scholarly journals Carbon and Oxygen Isotopic Composition of Saline Lacustrine Dolomite Cements and Its Palaeoenvironmental Significance: A Case Study of Paleogene Shahejie Formation, Bohai Sea

Minerals ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 13 ◽  
Author(s):  
Hailong Meng ◽  
Zhengxiang Lv ◽  
Zhongmin Shen ◽  
Chenhao Xiong
Keyword(s):  
Early Stage ◽  
Oxygen Isotopic Composition ◽  
Lake Basin ◽  
Bohai Bay ◽  
O Isotopes ◽  
Shahejie Formation ◽  
Oxygen Isotopic ◽  
C And O Isotopes ◽  
Two Stages ◽  
Saline Lacustrine

The dolomite reservoirs in the Paleogene Shahejie Formation in the Bozhong area of the Bohai Bay Basin contain a large amount of dolomite cement. Petrologic and mineralogic studies have shown that the dolomite cements can be divided into three types according to their occurrence: coating dolomite (CD), pore-lining dolomite (LD), and pore-filling dolomite (FD). The laser microsampling technique was used to analyze the C and O isotopes in the carbonate minerals. This method is an effective way to produce CO2 gas from a particular carbonate structure in a thin section, and it has a spatial resolution of 20–50 µm and an optimal precision of approximately ±0.22σ for δ13C and δ18O in carbonate standard materials. The carbon and oxygen isotopic compositions and the oxygen isotopic geothermometer results showed that the dolomitization fluid is mainly low temperature fluid, the lake basin environment is relatively closed, and the salinity index Z value is greater than 120, which indicates the invasion of seawater. CD and early-stage LD crystals were mainly very fine crystals with faint cathodoluminescence, which indicates the early formation of diagenesis. The high temperatures of late-stage LD and FD measured by oxygen isotope thermometers indicates that they formed at a deeper depth. The dolomite cements in the study area may have formed in two stages: seepage-reflux dolomitization during the penecontemporaneous period and burial dolomitization.

Effect of sedimentary environment on shale lithofacies in the lower third member of the Shahejie Formation, Zhanhua Sag, eastern China

2017 ◽  
Vol 5 (4) ◽  
pp. T487-T501 ◽  
Author(s):  
Tingwei Li ◽  
Zhenxue Jiang ◽  
Chenlu Xu ◽  
Yuan Yuan ◽  
Pengfei Wang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Early Stage ◽  
Eastern China ◽  
Sedimentary Environment ◽  
Gas Production ◽  
Bohai Bay ◽  
Calcareous Shale ◽  
Shahejie Formation ◽  
Scanning Electron

Research on shale lithofacies is important for shale oil and gas production. This study focused on the lower third member of the Shahejie Formation ([Formula: see text]) in the Luo-69 well in the Zhanhua Sag, Jiyang Depression, Bohai Bay Basin, eastern China. Several methods, including thin section observations, total organic carbon (TOC) analysis, X-ray diffraction analysis, quantitative evaluations of minerals by scanning electron microscopy, major and trace-element analyses, and field emission-scanning electron microscopy, are used to investigate the effect of sedimentary environment on the type and distribution of shale lithofacies. Our research indicates that 36 types of shale lithofacies can be classified based on the TOC content, mineral composition, and sedimentary structure, of which five types are identified in the study area. The [Formula: see text] shale has a high calcareous mineral content (average of 49.64%), low clay and siliceous minerals contents (averages of 19.54% and 19.02%, respectively), a high TOC content (average of 3.00 wt%), and well-developed horizontal bedding. The sedimentary environment during the deposition of the [Formula: see text] shale in the Zhanhua Sag had a warm and moist climate, limited provenance, saline water, and strong reducibility. The sedimentary environment in the early stage had a drier climate, more limited provenance, higher salinity, and stronger reducibility than that in the later stage. Shale lithofacies can reflect a certain sedimentary environment and depositional process; similarly, a depositional environment controls the type and distribution of shale lithofacies. Due to the characteristics of the [Formula: see text] sedimentary environment, organic-rich massive mixed shale, organic-rich bedded mixed-calcareous shale, organic-rich laminated calcareous shale, and organic-fair laminated calcareous shale are developed in the [Formula: see text] formation from top to bottom.

