scholarly journals Spectroscopic Methods in the Evaluation of Modified Vegetable Base Oils from Crambe abyssinica

Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3243 ◽  
Author(s):  
Michał Szmatoła ◽  
Justyna Chrobak ◽  
Rafał Grabowski ◽  
Jolanta Iłowska ◽  
Julia Woch ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Vegetable Oil ◽  
Supercritical Co2 ◽  
Spectroscopic Methods ◽  
Spectroscopic Techniques ◽  
Chemical Transformations ◽  
Chemical Changes ◽  
Crambe Abyssinica ◽  
Oxidation Processes ◽  
Ft Ir

Raw vegetable oil from Crambe abyssinica was subjected to oxidative treatment to enhance its viscosity. The oxidation processes were carried out in the presence of N-hydroxyphthalimide with or without supercritical CO2 as a solvent. Four spectroscopic techniques (Raman, UV-VIS, FT-IR, NMR) were applied to assess the chemical changes taking place during the oxidation. Raman and NMR spectroscopy proved best in the assessment of the chemical transformations leading to increased viscosity of the modified vegetable oil.

scholarly journals Preparation and Characterization of Cu (II), Mn(II) and Zn(II)complexes with new sulfamethoxazole Compounds

2017 ◽  
Vol 14 (3) ◽  
pp. 575-581
Author(s):  
Baghdad Science Journal
Keyword(s):  
Magnetic Susceptibility ◽  
Melting Point ◽  
Metal Complexes ◽  
Atomic Absorption ◽  
Spectroscopic Methods ◽  
Aqueous Alcohol ◽  
Spectroscopic Techniques ◽  
Ft Ir ◽  
Ir Spectroscopic

Acetophenone sulfamethoxazole and 3-Nitrobenzophenone sulfamethoxazole were prepared from the reaction of sulfamethoxazole with two ketones. The prepared ligands were identified by (C.H.N) analysis and UV-VIS, FT-IR spectroscopic techniques. Metal complexes of the two ligands were prepared in an aqueous alcohol with Zn (II), Mn (II) and Cu (II) ions with a molar ratio1:1. The proposed general formula for the resulting complexes was [ML.CL2.H2O]H2O .The complexes were characterized by (C.H.N) technique , spectroscopic methods ,conductivity, atomic absorption ,magnetic susceptibility measurements and melting point. According to the results obtained, the suggested geometry is to be octahedral for all the complexes.

scholarly journals The Application of NMR Spectroscopy and Chemometrics in Authentication of Spices

Molecules ◽  
2021 ◽  
Vol 26 (2) ◽  
pp. 382
Author(s):  
Barbara Pacholczyk-Sienicka ◽  
Grzegorz Ciepielowski ◽  
Łukasz Albrecht
Keyword(s):  
Quality Assurance ◽  
Nmr Spectroscopy ◽  
Sample Preparation ◽  
Bioactive Compounds ◽  
Analytical Methods ◽  
Structural Information ◽  
Chemometric Analysis ◽  
Spectroscopic Methods ◽  
Regular Consumption ◽  
No Sample Preparation

Spices and herbs are among the most commonly adulterated food types. This is because spices are widely used to process food. Spices not only enhance the flavor and taste of food, but they are also sources of numerous bioactive compounds that are significantly beneficial for health. The healing effects of spices are connected with their antimicrobial, anti-inflammatory and carminative properties. However, regular consumption of adulterated spices may cause fatal damage to our system because adulterants in most cases are unhealthy. For that reason, the appropriate analytical methods are necessary for quality assurance and to ensure the authenticity of spices. Spectroscopic methods are gaining interest as they are fast, require little or no sample preparation, and provide rich structural information. This review provides an overview of the application of NMR spectroscopy combined with chemometric analysis to determine the quality and adulteration of spices.

scholarly journals Clinoptilolite as a natural, active zeolite catalyst for the chemical transformations of geraniol

2021 ◽  
Author(s):  
Anna Fajdek-Bieda ◽  
Agnieszka Wróblewska ◽  
Piotr Miądlicki ◽  
Jadwiga Tołpa ◽  
Beata Michalkiewicz
Keyword(s):  
Reaction Time ◽  
Nitrogen Adsorption ◽  
Carbon Chain ◽  
Raw Material ◽  
Chemical Transformations ◽  
Renewable Biomass ◽  
Ft Ir ◽  
Catalyst Content ◽  
Favorable Conditions ◽  
Instrumental Methods

