scholarly journals Ore Genesis of the Chuduoqu Pb-Zn-Cu Deposit in the Tuotuohe Area, Central Tibet: Evidence from Fluid Inclusions and C–H–O–S–Pb Isotopes Systematics

Minerals ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 285 ◽  
Author(s):  
Yong-Gang Sun ◽  
Bi-Le Li ◽  
Feng-Yue Sun ◽  
Ye Qian ◽  
Run-Tao Yu ◽  
...  

The Chuduoqu Pb-Zn-Cu deposit is located in the Tuotuohe area in the northern part of the Sanjiang Metallogenic Belt, central Tibet. The Pb-Zn-Cu ore bodies in this deposit are hosted mainly by Middle Jurassic Xiali Formation limestone and sandstone, and are structurally controlled by a series of NWW trending faults. In this paper, we present the results of fluid inclusions and isotope (C, H, O, S, and Pb) investigations of the Chuduoqu deposit. Four stages of hydrothermal ore mineralization are identified: quartz–specularite (stage I), quartz–barite–chalcopyrite (stage II), quartz–polymetallic sulfide (stage III), and quartz–carbonate (stage IV). Two types of fluid inclusions are identified in the Chuduoqu Pb-Zn-Cu deposit: liquid-rich and vapor-rich. The homogenization temperatures of fluid inclusions for stages I–IV are 318–370 °C, 250–308 °C, 230–294 °C, and 144–233 °C, respectively. Fluid salinities range from 2.07 wt. % to 11.81 wt. % NaCl equivalent. The microthermometric data indicate that the fluid mixing and cooling are two important mechanisms for ore precipitation. The H and O isotopic compositions of quartz indicate a primarily magmatic origin for the ore-forming fluids, with the proportion of meteoric water increasing over time. The C and O isotopic compositions of carbonate samples indicate that a large amount of magmatic water was still involved in the final stage of mineralization. The S and Pb isotopic compositions of sulfides, demonstrate that the ore minerals have a magmatic source. On a regional basis, the most likely source of the metallogenic material was regional potassium-enriched magmatic hydrothermal fluid. Specifically for the Chuduoqu Pb-Zn-Cu deposit, the magmatic activity of a syenite porphyry was the likely heat source, and this porphyry also provided the main metallogenic material for the deposit. Mineralization took place between 40 and 24 Ma. The Chuduoqu deposit is a mesothermal hydrothermal vein deposit and was formed in an extensional environment related to the late stage of intracontinental orogenesis resulting from India–Asia collision. The determination of the deposit type and genesis of Chuduoqu is important because it will inform and guide further exploration for hydrothermal-type Pb and Zn deposits in the Tuotuohe area and in the wider Sanjiang Metallogenic Belt.

2021 ◽  
Vol 9 ◽  
Author(s):  
Tong Ha Lee ◽  
Jung Hun Seo ◽  
Bong Chul Yoo ◽  
Bum Han Lee ◽  
Seung Hee Han ◽  
...  