Two stages of CO2 metasomatism at the Munro mine, Munro Township, Ontario: evidence from fluid-inclusion, stable-isotope, and mineralogical studies

1991 ◽  
Vol 28 (5) ◽  
pp. 721-728 ◽  
Author(s):  
Eva S. Schandl ◽  
Frederick J. Wicks
Keyword(s):  
Isotopic Composition ◽  
Regional Metamorphism ◽  
Oxygen Isotopic Composition ◽  
First Episode ◽  
Widespread Occurrence ◽  
Metamorphic History ◽  
Calcite Veins ◽  
History Of ◽  
Oxygen Isotopic ◽  
Two Stages

The Munro asbestos mine is hosted by a differentiated ultramafic sill of Archean age. Localized carbonate alteration at the mine has resulted from two separate episodes of CO2 metasomatism, and the fluids were unrelated. The first episode affected only the serpentinized peridotite and occurred at 250 °C. The fluid was a saline brine (up to 24 wt.% NaCl–CaCl2), and had an oxygen isotopic composition of −3‰, and δ13C was equal to −7.8‰. Calcite veins were emplaced into the overlying, fractured pyroxenite at approximately 300–400 °C during the second episode. The salinity of this fluid was only 1–5 equiv. wt.% NaCl, the oxygen isotopic composition was +7.5‰, and δ13C equaled −3 to −5‰. The first episode was probably associated with burial metamorphism (diagenesis) and the second episode with regional metamorphism. The widespread occurrence of two separate stages of CO2 metasomatism in the Abitibi belt and in other well-documented Archean terranes, such as the Norseman–Wiluna greenstone belt in Western Australia, suggests that this may be an important factor in the tectonic evolution and metamorphic history of Archean greensone belts.

scholarly journals Diagenesis and Origination of Carbonate Cements in Deeply Buried Sandstones of the Eocene Es3 Member, Raoyang Sag, Bohai Bay Basin, China

Geofluids ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-18
Author(s):  
Kaixun Zhang ◽  
Xinxin Fang ◽  
Ying Xie ◽  
Shun Guo ◽  
Zhenwang Liu ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Carbon Sources ◽  
Oxygen Isotopic Composition ◽  
Source Rocks ◽  
Bohai Bay ◽  
Isotopic Data ◽  
Bohai Bay Basin ◽  
Carbon And Oxygen Isotopes ◽  
Carbonate Cements ◽  
Oxygen Isotopic