AbstractThis work presented the studies with the natural zeolite—clinoptilolite as the catalyst for the isomerization of geraniol. During the research, it turned out that the studied process is much more complicated, and not only isomerization takes place in it, but also dehydration, oxidation, dimerization, cyclization and fragmentation of the carbon chain. Geraniol is an organic raw material which can be obtained not only by a chemical synthesis but also from plants (renewable biomass) by distillation or extraction method, for example a source of geraniol can be a plant—geranium. Before catalytic tests clinoptilolite was characterized by the instrumental methods, such as: XRD, porosity studies—nitrogen adsorption at 77 K, SEM, EDXRF, and FT-IR. Gas chromatography analyses showed that the main products of geraniol isomerization process were 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol. The selectivity of 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol depended on the temperature, catalyst content and reaction time. These parameters were changed in the following ranges: 80–150 °C (temperature), 5–15 wt% (catalyst content) and 15–1440 min. (reaction time). The most favorable conditions for 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol obtaining were: temperature 140 ºC, catalyst content 12.5 wt% and reaction time 180 min. At these conditions, the conversion of geraniol amounted to 98 mol%, and the selectivities of 6,11-dimethyl-2,6,10-dodecatrien-1-ol and thumbergol amounted to 14 and 47 mol%, respectively.

scholarly journals Quantitative analysis of doxorubicin hydrochloride and arterolane maleate by mid IR spectroscopy using transmission and reflectance modes

BMC Chemistry ◽  
2021 ◽  
Vol 15 (1) ◽  
Author(s):  
Ranju Bansal ◽  
Ranjit Singh ◽  
Khushpal Kaur
Keyword(s):  
Quantitative Analysis ◽  
Spectroscopic Methods ◽  
Doxorubicin Hydrochloride ◽  
Intermediate Precision ◽  
Solid Dosage ◽  
Ich Guidelines ◽  
Relative Standard ◽  
Ft Ir ◽  
Solid Bulk ◽  
Ir Spectroscopic

Abstract Background Environment-friendly fast and accurate mid-infrared spectroscopic methods have been developed for the quantitative analysis of doxorubicin hydrochloride (DOX) and arterolane maleate (ALM) in bulk and marketed formulations. Both transmittance and reflectance modes have been used for the analysis and a comparison has been drawn for better accuracy. The analytical methods were validated in accordance with International Council for Harmonisation (ICH) guidelines Results The proposed methods have been successfully developed and validated for the quantification of doxorubicin and arterolane maleate in solid bulk and dosage form. High recovery values in both the modes, while analysing DOX and ALM, indicated good accuracy of the methods. The methods showed excellent repeatability and intermediate precision [% RSD (Relative Standard Deviation < 2.0%]. The assay values of the drugs in solid dosage forms were also found close to the labelled claim. Conclusion The proposed Fourier transform infrared (FT-IR) spectroscopic methods were found to be specific, reproducible, valid and could be used as general methods for the quantification of most of the solid drug preparations such as tablets, capsules and powders.

scholarly journals Probing the Interactions of Porphyrins with Macromolecules Using NMR Spectroscopy Techniques

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1942
Author(s):  
Ilche Gjuroski ◽  
Julien Furrer ◽  
Martina Vermathen
Keyword(s):  
Nmr Spectroscopy ◽  
Photophysical Properties ◽  
Optical Methods ◽  
Spectroscopic Techniques ◽  
Control Mechanisms ◽  
Dynamic Information ◽  
Non Covalent Interactions ◽  
And Control ◽  
And Diffusion ◽  
Covalent Interactions

Porphyrinic compounds are widespread in nature and play key roles in biological processes such as oxygen transport in blood, enzymatic redox reactions or photosynthesis. In addition, both naturally derived as well as synthetic porphyrinic compounds are extensively explored for biomedical and technical applications such as photodynamic therapy (PDT) or photovoltaic systems, respectively. Their unique electronic structures and photophysical properties make this class of compounds so interesting for the multiple functions encountered. It is therefore not surprising that optical methods are typically the prevalent analytical tool applied in characterization and processes involving porphyrinic compounds. However, a wealth of complementary information can be obtained from NMR spectroscopic techniques. Based on the advantage of providing structural and dynamic information with atomic resolution simultaneously, NMR spectroscopy is a powerful method for studying molecular interactions between porphyrinic compounds and macromolecules. Such interactions are of special interest in medical applications of porphyrinic photosensitizers that are mostly combined with macromolecular carrier systems. The macromolecular surrounding typically stabilizes the encapsulated drug and may also modify its physical properties. Moreover, the interaction with macromolecular physiological components needs to be explored to understand and control mechanisms of action and therapeutic efficacy. This review focuses on such non-covalent interactions of porphyrinic drugs with synthetic polymers as well as with biomolecules such as phospholipids or proteins. A brief introduction into various NMR spectroscopic techniques is given including chemical shift perturbation methods, NOE enhancement spectroscopy, relaxation time measurements and diffusion-ordered spectroscopy. How these NMR tools are used to address porphyrin–macromolecule interactions with respect to their function in biomedical applications is the central point of the current review.

