scholarly journals Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry

Molecules ◽  
2017 ◽  
Vol 22 (5) ◽  
pp. 780 ◽  
Author(s):  
◽  
◽  
Keyword(s):  
Transition Metal ◽  
Hypervalent Iodine ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
High Valent

High valent transition metal chemistry. Synthesis and characterization of an intermediate-spin iron(IV) complex of a strong .pi.-acid ligand

1992 ◽  
Vol 114 (22) ◽  
pp. 8724-8725 ◽  
Author(s):  
Terrence J. Collins ◽  
Brian G. Fox ◽  
Zheng Guo Hu ◽  
Kimberly L. Kostka ◽  
Eckard Munck ◽  
...  
Keyword(s):  
Transition Metal ◽  
Synthesis And Characterization ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
Acid Ligand ◽  
Intermediate Spin ◽  
High Valent

scholarly journals Alkene Difunctionalization Using Hypervalent Iodine Reagents: Progress and Developments in the Past Ten Years

Molecules ◽  
2019 ◽  
Vol 24 (14) ◽  
pp. 2634 ◽  
Author(s):  
Lee ◽  
Choi ◽  
Hong
Keyword(s):  
Organic Chemistry ◽  
Transition Metal ◽  
Hypervalent Iodine ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
The Past ◽  
Catalytic Asymmetric ◽  
Alkene Difunctionalization

Hypervalent iodine reagents are of considerable relevance in organic chemistry as they can provide a complementary reaction strategy to the use of traditional transition metal chemistry. Over the past two decades, there have been an increasing number of applications including stoichiometric oxidation and catalytic asymmetric variations. This review outlines the main advances in the past 10 years in regard to alkene heterofunctionalization chemistry using achiral and chiral hypervalent iodine reagents and catalysts.

High-valent transition metal chemistry. Moessbauer and EPR studies of high-spin (S = 2) iron(IV) and intermediate-spin (S = 3/2) iron(III) complexes with a macrocyclic tetraamido-N ligand

1993 ◽  
Vol 115 (15) ◽  
pp. 6746-6757 ◽  
Author(s):  
Kimberly L. Kostka ◽  
Brian G. Fox ◽  
Michael P. Hendrich ◽  
Terrence J. Collins ◽  
Clifton E. F. Rickard ◽  
...  
Keyword(s):  
Transition Metal ◽  
High Spin ◽  
Transition Metal Chemistry ◽  
Metal Chemistry ◽  
Intermediate Spin ◽  
High Valent

Transition metal chemistry in synthetically viable alkaline earth complexes M(Cp)3– (M = Ca, Sr, Ba)

2021 ◽  
Author(s):  
Bin Huo ◽  
Rui Sun ◽  
Bo Jin ◽  
Lingfei Hu ◽  
Jian-Hong Bian ◽  
...  
Keyword(s):  
Transition Metal ◽  
Oxidation State ◽  
Alkaline Earth ◽  
Transition Metal Chemistry ◽  
Metal Chemistry

We predicted the stable alkaline earth complexes M(Cp)3– (M = Ca, Sr, Ba; Cp = cyclopentadienyl), where the M centers were in their stable +2 oxidation state and mimicked the...

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