Diagenesis is one of the most predominant factors controlling reservoir quality in the deeply buried siliciclastic sandstones of the third member in the Eocene Shahejie Formation (Es3), in the Raoyang Sag, the Bohai Bay Basin. In this study, thin section, cathodoluminescence (CL), scanning electron microscope (SEM), X-ray diffraction (XRD), Raman spectrum, carbon and oxygen isotopes, and fluid inclusion analyses are used to restructure paragenetic sequences and detect origins of carbonate cements recorded in this deeply buried member. Based on petrographic analyses, the Es3 sandstones are identified as lithic arkoses and feldspathic litharenites at present, but derived from original arkoses and lithic arkoses, respectively. Geohistorically, the Es3 sandstones have undergone two diagenetic episodes of eogenesis and mesogenesis. Events observed during eogenesis include chemical compaction, leaching of feldspar, development of chlorite coating and kaolinite, precipitation of the first generation of quartz overgrowth (QogI), dissolution of feldspar, and precipitation of calcite and nonferroan dolomite cement. Mesogenetic alterations include chemical compaction, precipitation of kaolinite aggregate and the second generation of quartz overgrowth (QogII), precipitation of ankerite, development of I/S and illite, and formation of pyrite. Carbon and oxygen isotopic data show that calcite cements are characterized by 13C ( δ 13 C PDB ranging from -0.7‰ to 1.0‰ with an average of 0.1‰) and 18O ( δ 18 O SMOW varying from 12.3‰ to 19.0‰ with an average of 16.2‰); these stable isotopic data combined with Z value (from 114.69 to 122.18) indicate skeletal debris ( δ 13 C PDB ranging from -1.2‰ to -1.1‰ with an average of -1.15‰; δ 18 O SMOW varying from 23.0‰ to 23.2‰ with an average of 23.1‰) and ooids in adjacent carbonate beds involved in meteoric water and seawater from outside jointly served as the carbon sources. For nonferroan dolomite, the δ 13 C PDB value of -4.1‰ is a little bit negative than the calcite, and the δ 18 O SMOW of 14.3‰ is coincident with the calcite, which suggest the nonferroan dolomites come from the diagenetic fluids with a similar oxygen isotopic composition to that of the calcite but modified by the external acidic δ 13C-depleted water. However, the ankerites are actually rich in 12C ( δ 13 C PDB ranging from -10.0‰ to -1.2‰, mean = − 4.3 ‰ ) and 16O ( δ 18 O SMOW varying from 10.1‰ to 19.4‰, mean = 14.9 ‰ ), when combined with the distribution of cutting down along the direction pointing to sand-body center from the margin and microthermometric temperature (Th’s) data mainly varying between 115.2°C and 135.5°C with an average of 96.0°C, indicating the main origination from the Es3 source rocks with effective feldspar buffer action for the acidic fluids in the margins of the Es3 sandstones. In addition, the necessary elements for ankerite such as Fe2+, Ca2+, and Mg2+ ions also come from organic matter and clay minerals during thermal maturation of the Es3 source rocks. The study provides insights into diagenetic processes and origination of carbonate cements in the Es3 sandstones; it will facilitate the cognition of predictive models of deeply buried sandstone reservoirs to some extent, which can reduce the risks involved in oil and gas exploration and development.

The Carboniferous timescale: an introduction

2021 ◽  
pp. SP512-2021-160
Author(s):  
Spencer G. Lucas ◽  
Joerg W. Schneider ◽  
Svetlana Nikolaeva ◽  
Xiandong Wang
Keyword(s):  
Early Stage ◽  
Magnetic Polarity ◽  
Future Research ◽  
Global Correlation ◽  
O Isotopes ◽  
Isotope Stratigraphy ◽  
C And O Isotopes ◽  
Selection For ◽  
Further Development

AbstractThe Carboniferous chronostratigraphic scale consists of two subsystems, six series and seven stages. Precise numerical age control within the Carboniferous is uneven, and a global magnetic polarity timescale for the Carboniferous is far from established. Isotope stratigraphy based on Sr, C and O isotopes is in an early stage but has already identified a few Sr and C isotope events of use to global correlation. Cyclostratigraphy has created a workable astrochronology for part of Pennsylvanian time that needs better calibration. Chronostratigraphic definitions of most of the seven Carboniferous stages remain unfinished. Future research on the Carboniferous timescale should focus on GSSP selection for the remaining, undefined stage bases, definition and characterization of substages, and further development and integration of the Carboniferous chronostratigraphic scale with radioisotopic, magnetostratigraphic, chemostratigraphic and cyclostratigraphic tools for calibration and correlation and the cross correlation of nonmarine and marine chronologies.

scholarly journals Oxygen and Carbon Isotopic Composition of Carbonate Rocks of the Permian Qixia Formation, Sichuan Basin: Thermal Effects of Emeishan Basalt

2016 ◽  
Vol 20 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Keke Huang ◽  
Xiaoning Li ◽  
Zuowei Hu ◽  
Yijiang Zhong
Keyword(s):  
Isotopic Composition ◽  
Thermal Effects ◽  
Sichuan Basin ◽  
Early Stage ◽  
Carbon Isotopic Composition ◽  
Oxygen Isotopic Composition ◽  
Rock Properties ◽  
Carbon Isotopic ◽  
Emeishan Basalt ◽  
Oxygen Isotopic

