scholarly journals Chiral Separation of the Phenylglycinol Enantiomers by Stripping Crystallization

Molecules ◽  
2018 ◽  
Vol 23 (11) ◽  
pp. 2901 ◽  
Author(s):  
Lie-Ding Shiau
Keyword(s):  
Phase Transformation ◽  
Recovery Ratio ◽  
Operating Pressure ◽  
Melt Crystallization ◽  
Cooling Process ◽  
Initial Concentration ◽  
Crystalline Product ◽  
Three Phase ◽  
Solid Liquid ◽  
Low Pressures

Stripping crystallization (SC) is introduced in this work for chiral purification of R-phenylglycinol from the enantiomer mixture with an initial concentration ranging from 0.90 to 0.97. As opposed to the solid–liquid transformation in melt crystallization, the three-phase transformation occurs in SC at low pressures during the cooling process. SC combines melt crystallization and vaporization to produce a crystalline product and mixture vapor from a mixture melt due to the three-phase transformation. Thermodynamic calculations were applied to determine the operating pressure for the three-phase transformation during the cooling process in the SC experiments. To consider the possible deviations between the calculated and the actual three-phase transformation conditions, the product purity and the recovery ratio of R-phenylglycinol were investigated within a range of operating pressures during the cooling process.

Two-Dimensional Transient Heat Transfer Model for High-Temperature Laser-Scanning Confocal Microscopy

2021 ◽  
Author(s):  
Dasith Liyanage ◽  
Suk-Chun Moon ◽  
Ajith S. Jayasekare ◽  
Abheek Basu ◽  
Madeleine Du Toit ◽  
...  
Keyword(s):  
Heat Transfer ◽  
Phase Transformation ◽  
High Temperature ◽  
Laser Scanning ◽  
Laser Scanning Confocal Microscopy ◽  
Transfer Model ◽  
Two Dimensional ◽  
Scanning Confocal Microscopy ◽  
Solid Liquid Interface ◽  
Solid Liquid

Abstract High-temperature laser-scanning confocal microscopy (HT-LSCM) has proven to be an excellent experimental technique through in-situ observations of high temperature phase transformation to study kinetics and morphology using thin disk steel specimens. A 1.0 kW halogen lamp, within the elliptical cavity of the HT-LSCM furnace radiates heat and imposes a non-linear temperature profile across the radius of the steel sample. This local temperature profile when exposed at the solid/liquid interface determines the kinetics of solidification and phase transformation morphology. A two-dimensional numerical heat transfer model for both isothermal and transient conditions is developed for a concentrically solidifying sample. The model can accommodate solid/liquid interface velocity as an input parameter under concentric solidification with cooling rates up to 100 K/min. The model is validated against a commercial finite element analysis software package, Strand7, and optimized with experimental data obtained under near-to equilibrium conditions. The validated model can then be used to define the temperature landscape under transient heat transfer conditions.

A three-phase solid-liquid-gas slug flow mechanistic model coupling hydrate dispersion formation with heat and mass transfer

2018 ◽  
Vol 178 ◽  
pp. 222-237 ◽  
Author(s):  
Carlos L. Bassani ◽  
Fausto A.A. Barbuto ◽  
Amadeu K. Sum ◽  
Rigoberto E.M. Morales
Keyword(s):  
Mass Transfer ◽  
Heat And Mass Transfer ◽  
Slug Flow ◽  
Mechanistic Model ◽  
Model Coupling ◽  
Three Phase ◽  
Solid Liquid

Numerical Modeling of Microporosity Formation in Aluminum-Rich Aluminum-Copper Alloys in Microgravity Conditions

2000 ◽  
Author(s):  
M. Xiong ◽  
A. V. Kuznetsov
Keyword(s):  
Copper Alloys ◽  
Heat Transfer Fluid ◽  
Gas Phases ◽  
Alloy Casting ◽  
Cu Alloy ◽  
Aluminum Copper Alloys ◽  
Three Phase ◽  
Microgravity Conditions ◽  
Parametric Analyses ◽  
Solid Liquid

Abstract The microporosity formation in a vertical unidirectionally solidifying Al-4.1%Cu alloy casting is modeled in both microgravity and standard gravity as well as in the conditions of decreased (Moon, Mars) and increased (Jupiter) gravity. Due to the unique opportunities offered by a low-gravity environment (absence of metallostatic pressure and of natural convection in the solidifying alloy) future microgravity experiments will significantly contribute to attaining a better physical understanding of the mechanisms of microporosity formation. One of the aims of the present theoretical investigation is to predict what microporosity patterns will look like in microgravity in order to help plan a future microgravity experiment. To perform these simulations, the authors suggest a novel three-phase model of solidification that accounts for the solid, liquid, and gas phases in the mushy zone. This model accounts for heat transfer, fluid flow, macrosegregation, and microporosity formation in the solidifying alloy. Special attention is given to the investigation of the influence of microporosity formation on the inverse segregation. Parametric analyses for different initial hydrogen concentrations and different gravity conditions are carried out.

Dependence of the Contact Angle on Adsorption at the Solid-Liquid Interface

2010 ◽  
Author(s):  
C. A. Ward
Keyword(s):  
Surface Tension ◽  
Contact Angle ◽  
Pressure Range ◽  
Line Tension ◽  
Liquid Interface ◽  
Fluid Interfaces ◽  
Phase Line ◽  
Three Phase ◽  
Solid Liquid Interface ◽  
Solid Liquid

A method for determining the surface tension of solid-fluid interfaces has been proposed. For a given temperature and fluid-solid combination, these surface tensions are expressed in terms of material properties that can be determined by measuring the amount of vapor adsorbed on the solid surface as a function of xV, the ratio of the vapor-phase pressure to the saturation-vapor pressure. The thermodynamic concept of pressure is shown to be in conflict with that of continuum mechanics, but is supported experimentally. This approach leads to the prediction that the contact angle, θ, can only exist in a narrow pressure range and that in this pressure range, the solid-vapor surface tension is constant and equal to the surface tension of the liquid-vapor interface, γLV. The surface tension of the solid-liquid interface, γSL, may be expressed in terms of measurable properties, γLV and θ: γSL = γLV(1 − cosθ). The value of θ is predicted to depend on both the pressure in the liquid at the three-phase, line x3L, and the three-phase line curvature, Ccl. We examine these predictions using sessile water droplets on a polished Cu surface, maintained in a closed, constant volume, isothermal container. The value of θ is found to depend on the adsorption at the solid-liquid interface, nSL = nSL(x3L,Ccl). The predicted value of θ is compared with that measured, and found to be in close agreement, but no effect of line tension is found.

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