scholarly journals Cathodic Aromatic C,C Cross-Coupling Reaction via Single Electron Transfer Pathway

Molecules ◽  
2017 ◽  
Vol 22 (3) ◽  
pp. 413 ◽  
Author(s):  
Yang Qu ◽  
Hiroyuki Tateno ◽  
Yoshimasa Matsumura ◽  
Tsuneo Kashiwagi ◽  
Mahito Atobe
Keyword(s):  
Electron Transfer ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Electron Transfer Pathway ◽  
Cross Coupling Reaction

Improved Procedure for Single-electron-transfer-induced Grignard Cross-coupling Reaction

2014 ◽  
Vol 43 (6) ◽  
pp. 922-924 ◽  
Author(s):  
Eiji Shirakawa ◽  
Keisho Okura ◽  
Nanase Uchiyama ◽  
Takuya Murakami ◽  
Tamio Hayashi
Keyword(s):  
Electron Transfer ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Cross Coupling Reaction

ChemInform Abstract: Improved Procedure for Single-Electron-Transfer-Induced Grignard Cross-Coupling Reaction.

ChemInform ◽  
2015 ◽  
Vol 46 (5) ◽  
pp. no-no
Author(s):  
Eiji Shirakawa ◽  
Keisho Okura ◽  
Nanase Uchiyama ◽  
Takuya Murakami ◽  
Tamio Hayashi
Keyword(s):  
Electron Transfer ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Cross Coupling Reaction

Microfluidic electrochemistry for single-electron transfer redox-neutral reactions

Science ◽  
2020 ◽  
Vol 368 (6497) ◽  
pp. 1352-1357 ◽  
Author(s):  
Yiming Mo ◽  
Zhaohong Lu ◽  
Girish Rughoobur ◽  
Prashant Patil ◽  
Neil Gershenfeld ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Molecular Diffusion ◽  
Microfluidic Channel ◽  
Cross Coupling ◽  
Reactive Intermediates ◽  
Single Electron ◽  
Visible Light Photocatalysis ◽  
Single Electron Transfer ◽  
Selective Transformation ◽  
Crystal Compound

Electrochemistry offers opportunities to promote single-electron transfer (SET) redox-neutral chemistries similar to those recently discovered using visible-light photocatalysis but without the use of an expensive photocatalyst. Herein, we introduce a microfluidic redox-neutral electrochemistry (μRN-eChem) platform that has broad applicability to SET chemistry, including radical-radical cross-coupling, Minisci-type reactions, and nickel-catalyzed C(sp2)–O cross-coupling. The cathode and anode simultaneously generate the corresponding reactive intermediates, and selective transformation is facilitated by the rapid molecular diffusion across a microfluidic channel that outpaces the decomposition of the intermediates. μRN-eChem was shown to enable a two-step gram-scale electrosynthesis of a nematic liquid crystal compound, demonstrating its practicality.

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