scholarly journals Organic Acids and Polyphenols Determination in Polish Wines by Ultrasound-Assisted Solvent Extraction of Porous Membrane-Packed Liquid Samples

Molecules ◽  
2019 ◽  
Vol 24 (23) ◽  
pp. 4376 ◽  
Author(s):  
Robles ◽  
Fabjanowicz ◽  
Płotka-Wasylka ◽  
Konieczka
Keyword(s):  
Solvent Extraction ◽  
Organic Acids ◽  
Extraction Process ◽  
Porous Membrane ◽  
New Technique ◽  
Extraction Temperature ◽  
Extraction Solvent ◽  
Liquid Samples ◽  
Ultrasound Assisted ◽  
A New Technique

In the near future, Poland is going to have more and more favorable conditions for viticulture. Organic acids and polyphenols are among the most commonly analyzed compounds due to their beneficial properties for human health and their importance in the winemaking process. In this work, a new technique involving ultrasound-assisted solvent extraction of porous membrane-packed liquid samples (UASE-PMLS) was for the first time described and applied for real samples. The methodology based on UASE-PMLS for organic acids and polyphenols in wine samples was optimized and validated. Using the new technique coupled to GC–MS, organic acids and polyphenols were evaluated in Polish wine samples. Extraction solvent, extraction temperature, derivatization time and sample pH were optimized. Chemometric tools were used for data treatment. Good linearity was obtained for the concentration ranges evaluated with r values between 0.9852 and 0.9993. All parameters of method validation (intra- and inter-day precision and matrix effect) were over 80% with coefficient of variation (CV) up to 17%. Recovery was between (92.0 ± 8.5)% and (113 ± 16)%. Finally, green assessment was evaluated using Analytical Eco-Scale and Green Analytical Procedure Index (GAPI). The UASE-PMLS is characterized by many advantages, e.g., the extraction process is fast and easy coupled to GC–MS. Regarding other extraction techniques, the amount of used solvent is minimum, and no waste is generated. Therefore, it is an environmentally friendly technique.

scholarly journals Ultrasound-Assisted Deep Eutectic Solvent Extraction of Anthocyanins from Blueberry Wine Residues: Optimization, Identification, and HepG2 Antitumor Activity

Molecules ◽  
2020 ◽  
Vol 25 (22) ◽  
pp. 5456
Author(s):  
Hongkun Xue ◽  
Jiaqi Tan ◽  
Qian Li ◽  
Jintian Tang ◽  
Xu Cai
Keyword(s):  
Solvent Extraction ◽  
Antitumor Activity ◽  
Deep Eutectic Solvent ◽  
Extraction Process ◽  
Ultrasonic Power ◽  
Extraction Temperature ◽  
Brewing Process ◽  
Ultrasound Assisted ◽  
Optimum Extraction ◽  
Better Than

Blueberry wine residues produced during the wine-brewing process contain abundant anthocyanins and other bioactive compounds. To extract anthocyanins from blueberry wine residues more efficiently, a novel procedure of ultrasound-assisted deep eutectic solvent extraction (UADESE) was proposed in this work. The extraction process was optimized by response surface methodology coupled with genetic algorithm. The optimum extraction parameters to achieve the highest yield of anthocyanins (9.32 ± 0.08 mg/g) from blueberry wine residues by UADESE were obtained at water content of 29%, ultrasonic power of 380 W, extraction temperature of 55 °C, and extraction time of 40 min. The AB-8 macroporous resin combined with Sephadex LH-20 techniques was used to purify the crude extract (CE) obtained under optimum extraction conditions and analyze the anthocyanins composition by HPLC-ESI-MS/MS. The cyanidin-3-rutinoside with purity of 92.81% was obtained. The HepG2 antitumor activity of CE was better than that of the purified anthocyanins component. Moreover, CE could increase the intracellular reactive oxygen species levels and the apoptosis, and arrest HepG2 cells in the S phases. These findings provided an effective and feasible method for anthocyanins extraction, and reduced the environmental burden of this waste.