Haman, Gunbuk, and Daejang deposits are neighboring vein-type hydrothermal Cu deposits located in the SE part of the Korean Peninsula. These three deposits are formed by magmatic-hydrothermal activity associated with a series of Cretaceous granodioritic intrusions of the Jindong Granitoids, which have created a series of veins and alterations in a hornfelsed shale formation. The copper deposits have common veining and alteration features: 1) a pervasive chlorite-epidote alteration, cut by 2) Cu-Pb-Zn-bearing quartz veins with a tourmaline-biotite alteration, and 3) the latest barren calcite veins. Chalcopyrite, pyrite, and pyrrhotite are common ore minerals in the three deposits. Whereas magnetite is a dominant mineral in the Haman and Gunbuk deposits, no magnetite is present, but sphalerite and galena are abundant in the Daejang deposit. Ore-bearing quartz veins have three types of fluid inclusions: 1) liquid-rich, 2) vapor-rich, and 3) brine inclusions. Hydrothermal temperatures obtained from the brine inclusion assemblages are about 340–600, 250–500, and 320–460°C in the Haman, Gunbuk, and Daejang deposits, respectively. The maximum temperatures (from 460 to 600°C) recorded in the fluid inclusions of the three deposits are higher than those of the Cu ore precipitating temperature of typical porphyry-like deposits (from 300 to 400°C). Raman spectroscopy of vapor inclusions showed the presence of CO2 and CH4 in the three deposits, which indicates relatively reduced hydrothermal conditions as compared with typical porphyry deposits. The Rb/Sr ratios and Cs concentrations of brine inclusions suggest that the Daejang deposit was formed by a later and more fractionated magma than the Haman and Gunbuk deposits, and the Daejang deposit has lower Fe/Mn ratios in brine inclusions than the Haman and Gunbuk deposits, which indicates contrasting redox conditions in hydrothermal fluids possibly caused by an interaction with a hosting shale formation. In brines, concentrations of base metals do not change significantly with temperature, which suggests that significant ore mineralization precipitation is unlikely below current exposure levels, especially at the Haman deposit. Ore and alteration mineral petrography and fluid inclusions suggest that the Haman deposit was formed near the top of the deep intrusion center, whereas the Gunbuk deposit was formed at a shallower intrusion periphery. The Daejang deposit was formed later at a shallow depth by relatively fractionated magma.


2020 ◽  
Vol 28 (1) ◽  
pp. 210-218
Author(s):  
Štefan Čík ◽  
Martin Chovan ◽  
Juraj Majzlan

Ore mineralization in small Sb-Au occurrences Lomnistá, Husárka and Suchá dolina (Nízke Tatry Mts., Western Carpathians) was investigated by reflected-light microscopy, electron microprobe, fluid inclusion measurements, identification of host rock alteration and secondary minerals. Hydrothermal Sb-Au mineralization was formed during the arsenopyrite-pyrite-gold and stibnite-Pb-Sb-sulfosalts stages. The first stage of mineralization consists of arsenopyrite, pyrite, and quartz, but gold, typical for this stage in the Nízke Tatry Mts. is missing. Stibnite and zinkenite are dominant in the following stage in Lomnistá and Husárka. Berthierite and jamesonite are frequent in Suchá dolina. Other ore minerals identified here are sphalerite, chalcostibite, chalcopyrite, cinnabar, tetrahedrite-(Hg) at Lomnistá and Husárka and pyrrhotite, chalcostibite, tetrahedrite-(Fe), chalcopyrite, antimony, and gold in Suchá dolina. Identified secondary minerals are valentinite and stibiconite. Stibnite, gold, and other ore minerals were found in heavy-mineral fractions from alluvial sediments, pointing at short transport from the primary sources. Two quartz samples, thought to be related to stibnite or berthierite, contained two-phase fluid inclusions with salinity of 10 - 20 wt.% NaCl eq. The total homogenization temperatures are 230 - 330 ºC in Lomnistá and 200 - 260 ºC in Suchá dolina.


Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 592
Author(s):  
Shunda Li ◽  
Chuan Chen ◽  
Lingling Gao ◽  
Fang Xia ◽  
Xuebing Zhang ◽  
...  

