scholarly journals Major and Trace Element Geochemistry of Pyrite and Pyrrhotite from Stratiform and Lamellar Orebodies: Implications for the Ore Genesis of the Dongguashan Copper (Gold) Deposit, Eastern China

Minerals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 380 ◽  
Author(s):  
Zhongfa Liu ◽  
Yongjun Shao ◽  
Haodi Zhou ◽  
Nan Liu ◽  
Kuanxin Huang ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Inductively Coupled Plasma ◽  
Eastern China ◽  
Gold Deposits ◽  
Trace Element Geochemistry ◽  
Magma Intrusion ◽  
Element Geochemistry ◽  
Important Region ◽  
Copper Gold ◽  
Deposit Type

The Dongguashan copper (gold) deposit in Anhui Province is one of the largest copper (gold) deposits in the Tongling ore district, which is the most important region in the Middle–Lower Yangtze River Metallogenic Belt, Eastern China. Stratiform and lamellar orebodies are the major deposit types. Pyrite and pyrrhotite from the stratiform deposit type (Py I, Po I) and lamellar deposit type (Py II, Po II) are investigated using Electron-probe Microanalyses (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). Py I, Py II, Po I and Po II have high contents of Cu, Co, Au and Se, low contents of As, Pb and Zn, with Co/Ni ratios of 0.50−48.00, 4.00−45.00, 1.55−14.45 and 1.02−1.36, respectively, most of which are greater than 1 and vary widely; these characteristics are consistent with those of pyrite with a magmatic–hydrothermal origin. The higher Au/Ag and Fe/(S + As) ratios of pyrite and crystallization temperatures (286–387 °C) of hexagonal pyrrhotite indicate that the mineralization occurrs in environments with medium- to high-temperatures, high sulfur fugacity and medium-shallow depths. Therefore, we suggest that the Dongguashan copper (gold) deposit is a stratabound skarn-type ore deposit associated with magma intrusion activity during the Yanshanian Period.

Chapter 1: Gold Deposit Types: An Overview

2020 ◽  
pp. 1-28
Author(s):  
Richard H. Sillitoe
Keyword(s):  
Gold Deposit ◽  
Unknown Origin ◽  
Mafic Magma ◽  
Massive Sulfide ◽  
Gold Deposits ◽  
Hydrothermal Fluids ◽  
Copper Gold ◽  
Deposit Type ◽  
Ambient Surface

Abstract Gold is either the only economically important metal or a major by-product in 11 well-characterized deposit types—paleoplacer, orogenic, porphyry, epithermal, Carlin, placer, reduced intrusion related, volcanogenic massive sulfide (VMS), skarn, carbonate replacement, and iron oxide-copper-gold (IOCG), arguably more than for those of any other metal; it also dominates a number of deposits of uncertain or unknown origin. Major gold concentrations formed worldwide from the Mesoarchean to the Pleistocene, from Earth’s surface to midcrustal paleodepths, alone or in association with silver, base metals, and/or uranium, and from hydrothermal fluids of predominantly metamorphic, magmatic, meteoric, seawater, or, uncommonly, basinal origins, as well as from mafic magma or ambient surface water. Most of the Neoproterozoic and Phanerozoic deposits unequivocally formed in accretionary orogens. As an introduction to this compilation of the world’s major gold deposits and provinces, this paper provides a thumbnail sketch of each gold deposit type, including geologic and economic characteristics and widely accepted genetic models, as well as briefly discusses aspects of their spatial and temporal associations and distributions.

Magnetite texture and trace-element geochemistry fingerprint of pulsed mineralization in the Xinqiao Cu-Fe-Au deposit, Eastern China

2020 ◽  
Vol 105 (11) ◽  
pp. 1712-1723
Author(s):  
Yu Zhang ◽  
Pete Hollings ◽  
Yongjun Shao ◽  
Dengfeng Li ◽  
Huayong Chen ◽  
...  
Keyword(s):  
Trace Element ◽  
Triple Junction ◽  
Eastern China ◽  
Black Shales ◽  
Hydrothermal Fluids ◽  
Oscillatory Zoning ◽  
Trace Element Geochemistry ◽  
Element Geochemistry ◽  
Rock Interaction ◽  
Multiple Pulses