<p>The late Permian thermal events related to Emeishan Basalt has made a great impact on the underlying carbonate rock properties in the western margin of the Yangtze Platform. In this paper, we investigate the carbon and oxygen isotopic composition of the Qixia Formation carbonates from two sections: the Qiaoting Section in the northeastern part of the Sichuan Basin and the Changjianggou Section at the northwestern edge of the Basin. The data reveal that: (i) Samples from Qiaoting section show a relatively narrow range of δ<sup>13</sup>C and δ<sup>18</sup>O, varying from 2.7‰ to 5.2‰ with an average of 4.2‰, and -3.8‰ to -7.8‰ with an average of -5.4‰, respectively. In contrast, Samples from Changjianggou section exhibit larger magnitude of variation in δ<sup>13</sup>C and δ<sup>18</sup>O, ranging from -1‰ to 3.8‰ with an average of 1.5‰, and -2.1 to -9.2‰, with an average of -6.0‰ respectively; (ii) δ<sup>13</sup>C and δ<sup>18</sup>O records in carbonates from Qiaoting section are similar to those of Middle Permian seawater whereas carbonates from the Changjianggou section are depleted in <sup>13</sup>C and <sup>18</sup>O compared to contemporary seawater; (iii) On the basis of combined petrographic and paleo-heat flow evidence, the lower carbon and oxygen isotopic composition of the carbonates from the Changjianggou section are interpreted to be the results of thermal effects of Emeishan Basalt because of its proximity to the eruption center of the basalt. The high temperature reduced the δ<sup>18</sup>O values of the carbonates and forced the organic matter to mature at an early stage, thus producing <sup>13</sup>C-enriched carbon dioxide to participate in the formation of carbonates.  </p><p> </p><p><strong>Composición Isotópica de Oxígeno y Carbón en Rocas de Carbonato de la Formación de Edad Pérmica Qixia, en la Cuenca de Sichuan: Efectos Térmicos del Basalto Emeishan  </strong></p><p><strong><br /></strong></p><p><strong>Resumen</strong></p><p>Los eventos térmicos del Pérmico tardío relacionados con el Basalto Emeishan han tenido un gran impacto en las propiedades de las rocas de carbonato subyacentes en el margen occidental de la plataforma Yangtze. En este artículo se investiga la composición isotópica de carbonatos de la formación Qixia en dos secciones: la sección de Qiaoting en la parte nororiental de la cuenca Sichuan y la sección Changjianggou, en el noroccidente de la cuenca. La información evidencia que, (i) las muestras de la sección Qiaoting tienen un espectro más angosto que va de δ<sup>13</sup>C a δ<sup>18</sup>O, con variación de 2.7 ‰ a 5,2 ‰, con un promedio de 4.2 ‰, y -3.8 ‰ a -7.8 ‰, con una media de -5.4 ‰, respectivamente. En contraste, las muestras de la sección Changjianggou tienen una variación de mayor magnitud en δ<sup>13</sup>C a δ<sup>18</sup>O que va desde -1 ‰ hasta 3.8 ‰, con un promedio de 1.5 ‰, y de -2.1 a -9.2 ‰, con una media de -6.0 ‰, respectivamente; (ii) los registros de δ<sup>13</sup>C y δ<sup>18</sup>O en carbonatos son similares a los de agua marina del pérmico medio, mientras que los carbonatos de la sección Changjianggou se ven empobrecidos en 13C y 18O comparados al agua marina de esta edad; con base en la petrografía combinada y la evidencia del flujo paleotérmico, la baja composición isotópica de oxígeno y carbón de los carbonatos en la sección de Changjianggou se interpretó como resultado de los efectos térmicos del Basalto Emeishan debido a la proximidad con el centro de erupción. La alta temperatura redujo los valores de δ<sup>18</sup>O de los carbonatos y llevó a la maduración temprana de la materia orgánica, lo que produjo dióxido de carbono enriquecido en <sup>13</sup>C durante la formación de los carbonatos.</p>