The Kuergasheng Pb–Zn deposit is located in the Western Tianshan Orogen, Xinjiang Province, China. The ore bodies are mainly hosted in sandstone of the Tuosikuertawu Formation and are controlled by NW-trending faults. Three paragenetic stages were identified: early pyrite–chalcopyrite–quartz veins (stage 1), middle galena–sphalerite–quartz veins (stage 2), and late sulfide-poor calcite–quartz veins (stage 3). Fluid inclusions (FIs) include liquid-rich aqueous (LV-type), vapor-rich aqueous (VL-type), halite-bearing (S-type), and monophase liquid aqueous (L-type). Homogenization temperatures for FIs from stages 1–3 are 221–251, 173–220, and 145–172 °C, respectively. Stage 1 fluids in LV-, VL-, and S-type FIs yield salinities of 6.2–9.6, 1.7–3.1, and 32.7–34.9 wt % NaCl equiv., respectively. Stage 2 fluids in LV- and S-type FIs have salinities of 5.1–7.9 and 31.9–32.1 wt % NaCl equiv., respectively. Stage 3 fluids in LV- and L-type FIs have salinities of 3.4–5.9 wt % NaCl equiv. Oxygen, hydrogen, and carbon isotopic data (δ18OH2O = −7.7 to 1.7‰, δDH2O = −99.2 to −83.1‰, δ13CH2O = −16.6 to 9.1‰) indicate that the ore-forming fluids have a hybrid origin —an initial magmatic source with input of meteoric water becoming dominant in the later stage. Sulfur and lead isotopic data for galena (δ34S = 5.6 to 6.9‰, 206Pb/204Pb = 18.002–18.273, 207Pb/204Pb = 15.598–15.643, 208Pb/204Pb = 38.097–38.209) reveal that the ore-forming materials were mainly derived from the Beidabate intrusive body and the Tuosikuertawu Formation.


2021 ◽  
Vol 54 (1E) ◽  
pp. 1-18
Author(s):  
Toe Oo ◽  
Agung Harijoko ◽  
Lucas Setijadji

The Kyaukmyet prospect is one of the principal epithermal gold prospects in the Monywa District, Central Myanmar; its gold- and base metal-bearing quartz veins contain around 3 g/t gold. Ore minerals are mainly hosted by volcanic and volcaniclastic rocks of the Late Oligocene to Middle Miocene Magyigon Formation. The distribution of magmatic intrusions in the area is controlled by ENE-WSW trending faults; these faults are likely related to ore mineralization. Common ore minerals at the Kyaukmyet prospect include pyrite, sphalerite, galena, chalcopyrite, and electrum. They occur in mineralized crustiform-textured brecciated quartz veins and banded (colloform) and massive quartz veins. Mineralized rock is accompanied by silicification and propylitic and argillic alterations. The alteration mineral assemblages include quartz, adularia, calcite, chlorite, illite/smectite, sericite, and illite. Fluid inclusions in the quartz veins have homogenization temperatures ranging from 148 °C to 304 °C and salinities from 0.35 wt % to 2.75 wt % NaCl equiv. The quartz in the mineralized quartz veins was most likely precipitated at a depth ranges165-256 m below the paleosurface. The precipitation of gold at the Kyaukmyet prospect may have been formed by mixing large amounts of meteoric fluid with small amounts of magmatic fluid. The coexistence of liquid-rich and vapor-rich inclusions and presence of adularia and bladed calcite indicate that fluid boiling is caused the main mechanism of ore formation. The vein textures, ore mineral assemblages, alteration minerals and fluid inclusion data suggest that the Kyaukmyet prospect is a polymetallic low-sulfidation epithermal gold deposit.


2017 ◽  
Vol 743 ◽  
pp. 417-421 ◽  
Author(s):  
Vasilii Ivanovich Leontev ◽  
Yackov Yur’evich Bushuev

The Podgolechnoe deposit, which belongs to the alkalic-type (A-type) epithermal gold-ore deposits, lies in the Central Aldan ore district (Russia). Gold-ore mineralization is associated with a volcano-plutonic complex made of rocks of the monzonite-syenite formation (J3–K1). The ore bodies are localized in the crushing zones developed after crystalline schists, gneisses, and granites of the crystalline basement complexes (Ar–Pr). Metasomatic alterations in host rocks have potassic specialization. Vein ore minerals are adular, fluorite, roscoelite, sericite, and carbonate. Ore minerals are pyrite, galena, sphalerite, cinnabar, brannerite, monazite, bismuth telluride, stutzite, hessite, petzite, montbraite, and native gold. The deposit has been explored as a gold-ore deposit, however, due to complex composition of ores there is a need to reveal the possibilities of the integrated development of this deposit. This could provide for a reserve increment and an increase in the gross recoverable value of ores due to the extraction of associated components.


