scholarly journals The Tocantinzinho Paleoproterozoic Porphyry-Style Gold Deposit, Tapajós Mineral Province (Brazil): Geology, Petrology and Fluid Inclusion Evidence for Ore-Forming Processes

Minerals ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 29 ◽  
Author(s):  
Adriana Araújo Castro Lopes ◽  
Márcia Abrahão Moura
Keyword(s):  
Gold Deposit ◽  
Meteoric Water ◽  
Gold Deposits ◽  
Magmatic Fluid ◽  
Calc Alkaline ◽  
Alkaline Granite ◽  
Volcanic Arc ◽  
Primary Fluid ◽  
Intrusive Suite ◽  
Phyllic Alteration

The Tocantinzinho gold deposit, located in the Tapajós Mineral Province, Amazonia, Brazil, is considered the largest gold deposit in the region. It is a stockwork-disseminated gold deposit, hosted in a 1982 ± 8 Ma hydrothermalized monzogranite of the Creporizão Intrusive Suite, with petrographic and geochemical characteristics of volcanic arc to post-collisional granites. Gold is mainly associated with phyllic alteration. Primary fluid inclusions trapped in the mineralization stages are H2O–NaCl and unsaturated and homogenize either to the vapor or to the liquid with Th(t) of 300–430 °C, salinity of 2–16 wt % NaCl eq. and density from 0.43 to 0.94 g/cm3. At these conditions, Au is expected to be transported as Au(HS)2− complexes and ore is deposited as the result of boiling in the first mineralizing stages and of mixing between magmatic fluid and meteoric water during the phyllic alteration. Compared with other deposits, Tocantinzinho has similarities with magmatic-hydrothermal oxidized calc-alkaline granite-related gold deposits classified as porphyry gold deposits but we classify as a porphyry-style gold deposit, as it lacks some characteristics of the Phanerozoic porphyry-type deposits. The results from this study can be used to elaborate and guide prospection models in Amazonia and in similar Proterozoic terrains.

scholarly journals Significance of Calcite Trace Elements Contents and C-O Isotopic Compositions for Ore-Forming Fluids and Gold Prospecting in the Zhesang Carlin-Like Gold Deposit of Southeastern Yunnan, China

Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 338
Author(s):  
Jiasheng Wang ◽  
Jinyang Chang ◽  
Chao Li ◽  
Zhenchun Han ◽  
Tao Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Gold Deposit ◽  
Meteoric Water ◽  
Gold Mineralization ◽  
Mining Area ◽  
Gold Deposits ◽  
Hydrothermal Fluids ◽  
Magmatic Fluid ◽  
Isotopic Compositions

The Zhesang gold deposit of southeastern Yunnan is an important component of the Dian-Qian-Gui (Yunnan, Guizhou, and Guangxi) “Golden Triangle”, which hosts a multitude of Carlin-like gold deposits (CLGDs). Calcite is one of the most common gangue minerals in Zhesang. The calcites that have been found in the mining area are classified as ore-stage and post-ore calcites. The ore-stage calcite exhibits a clear paragenetic relationship with gold-bearing arsenopyrite and with an alteration halo that has been cut by the post-ore calcite. To elucidate the origin of the ore-forming fluids of the Zhesang gold deposit and to investigate the possibility of utilizing calcite geochemistry as prospecting indicators, the rare earth elements (REEs), Y, Fe, Mn and Mg contents, and C-O isotopic compositions of calcites from Zhesang have been analyzed. The ore-stage calcite is enriched in middle rare earth elements (MREEs) relative to light rare earth elements (LREEs) and heavy rare earth elements (HREEs) (MREE/LREE = 1.11–1.61, MREE/HREE = 6.12–8.22), whereas post-ore calcite exhibits an enrichment in LREE (LREE/HREE = 4.39–14.93, MREE/LREE = 0.35–0.71). The ore-stage and post-ore calcites were both formed by hydrothermal fluids; however, these hydrothermal fluids may have different sources. The Fe contents of the ore-stage calcite are significantly higher than those of post-ore calcite (4690–6300 μg/g versus 2030–2730 μg/g). Ore-stage calcite also has significantly lower δ18OV-SMOW values than post-ore calcite (11.03–12.49‰ versus 16.48–17.14‰). These calcites with an MREE/LREE ratio greater than 0.92, MREE/HREE ratio greater than 5.69, Fe content greater than 3827 μg/g, and δ18OV-SMOW value less than 14.40‰ represent ore-stage calcites and are important prospecting guidelines. According to the REE, C-O isotopic characteristics of the calcites and the previous findings, it is inferred that the ore-forming fluids of the Zhesang gold deposit were a mixture of crustal fluid by meteoric water leaching wall rocks and a small amount of basic magmatic fluid. The formation of post-ore calcite might be derived from meteoric water and marine carbonates interaction. The ore-forming fluids of the Zhesang gold deposit may be associated with the intrusion of diabase that outcrops in the mining area, and that the basic magmatic activities of the Indosinian period also provided some of the ore-forming materials and heat for gold mineralization.