scholarly journals Development of Membrane-Based Inverted Liquid–Liquid Extraction for the Simultaneous Extraction of Eight Metals in Seawater before ICP-OES Analysis

Molecules ◽  
2020 ◽  
Vol 25 (15) ◽  
pp. 3395
Author(s):  
Muhammad Sajid ◽  
Muhamed Kabeer ◽  
Wail Falath
Keyword(s):  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Extraction Process ◽  
Porous Membrane ◽  
Liquid Extraction ◽  
Icp Oes ◽  
Extraction Solvent ◽  
Liquid Liquid Extraction ◽  
Liquid Samples ◽  
Seawater Samples

In this work, we developed an extraction technique that can handle simple as well as complex matrixed liquid (aqueous) samples. In the standard liquid–liquid extraction, it is quite challenging to deal with complex liquid samples as they may complicate the process of phase separation and may lead to the formation of multiple layers. To resolve this issue, we have proposed a simple but unique idea that suggests the packing of the liquid samples inside a porous membrane bag. The edges of the membrane bag can be sealed using an electrical heat-sealer. The porous membrane bag filled with the liquid sample was immersed in an extraction solvent, and the extraction process was assisted by mechanical shaking. In order to demonstrate the proof of concept, a method was developed for the extraction of metals from seawater samples. The pH-adjusted sample, along with the complexing reagent, was packed inside the porous membrane bag, and the chelated complex was then extracted by immersing and shaking the bag inside the organic solvent. The solvent was then evaporated, and the chelated complex was dissolved/digested in acid with the aid of the heat. The final extract was subjected to Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) analysis. The proposed method was used for extraction of eight metals (Cd, Co, Cu, Mo, Ni, Pb, V and Zn) from seawater samples and good extraction recoveries (75–94%) were obtained.

scholarly journals Ultrasound-Assisted Solvent Extraction of a Porous Membrane Packed Sample for the Determination of Tobacco-Specific Nitrosamines in the Replacement Liquids for E-Cigarettes

Molecules ◽  
2019 ◽  
Vol 24 (24) ◽  
pp. 4618 ◽  
Author(s):  
Paweł Kubica
Keyword(s):  
Solvent Extraction ◽  
Sample Preparation ◽  
Electronic Cigarettes ◽  
Multiple Reaction Monitoring ◽  
Porous Membrane ◽  
Liquid Chromatography Tandem Mass ◽  
Multiple Reaction Monitoring Mode ◽  
Ultrasound Assisted ◽  
Tobacco Specific Nitrosamines

The content of tobacco-specific nitrosamines (TSNAs) possessing carcinogenic properties has been an important area of research since replacement liquids were introduced for e-cigarettes. A method for determining N′-nitrosonornicotine (NNN), 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK), N′-nitrosoanatabine (NAT), and N′-nitrosoanabasine (NAB) in replacement liquids for electronic cigarettes was developed using liquid chromatography–tandem mass spectrometry with electrospray ionisation (HPLC-ESI-MS/MS) in the multiple reaction monitoring mode. The sample preparation of replacement liquids was accomplished via the ultrasound-assisted solvent extraction of a porous membrane packed sample. The sample preparation proved to be successful in extracting the analytes, with recoveries from 87% to 105%, with coefficients of variation < 4.9%. Moreover, the linearity and limits of detection and quantitation (LOD, LOQ), together with repeatability and accuracy, were determined for the developed method. The proposed sample preparation and developed chromatographic method were successfully applied to the determination of TSNAs in 9 replacement liquid samples. The NNK and NNN were found to be most frequently detected (89 and 67%, respectively), with concentration ranges from 1.2–54.3 ng/mL and 4.1–30.2 ng/mL, respectively, while NAT was detected with frequency of 22% with range 1.7–2.5 ng/mL and NAB were found to be below the LOD in all samples.

scholarly journals The “Cello Technique”: A New Technique for Ultrasound-Assisted Calcaneoplasty