2016 ◽  
Vol 11 (2) ◽  
pp. 103-115
Author(s):  
Euis Tintin Yuningsih, ST., MT., Ph.D

Toya-Takarada mine is Au- and Ag-rich Kuroko-type deposit located in Takarada, Toya-mura, southwest Hokkaido, Japan. The deposits were hosted in rhyolitic tuff and mudstone of Middle Miocene age. Ore samples of fine-grained black ore, vuggy black-yellow ore, granular vuggy black ore, quartz-sulfide ore and massive quartz-barite ore were studied to identify the ore minerals association in the Toya-Takarada mine. The ore minerals are dominated by sphalerite, galena, chalcopyrite and pyrite with fewer amounts of electrum, tetrahedrite-tennantite, and other sulfosalt minerals with secondary mineral of covellite.The quantitative chemical analysis of ore minerals by EPMA indicated that FeS contents in sphalerite is low (0.3-1.2 mol.%) in all kinds of ore samples. Small grains of electrum as inclusions in pyrite are identified in vuggy black-yellow ore with Ag content around 32-33 atm %.In general, the silver minerals in Kuroko-type deposits occurred mainly in the black and yellow ores zone dominantly composed of sphalerite, galena, pyrite, chalcopyrite and barite as a form of electrum and/or argentian tetrahedrite-tennantite series. Thus, the massive quartz-barite ore sample of Toya-Takarada mine are also contain some rare silver sulfosalt minerals such as proustite, Cu-rich pearceite, geocronite-jordanite and fizelyite. Those minerals were found together in association with sphalerite. It seems that sphalerite was crystallized first followed by proustite and Cu-rich pearceite, then geocronite-jordanite and fizelyite are crystallized later.Sphalerites from quartz-sulfide ore of Toya-Takarada contain some fluid inclusions and measured homogenization temperatures are in the range of 164-247°C (av. 208°C) with salinity ranging from 1.9 to 4.7 wt.% NaClequiv. (av. 3.9 wt.% NaClequiv.). The mineral assemblage, iron content in sphalerite and silver content in electrum were indicated that sulfur fugacity was slightly higher during ore mineralization in Toya-Takarada mine.   


Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 725
Author(s):  
Ludmila B. Damdinova ◽  
Bulat B. Damdinov

This article discusses the peculiarities of mineral composition and a fluid inclusions (FIs further in the text) study of the Kholtoson W and Inkur W deposits located within the Dzhida W-Mo ore field (Southwestern Transbaikalia, Russia). The Mo mineralization spatially coincides with the apical part of the Pervomaisky stock (Pervomaisky deposit), and the W mineralization forms numerous quartz veins in the western part of the ore field (Kholtoson vein deposit) and the stockwork in the central part (Inkur stockwork deposit). The ore mineral composition is similar at both deposits. Quartz is the main gangue mineral; there are also present muscovite, K-feldspar, and carbonates. The main ore mineral of both deposits is hubnerite. In addition to hubnerite, at both deposits, more than 20 mineral species were identified; they include sulfides (pyrite, chalcopyrite, galena, sphalerite, bornite, etc.), sulfosalts (tetrahedrite, aikinite, stannite, etc.), oxides (scheelite, cassiterite), and tellurides (hessite). The results of mineralogical and fluid inclusions studies allowed us to conclude that the Inkur W and the Kholtoson W deposits were formed by the same hydrothermal fluids, related to the same ore-forming system. For both deposits, the fluid inclusion homogenization temperatures varied within the range ~195–344 °C. The presence of cogenetic liquid- and vapor-dominated inclusions in the quartz from the ores of the Kholtoson deposit allowed us to estimate the true temperature range of mineral formation as 413–350 °C. Ore deposition occurred under similar physical-chemical conditions, differing only in pressures of mineral formation. The main factors of hubnerite deposition from hydrothermal fluids were decreases in temperature.


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