scholarly journals Genesis of the Koka Gold Deposit in Northwest Eritrea, NE Africa: Constraints from Fluid Inclusions and C-H-O-S Isotopes

2019 ◽  
Author(s):  
Kai Zhao ◽  
Huazhou Yao ◽  
Jianxiong Wang ◽  
Ghebsha Fitwi Ghebretnsae ◽  
Wenshuai Xiang ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Meteoric Water ◽  
Gold Mineralization ◽  
Early Stage ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Quartz Veins ◽  
Three Phase ◽  
Igneous Origin ◽  
Ne Africa

The Koka gold deposit is located in the Elababu shear zone between the Nakfa terrane and the Adobha Abiy terrane, NW Eritrea. Based on the paragenetic study two main stages of gold mineralization were identified in the Koka gold deposit: 1) an early stage of pyrite-chalcopyrite-sphalerite-galena-gold-quartz vein; and 2) a second stage of pyrite-quartz veins. NaCl-aqueous inclusions, CO2-rich inclusions, and three-phase CO2-H2O inclusions occur in the quartz veins at Koka. The ore-bearing quartz veins formed at 268℃, from NaCl-CO2-H2O(-CH4) fluids averaging 5 wt% NaCl eq. The ore-forming mechanisms include fluid immiscibility during stage I, and mixing with meteoric water during stage II. Oxygen, hydrogen and carbon isotopes suggest that the ore-forming fluids originated as mixtures of metamorphic water, meteoric water and magmatic water, whereas sulfur isotope suggest an igneous origin. Features of geology and ore-forming fluid at Koka deposit are similar to those of orogenic gold deposits, suggesting the Koka deposit might be an orogenic gold deposit related to granite.

Geology and age of the Morrison porphyry Cu–Au–Mo deposit, Babine Lake area, British Columbia

2016 ◽  
Vol 53 (9) ◽  
pp. 950-978 ◽  
Author(s):  
Lijuan Liu ◽  
Jeremy P. Richards ◽  
Robert A. Creaser ◽  
S. Andrew DuFrane ◽  
Karlis Muehlenbachs ◽  
...  
Keyword(s):  
Meteoric Water ◽  
Gold Mineralization ◽  
Lake Area ◽  
Calc Alkaline ◽  
Porphyry Cu ◽  
High K ◽  
Vein Type ◽  
Intrusive Suite ◽  
Stage 1 ◽  
Porphyry Intrusion

The Morrison porphyry Cu–Au–Mo deposit is genetically and spatially related to Eocene plagioclase–hornblende–biotite porphyry intrusions. One porphyry intrusion yielded a U–Pb age of 52.54 ± 1.05 Ma. Mineralization occurs in three stages: (1) vein-type and disseminated chalcopyrite and minor bornite (associated with potassic alteration and gold mineralization); (2) vein-type molybdenite (associated with weak phyllic alteration); and (3) polymetallic sulfide–carbonate veins (dolomite ± quartz–sphalerite–galena–arsenopyrite–chalcopyrite, associated with weak sericite–carbonate alteration). Re–Os dating of molybdenite yielded ages of 52.54 ± 0.22 and 53.06 ± 0.22 Ma, similar to the age of the host porphyry intrusion. Stage 1 vein fluids were predominantly of magmatic origin: Th = 400–526 °C; salinity = 39.8–47.8 wt.% NaCl equiv.; δ18Ofluid = 3.7‰–6.3‰; disseminated chalcopyrite–pyrite δ34SCDT = 0.2‰ and −0.8‰ (CDT, Canyon Diablo Troilite). Stage 2 fluids were a mixture of magmatic and meteoric water: Th = 320–421 °C; salinity = 37.0–43.1 wt.% NaCl equiv.; δ18Ofluid values range from 0.3‰ to 3.4‰; molybdenite and pyrite δ34SCDT = −2.1‰ and −1.2‰. Stage 3 fluids were predominantly of meteoric water origin: Th = 163–218 °C; salinity = 3.1–3.9 wt.% NaCl equiv.; δ18Ofluid = −2.3‰ to 3.9‰ for early vein quartz, and 1.1‰ to 6.1‰ for late vein dolomite; sphalerite and pyrite δ34SCDT = −7.1‰ to −5.6‰. Morrison is interpreted to be a typical porphyry Cu–Au–Mo deposit related to a calc-alkaline to a high-K calc-alkaline diorite to granodiorite intrusive suite, generated in a continental arc in response to early Eocene subduction of the Kula–Farallon plate beneath North America.