Liquid Crystalline Properties of 4,4and#39;-methylenebis(N-(4-Alkanoxybenzylidene)aniline): Synthesis, Characterization, and Theoretical study

2019 ◽  
Vol 41 (6) ◽  
pp. 1107-1107
Author(s):  
Mohammed Taha Yaseen and Abdullah Hussein Kshash Mohammed Taha Yaseen and Abdullah Hussein Kshash
Keyword(s):  
Liquid Crystalline ◽  
Theoretical Study ◽  
Basis Set ◽  
Spectroscopic Techniques ◽  
Benzene Nucleus ◽  
Crystal Properties ◽  
Ft Ir ◽  
Alkoxy Groups ◽  
Gaussian Program ◽  
Mesomorphic Properties

The paper presents six homologues series of Schiff bases ether compounds distinguished by the length of terminal alkoxy groups which substituted on a side benzene nucleus. The above structures were demonstrated through the use of spectroscopic techniques, like FT- IR and 1H-NMR. Polarized hot stage optical microscopy was used to study both mesomorphic properties and phase transitions. The results showed that out of the six compounds only three (B2, B3 and B4) were pure (marble) nematic mesophase, while no liquid crystal properties for (B5, B6 and B7) compounds. The theoretical study for the electronic structures was intended to study the effects of alkyl chain length on the electronic structure by using Gaussian program, DFT and 6-31G as basis set. The theoretical results indicate that there is no effect to the terminal substituted alkoxy groups on the HOMO energies but there is an effect on LUMO energies through decreasing energy for the prepared compounds.

scholarly journals The Influence of Storage Conditions on the Biochemical Composition and Morphology of Dahlia Tubers

2016 ◽  
Vol 44 (2) ◽  
pp. 459-465 ◽  
Author(s):  
Ioana CIOBANU ◽  
Maria CANTOR ◽  
Razvan STEFAN ◽  
Erzsebet BUTA ◽  
Klara MAGYARI ◽  
...  
Keyword(s):  
Biochemical Composition ◽  
Storage Conditions ◽  
Spectroscopic Techniques ◽  
Air Humidity ◽  
Raman Spectroscopic ◽  
Pathogen Invasion ◽  
Ft Ir ◽  
Biometric Measurements ◽  
C 30 ◽  
Ft Raman

The aim of this study was to assess by means of biometric measurements and FT-IR and FT-Raman spectroscopic techniques the influence of storage conditions on the morphology and biochemical composition of Dahlia tubers. Investigated samples belong to ‘Kennemerland’ and ‘Red Pygmy’ cultivars of the Dahlia hybrida species, which were preserved over winterat 5-8 °C, 30-40% air humidity in different substrates: sand, sand and sawdust, peat and sawdust. The biometric parameters revealed that the peat and sawdust substrate is the most appropriate one for tubers storage, whereas the sand substrate is the least suitable one. The inulin signature was evidenced in all tuber samples as well as the changes of biochemical composition induced by different storage conditions. The analysis of the FT-IR and FT-Raman spectra demonstrated that the inulinaccumulation inside the tubers is favourably influenced by the sand storage, and depends on the cultivar type. Moreover, it was established that the peat and sawdust substrate favours the polyacetylene formation inside the tubers probably because it facilitates the occurrence and development of pathogens inside the tuber. It was also found that the polyacetylene concentration increased, which is associated with the plant response to the pathogen invasion, depends on the cultivar type.

scholarly journals Characterization of the synthetic cannabinoid MDMB-CHMCZCA

2016 ◽  
Vol 12 ◽  
pp. 2808-2815 ◽  
Author(s):  
Carina Weber ◽  
Stefan Pusch ◽  
Dieter Schollmeyer ◽  
Sascha Münster-Müller ◽  
Michael Pütz ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Nmr Spectroscopy ◽  
Hplc Method ◽  
Enantiomeric Purity ◽  
Synthetic Cannabinoid ◽  
Spectroscopic Techniques ◽  
Chiral Hplc ◽  
Tandem Mass ◽  
Synthetic Sample

The synthetic cannabinoid MDMB-CHMCZCA was characterized by various spectroscopic techniques including NMR spectroscopy and tandem mass spectrometry. The synthetic sample was found to be of S-configuration by VCD spectroscopy and comparison of the data with DFT calculations, while ECD spectroscopy was found to be inconclusive in this case. The enantiomeric purity of samples from test purchases and police seizures was assessed by a self-developed chiral HPLC method.

Microwave-assisted solvent-free synthesis and spectral and structural characterization of cyclotriphosphazene hexakis(o-tolylamide)

2018 ◽  
Vol 73 (12) ◽  
pp. 999-1003 ◽  
Author(s):  
Mohammad Hakimi ◽  
Homeyra Rezaei ◽  
Keyvan Moeini ◽  
Heidar Raissi ◽  
Vaclav Eigner ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Microwave Irradiation ◽  
Stacking Interactions ◽  
X Ray Diffraction ◽  
Aromatic Rings ◽  
X Ray ◽  
Microwave Assisted ◽  
Ft Ir ◽  
Solvent Free Synthesis

AbstractA new cyclotriphosphazene, 2,2,4,4,6,6-hexakis (o-tolylamono)-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine (MPAP), was prepared using microwave irradiation and identified by elemental analysis, FT-IR, Raman, 31P NMR spectroscopy, and single-crystal X-ray diffraction. In the crystal, in addition to hydrogen bonds, the network is further stabilized by inter- and intramolecular π–π stacking interactions between aromatic rings.

Sign in / Sign up

Export Citation Format

Share Document