Changes of Ionic and Oxygen Isotopic Composition of the Snowpack at the Glacier Austre Okstindbreen, Norway, 1995

1998 ◽  
Vol 29 (1) ◽  
pp. 1-20 ◽  
Author(s):  
Peter Raben ◽  
Wilfred H. Theakstone
Keyword(s):  
Isotopic Composition ◽  
Sea Level ◽  
Oxygen Isotopes ◽  
Oxygen Isotopic Composition ◽  
Isotopic Ratios ◽  
Vertical Variations ◽  
Oxygen Isotopic ◽  
The Difference ◽  
Liquid Precipitation ◽  
Different Altitudes

Marked vertical variations of ions and oxygen isotopes were present in the snowpack at the glacier Austre Okstindbreen during the pre-melting phase in 1995 at sites between 825 m and 1,470 m above sea level. As the first meltwater percolated from the top of the pack, ions were moved to a greater depth, but the isotopic composition remained relatively unchanged. Ions continued to move downwards through the pack during the melting phase, even when there was little surface melting and no addition of liquid precipitation. The at-a-depth correlation between ionic concentrations and isotopic ratios, strong in the pre-melting phase, weakened during melting. In August, concentrations of Na+ and Mg2+ ions in the residual pack were low and vertical variations were slight; 18O enrichment had occurred. The difference of the time at which melting of the snowpack starts at different altitudes influences the input of ions and isotopes to the underlying glacier.

scholarly journals The influences of sedimentary environments on organic matter enrichment in fine-grained rocks of the Paleogene Shahejie formation in Nanpu Sag, Huanghua Depression, Bohai Bay Basin

2021 ◽  
pp. 014459872110310
Author(s):  
Min Li ◽  
Xiongqi Pang ◽  
Guoyong Liu ◽  
Di Chen ◽  
Lingjian Meng ◽  
...  
Keyword(s):  
Organic Matter ◽  
Source Rocks ◽  
Bohai Bay ◽  
Bohai Bay Basin ◽  
Humid Climate ◽  
High Productivity ◽  
Fine Grained ◽  
Huanghua Depression ◽  
Shahejie Formation ◽  
Nanpu Sag

The fine-grained rocks in the Paleogene Shahejie Formation in Nanpu Sag, Huanghua Depression, Bohai Bay Basin, are extremely important source rocks. These Paleogene rocks are mainly subdivided into organic-rich black shale and gray mudstone. The average total organic carbon contents of the shale and mudstone are 11.5 wt.% and 8.4 wt.%, respectively. The average hydrocarbon (HC)-generating potentials (which is equal to the sum of free hydrocarbons (S1) and potential hydrocarbons (S2)) of the shale and mudstone are 39.3 mg HC/g rock and 28.5 mg HC/g rock, respectively, with mean vitrinite reflectance values of 0.82% and 0.81%, respectively. The higher abundance of organic matter in the shale than in the mudstone is due mainly to paleoenvironmental differences. The chemical index of alteration values and Na/Al ratios reveal a warm and humid climate during shale deposition and a cold and dry climate during mudstone deposition. The biologically derived Ba and Ba/Al ratios indicate high productivity in both the shale and mudstone, with relatively low productivity in the shale. The shale formed in fresh to brackish water, whereas the mudstone was deposited in fresh water, with the former having a higher salinity. Compared with the shale, the mudstone underwent higher detrital input, exhibiting higher Si/Al and Ti/Al ratios. Shale deposition was more dysoxic than mudstone deposition. The organic matter enrichment of the shale sediments was controlled mainly by reducing conditions followed by moderate-to-high productivity, which was promoted by a warm and humid climate and salinity stratification. The organic matter enrichment of the mudstone was less than that of the shale and was controlled by relatively oxic conditions.

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