scholarly journals The Perron Gold Deposit, Archean Abitibi Belt, Canada: Exceptionally High-Grade Mineralization Related to Higher Gold-Carrying Capacity of Hydrocarbon-Rich Fluids

Minerals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1066
Author(s):  
Damien Gaboury ◽  
Dominique Genna ◽  
Jacques Trottier ◽  
Maxime Bouchard ◽  
Jérôme Augustin ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Trace Element ◽  
Gold Deposit ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Magmatic Fluid ◽  
High Grade ◽  
Host Rocks ◽  
Mineralizing Fluids

The Perron deposit, an Archean orogenic gold deposit located in the Abitibi belt, hosts a quartz vein-type gold-bearing zone, known as the high-grade zone (HGZ). The HGZ is vertically continuous along >1.2 km, and is exceptionally rich in visible gold throughout its vertical extent, with grades ranging from 30 to 500 ppm. Various hypotheses were tested to account for that, such as: (1) efficient precipitating mechanisms; (2) gold remobilization; (3) particular fluids; (4) specific gold sources for saturating the fluids; and (5) a different mineralizing temperature. Host rocks recorded peak metamorphism at ~600 °C based on an amphibole geothermometer. Visible gold is associated with sphalerite (<5%) which precipitated at 370 °C, based on the sphalerite GGIMFis geothermometer, during late exhumation of verticalized host rocks. Pyrite chemistry analyzed by LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) is comparable to classical orogenic gold deposits of the Abitibi belt, without indication of a possible magmatic fluid and gold contribution. Comparison of pyrite trace element signatures for identifying a potential gold source was inconclusive to demonstrate that primary base-metal rich volcanogenic gold mineralization, dispersed in the host rhyolitic dome, could be the source for the later formation of the HGZ. Rather, nodular pyrites in graphitic shales, sharing similar trace element signatures with pyrite of the HGZ, are considered a potential source. The most striking outcome is the lack of water in the mineralizing fluids, implying that gold was not transported under aqueous complexes, even if fugacity of sulfur (−6) and oxygen (−28), and pH (~7) are providing the best conditions at a temperature of 350 °C for solubilizing gold in water. Fluid inclusions, analyzed by solid-probe mass spectrometry, are rather comparable to fossil gas composed mostly of hydrocarbons (methane and ethane and possibly butane and propane and other unidentified organic compounds), rich in CO2, with N2 and trace of Ar, H2S, and He. It is interpreted that gold and zinc were transported as hydrocarbon-metal complexes or as colloidal gold nanoparticles. The exceptional high content of gold and zinc in the HGZ is thus explained by the higher transporting capacity of these unique mineralizing fluids.

scholarly journals Genesis of the Late Cretaceous Longquanzhan Gold Deposit in the Central Tan-Lu Fault Zone, Shandong Province, China: Constraints from Noble Gas and Sulfur Isotopes

Minerals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 250
Author(s):  
Chuanpeng Liu ◽  
Wenjie Shi ◽  
Junhao Wei ◽  
Huan Li ◽  
Aiping Feng ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Fault Zone ◽  
Late Cretaceous ◽  
Genetic Model ◽  
Gold Mineralization ◽  
Sulfur Isotopes ◽  
Noble Gas ◽  
Gold Deposits ◽  
Shandong Province ◽  
Magma Sources

The Longquanzhan deposit is one of the largest gold deposits in the Yi-Shu fault zone (central section of the Tan-Lu fault zone) in Shandong Province, China. It is an altered-rock type gold deposit in which ore bodies mainly occur at the contact zone between the overlying Cretaceous rocks and the underlying Neoarchean gneissic monzogranite. Shi et al. reported that this deposit formed at 96 ± 2 Ma using pyrite Rb–Sr dating method and represents a new gold mineralization event in the Shandong Province in 2014. In this paper, we present new He–Ar–S isotopic compositions to further decipher the sources of fluids responsible for the Longquanzhan gold mineralization. The results show that the δ34S values of pyrites vary between 0.9‰ and 4.4‰ with an average of 2.3‰. Inclusion-trapped fluids in ore sulfides have 3He/4He and 40Ar/36Ar ratios of 0.14–0.78 Ra and 482–1811, respectively. These isotopic data indicate that the ore fluids are derived from a magmatic source, which is dominated by crustal components with minor mantle contribution. Air-saturated water may be also involved in the hydrothermal system during the magmatic fluids ascending or at the shallow deposit site. We suggest that the crust-mantle mixing signature of the Longquanzhan gold deposit is genetically related to the Late Cretaceous lithospheric thinning along the Tan-Lu fault zone, which triggers constantly uplifting of the asthenosphere surface and persistent ascending of the isotherm plane to form the gold mineralization-related crustal level magma sources. This genetic model can be applied, to some extent, to explain the ore genesis of other deposits near or within the Tan-Lu fault belt.