2012 ◽  
Vol 1 (1) ◽  
pp. e91-e94 ◽  
Author(s):  
Ivan Rakovac ◽  
Tomislav Madarevic ◽  
Anton Tudor ◽  
Tomislav Prpic ◽  
Branko Sestan ◽  
...  
Keyword(s):  
New Technique ◽  
Ultrasound Assisted ◽  
A New Technique

scholarly journals Accelerated Solvent Extraction as a Green Tool for the Recovery of Polyphenols and Pigments from Wild Nettle Leaves

Processes ◽  
2020 ◽  
Vol 8 (7) ◽  
pp. 803
Author(s):  
Maja Repajić ◽  
Ena Cegledi ◽  
Valentina Kruk ◽  
Sandra Pedisić ◽  
Fırat Çınar ◽  
...  
Keyword(s):  
Solvent Extraction ◽  
Antioxidant Capacity ◽  
Accelerated Solvent Extraction ◽  
Ultrasound Assisted Extraction ◽  
Extraction Solvent ◽  
Green Approach ◽  
Assisted Extraction ◽  
Chlorophylls A And B ◽  
Different Temperatures ◽  
Ultrasound Assisted

This study aimed to investigate the performance of accelerated solvent extraction (ASE) as a green approach for the recovery of polyphenols and pigments from wild nettle leaves (NL). ASE was operated at different temperatures (20, 50, 80 and 110 °C), static times (5 and 10 min) and cycle numbers (1–4) using ethanol (96%) as an extraction solvent. In order to compare the efficiency of ASE, ultrasound assisted extraction (UAE) at 80 °C for 30 min was performed as a referent. Polyphenol and pigment analyses were carried out by HPLC and antioxidant capacity was assessed by ORAC. Seven polyphenols from subclasses of hydroxycinnamic acids and flavonoids, along with chlorophylls a and b and their derivatives and six carotenoids and their derivatives were identified and quantified. Chlorogenic acid was the most abundant polyphenol and chlorophyll a represented the dominant pigment. ASE conditions at 110 °C/10 min/3 or 4 cycles proved to be the optimal for achieving the highest yields of analyzed compounds. In comparison with UAE, ASE showed better performance in terms of yields and antioxidants recovery, hence delivering extract with 60% higher antioxidant capacity. Finally, the potential of NL as a functional ingredient from natural sources can be successfully accessed by ASE.

Ultrasound-assisted aspiration of loculated pneumothorax: A new technique

2015 ◽  
Vol 44 (5) ◽  
pp. 326-330 ◽  
Author(s):  
Søren Helbo Skaarup ◽  
Birgitte Holst Folkersen
Keyword(s):  
New Technique ◽  
Ultrasound Assisted ◽  
A New Technique

Optimization of Extraction Process of Lycopene from Watermelon (Citrullus lanatus) by Response Surface Methodology

2011 ◽  
Vol 140 ◽  
pp. 385-393 ◽  
Author(s):  
Xian Feng Shi ◽  
Yuan Xu ◽  
Yu Hua Li ◽  
Hong Xia Zeng ◽  
Yu Hong Sun
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Citrullus Lanatus ◽  
Extraction Process ◽  
Quadratic Equation ◽  
Raw Material ◽  
Extraction Time ◽  
Solvent Ratio ◽  
Extraction Temperature ◽  
Extraction Solvent

The extraction processing of lycopene from watermelon was investigated in this paper. Based on single factor experiments, response surface methodology (RSM) was adopted to study the key parameters such as number of extraction, extraction temperature, extraction time in order to increase extraction rate of lycopene. A second order quadratic equation was established and the applicability of model and interaction involved factors on predicting the lycopene extracting content was verified. The results indicated that the optimum extraction conditions were hexane (containing 2% dichloromethane) as extraction solvent, ratio of solvent to raw material of 3:1 (mL/g), number of extraction of 2, extraction time of 1.9 h and extraction temperature of 29.8°C. Under these conditions the extracting content of lycopene was 14.71±0.22 mg/kg, which is well in agreement with value predicted by the model.

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