydrogen evolution reaction activity with that of Pt/C because of the improvement of intrinsic activity and electrical conductivity.


Author(s):  
Lana Regent ◽  
Maximina Luis-Sunga ◽  
Elena Pastor ◽  
Gonzalo García

Developing sustainable and renewable energy sources is critical as higher and higher global energy and environmental challenges arise. Hydrogen has the highest mass/energy density of any fuel and is considered one of the best sources of clean energy. Water splitting is regarded as one of the most promising solutions for hydrogen production on a large scale. Highly efficient, durable and cost-effective catalysts for hydrogen evolution reaction (HER) are critical in the realization of this goal. Among many materials proposed, graphene-based materials offer some unique properties for HER catalysis. In this review, we present recent progress on development of graphene-based electrocatalysts toward HER throughout the past few years.


Author(s):  
Zhaoming Kang ◽  
Muhammad Arif Khan ◽  
Yanmei Gong ◽  
Rida Javed ◽  
Yuan Xu ◽  
...  

In this review, recent advances in MXenes and MXene-based nanomaterials applied in HER electrocatalysis are overviewed in terms of their synthesis, characterization, functional mechanisms, and HERperformance/optimization.


2021 ◽  
Author(s):  
Lili Fan ◽  
Zixi Kang ◽  
Mengfei Li ◽  
Daofeng Sun

Among various kinds of materials that have been investigated as electrocatalysts for hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and oxygen reduction reaction (ORR), metal-organic frameworks (MOFs) emerge as...


Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 929 ◽  
Author(s):  
Sajjad Hussain ◽  
Kamran Akbar ◽  
Dhanasekaran Vikraman ◽  
Rana Afzal ◽  
Wooseok Song ◽  
...  

To find an effective alternative to scarce, high-cost noble platinum (Pt) electrocatalyst for hydrogen evolution reaction (HER), researchers are pursuing inexpensive and highly efficient materials as an electrocatalyst for large scale practical application. Layered transition metal dichalcogenides (TMDCs) are promising candidates for durable HER catalysts due to their cost-effective, highly active edges and Earth-abundant elements to replace Pt electrocatalysts. Herein, we design an active, stable earth-abundant TMDCs based catalyst, WS(1−x)Sex nanoparticles-decorated onto a 3D porous graphene/Ni foam. The WS(1−x)Sex/graphene/NF catalyst exhibits fast hydrogen evolution kinetics with a moderate overpotential of ~−93 mV to drive a current density of 10 mA cm−2, a small Tafel slope of ~51 mV dec−1, and a long cycling lifespan more than 20 h in 0.5 M sulfuric acid, which is much better than WS2/NF and WS2/graphene/NF catalysts. Our outcomes enabled a way to utilize the TMDCs decorated graphene and precious-metal-free electrocatalyst as mechanically robust and electrically conductive catalyst materials.


Author(s):  
Hanwen Xu ◽  
Jiawei Zhu ◽  
Pengyan Wang ◽  
Ding Chen ◽  
Chengtian Zhang ◽  
...  

Rational design and construction of high-efficiency bifunctional catalysts for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is crucial for large-scale hydrogen production by water splitting. Herein, by a...


2020 ◽  
Vol 7 (14) ◽  
pp. 2000396 ◽  
Author(s):  
Zheng Li ◽  
Ruixiang Ge ◽  
Jianwei Su ◽  
Liang Chen

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