scholarly journals Petrogenesis of a late-stage calc-alkaline granite in a giant S-type batholith: geochronology and Sr–Nd–Pb isotopes from the Nomatsaus granite (Donkerhoek batholith), Namibia

2021 ◽  
Author(s):  
S. Aspiotis ◽  
S. Jung ◽  
F. Hauff ◽  
R. L. Romer
Keyword(s):  
Partial Melting ◽  
Mineral Assemblage ◽  
Central Zone ◽  
Calc Alkaline ◽  
Pb Isotope ◽  
Alkaline Granite ◽  
Ti Oxides ◽  
Eu Anomaly ◽  
Environment Characteristic ◽  
Southern Central

AbstractThe late-tectonic 511.4 ± 0.6 Ma-old Nomatsaus intrusion (Donkerhoek batholith, Damara orogen, Namibia) consists of moderately peraluminous, magnesian, calc-alkalic to calcic granites similar to I-type granites worldwide. Major and trace-element variations and LREE and HREE concentrations in evolved rocks imply that the fractionated mineral assemblage includes biotite, Fe–Ti oxides, zircon, plagioclase and monazite. Increasing K2O abundance with increasing SiO2 suggests accumulation of K-feldspar; compatible with a small positive Eu anomaly in the most evolved rocks. In comparison with experimental data, the Nomatsaus granite was likely generated from meta-igneous sources of possibly dacitic composition that melted under water-undersaturated conditions (X H2O: 0.25–0.50) and at temperatures between 800 and 850 °C, compatible with the zircon and monazite saturation temperatures of 812 and 852 °C, respectively. The Nomatsaus granite has moderately radiogenic initial 87Sr/86Sr ratios (0.7067–0.7082), relatively radiogenic initial εNd values (− 2.9 to − 4.8) and moderately evolved Pb isotope ratios. Although initial Sr and Nd isotopic compositions of the granite do not vary with SiO2 or MgO contents, fSm/Nd and initial εNd values are negatively correlated indicating limited assimilation of crustal components during monazite-dominated fractional crystallization. The preferred petrogenetic model for the generation of the Nomatsaus granite involves a continent–continent collisional setting with stacking of crustal slices that in combination with high radioactive heat production rates heated the thickened crust, leading to the medium-P/high-T environment characteristic of the southern Central Zone of the Damara orogen. Such a setting promoted partial melting of metasedimentary sources during the initial stages of crustal heating, followed by the partial melting of meta-igneous rocks at mid-crustal levels at higher P–T conditions and relatively late in the orogenic evolution.

CALCITE U-Pb DATING UNRAVELS THE AGE AND HYDROTHERMAL HISTORY OF THE GIANT SHUIYINDONG CARLIN-TYPE GOLD DEPOSIT IN THE GOLDEN TRIANGLE, SOUTH CHINA

2021 ◽  
Vol 116 (6) ◽  
pp. 1253-1265
Author(s):  
Xiao-Ye Jin ◽  
Jian-Xin Zhao ◽  
Yue-Xing Feng ◽  
Albert H. Hofstra ◽  
Xiao-Dong Deng ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Early Cretaceous ◽  
South China ◽  
Gold Deposits ◽  
Ore Deposits ◽  
Late Triassic ◽  
Gold Deposition ◽  
Golden Triangle ◽  
Icp Ms ◽  
Carlin Type Gold Deposits

Abstract The ages of Carlin-type gold deposits in the Golden Triangle of South China have long been questioned due to the general lack of minerals unequivocally linked to gold deposition that can be precisely dated using conventional radiogenic isotope techniques. Recent advances in U-Pb methods show that calcite can be used to constrain the ages of hydrothermal processes, but few studies have been applied to ore deposits. Herein, we show that this approach can be used to constrain the timing of hydrothermal activity that generated and overprinted the giant Shuiyindong Carlin-type gold deposit in the Golden Triangle. Three stages of calcite (Cal-1, Cal-2, and Cal-3) have been recognized in this deposit based on crosscutting relationships, cathodoluminescence colors, and chemical (U, Pb, and rare earth element [REE]) and isotope (C, O, Sr) compositions. Cal-1 is texturally associated with ore-stage jasperoid and disseminated Au-bearing arsenian pyrite in hydrothermally altered carbonate rocks, which suggests it is synmineralization. Cal-2 fills open spaces and has a distinct orange cathodoluminescence, suggesting that it precipitated during a second fluid pulse. Cal-1 and Cal-2 have similar carbonate rock-buffered chemical and isotopic compositions. Cal-3 occurs in veins that often contain realgar and/or orpiment and are chemically (low U, Pb, and REE) and isotopically (higher δ13C, lower δ18O and Sri values) distinct from Cal-1 and Cal-2, suggesting that it formed from a third fluid. U-Pb isotope analyses, by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) for U-rich Cal-1 and Cal-2 and by LA-multicollector (MC)-ICP-MS for U-poor Cal-3, yield well-defined age constraints of 204.3 to 202.6, 191.9, and 139.3 to 137.1 Ma for Cal-1, Cal-2, and Cal-3, respectively. These new ages suggest that the Shuiyindong gold deposit formed in the late Triassic and was overprinted by hydrothermal events in the early Jurassic and early Cretaceous. Given the association of Cal-3 with orpiment and realgar, and previous geochronologic studies of several other major gold deposits in the Golden Triangle, we infer that the latest stage of calcite may be associated with an early Cretaceous regional gold metallogenic event. Combined with existing isotopic ages in the region, these new ages lead us to propose that Carlin-type gold deposits in the Golden Triangle formed during two metallogenic episodes in extensional settings, associated with the late Triassic Indochina orogeny and early Cretaceous paleo-Pacific plate subduction. This study shows that the calcite U-Pb method can be used to constrain the timing of Carlin-type gold deposits and successive hydrothermal events.

scholarly journals A NEW GOLD ORE REGION IN TANZANIA

2018 ◽  
pp. 55-59
Author(s):  
V. Mykhailov ◽  
А. Tots
Keyword(s):  
Gold Deposit ◽  
Shear Zone ◽  
Gold Mineralization ◽  
Lake Victoria ◽  
Gold Deposits ◽  
Mobile Belt ◽  
Gold Content ◽  
Gold Ore ◽  
Metallogenic Zone ◽  
The Republic

Tanzania is one of the leading gold mining countries in the world and the discovery of new gold resources on its territory is an actual task. Known gold deposits are concentrated mainly in the northwest of the country, in the metallogenic zone of Lake Victoria, where they are associated with the Archean greenstone belts, and to a lesser extent – in the southwest, in the ore regions of Lupa and Mpanda, confined to the Ubendian Paleoproterozoic mobile belt. With regard to the eastern regions of Tanzania, where the Proterozoic structures of the Uzagaran mobile belt are developed, until recently in this region any significant manifestations of gold mineralization were not known. As a result of our research in the northern part of the Morogoro province of the Republic of Tanzania, a new previously unknown gold deposit Mananila was discovered. It is represented by a large volume, up to 400–450 m long, up to 60–80 m thick, mineralized shear zone over intensely leached and schistosed migmatites, gneisses, amphibolites, penetrated by echelon systems of quartz veins and veinlet, steeply dipping bodies of quartz breccia up to 1.0–1.5 m thick. Gold contents range from 0.61 to 8.11 g/t, the average zone content is 2.5–3.0 g/t. Parallel to the main zone, similar structures are developed on the site, although they are of lower thickness. The forecast resources of the deposit are estimated at 20 tons of gold. 2.8 km to the east from the Mananila field, the recently discovered Mazizi gold deposit is located, and a number of small occurrences of gold are also known in the region. All these objects are located within a large shear zone of the northeastern strike, up to 4–5 km width, over 20 km in length. This serves as the basis for the identification of a new gold ore region in the northern part of the Morogoro province of the United Republic of Tanzania, within the Proterozoic mobile belt of Usagaran, the possible gold content of which has never been previously discussed in geological literature.

Petrology and geochemistry of calc-alkaline volcanic and subvolcanic rocks, Dalli porphyry copper–gold deposit, Markazi Province, Iran

2012 ◽  
Vol 55 (2) ◽  
pp. 158-184 ◽  
Author(s):  
Farimah Ayati ◽  
Fuat Yavuz ◽  
Hooshang H. Asadi ◽  
Jeremy P. Richards ◽  
Fred Jourdan
Keyword(s):  
Gold Deposit ◽  
Porphyry Copper ◽  
Calc Alkaline ◽  
Copper Gold ◽  
Petrology And Geochemistry
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