Abstract The origin of stratabound deposits in the Middle-Lower Yangtze River Valley Metallogenic Belt (MLYRB), Eastern China, is the subject of considerable debate. The Xinqiao Cu-Fe-Au deposit in the Tongling ore district is a typical stratabound ore body characterized by multi-stage magnetite. A total of six generations of magnetite have been identified. Mt1 is commonly replaced by porous Mt2, and both are commonly trapped in the core of Mt3, which is characterized by both core-rim textures and oscillatory zoning. Porous Mt4 commonly truncates the oscillatory zoning of Mt3, and Mt5 is characterized by 120° triple junction texture. Mt1 to Mt5 are commonly replaced by pyrite that coexists with quartz, whereas Mt6, with a fine-grained foliated and needle-like texture, commonly cuts the early pyrite as veins and is replaced by pyrite that coexists with calcite. The geochemistry of the magnetite suggests that they are hydrothermal in origin. The microporosity of Mt2 and Mt4 magnetite, their sharp contacts with Mt1 and Mt3, and lower trace-element contents (e.g., Si, Ca, Mg, and Ti) than Mt1 and Mt3 suggest that they formed via coupled dissolution and reprecipitation of the precursor Mt1 and Mt3 magnetite, respectively. This was likely caused by high-salinity fluids derived from intensive water-rock interaction between the magmatic-hydrothermal fluids associated with the Jitou stock and Late Permian metalliferous black shales. The 120° triple junction texture of Mt5 suggests it is the result of fluid-assisted recrystallization, whereas Mt6 formed by replacement of hematite as a result of fracturing. The geochemistry of the magnetite suggests that the temperature increased from Mt2 to Mt3 and implies that there were multiple pulses of fluids from a magmatic-hydrothermal system. Therefore, we propose that the Xinqiao stratiform mineralization was genetically associated with multiple influxes of magmatic hydrothermal fluids derived from the Early Cretaceous Jitou stock. This study demonstrates that detailed texture examination and in situ trace-elements analysis under robust geological and petrographic frameworks can effectively constrain the mineralization processes and ore genesis.

scholarly journals Major and trace-element geochemistry of Late Cretaceous clastic rocks in the Jitai Basin, southeast China

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Kai Yan ◽  
Chun-lian Wang ◽  
Steffen Mischke ◽  
Jiu-yi Wang ◽  
Li-jian Shen ◽  
...  
Keyword(s):  
Late Cretaceous ◽  
Brackish Water ◽  
Inductively Coupled Plasma ◽  
Salt Water ◽  
Trace Element Geochemistry ◽  
Element Geochemistry ◽  
Humid Climate ◽  
Southeast China ◽  
Clastic Rocks ◽  
Wide Range

AbstractMajor, trace and rare earth element (REE) geochemistry of the late Cretaceous lower Zhoutian Formation from the Jitai Basin of Southeast China were measured by inductively coupled plasma mass spectrometry (ICP-MS) analysis to infer the provenance of the sediments and to reconstruct the palaeoenvironment and palaeoclimate. The wide range of Sr/Cu ratios point to a fluctuating palaeoclimate, and the negative correlation between the FeO/MnO and Al2O3/MgO ratios and the Sr/Cu ratio indicates that the late Cretaceous climate during the lower Zhoutian Formation in the Jitai Basin can be divided into two parts. The lower part experienced two cooling periods, whilst the upper part was dominated by warm-humid climate. Mostly corresponding trends of the B/Ga, Sr/Ba and Sr/Cu ratios show that the salinity changed consistently with the late Cretaceous climate during the lower Zhoutian Formation in the Jitai Basin. During the lower part, the salinity changed from salt water to fresh/brackish water. In the upper part, water was mainly fresh/brackish, and there were many changes from fresh/brackish water to salt water. The relatively stable Ni/Co, V/Cr, V/(V + Ni) and Ce/Ce* data indicate a long period of oxic conditions. The La-Th-Sc, Th-Sc-Zr/10 and La/Th-Hf data of the silt- and sandstones of the lower Zhoutian Formation show that its provenance was mainly a mixture of felsic upper crust sediments and older sedimentary rocks.

Trace Element Geochemistry and Mineral Inclusions Constraints on the Petrogenesis of a Marble–Hosted Ruby Deposit in Yunnan Province, China

2021 ◽  
Author(s):  
Wenqing Huang ◽  
Pei Ni ◽  
Ting Shui ◽  
Junyi Pan ◽  
Mingsen Fan ◽  
...  
Keyword(s):  
Trace Element ◽  
Inductively Coupled Plasma ◽  
Yunnan Province ◽  
Geographic Origin ◽  
Source Rocks ◽  
Trace Element Geochemistry ◽  
Mineral Inclusion ◽  
Element Geochemistry ◽  
Inductively Coupled ◽  
Mineral Inclusions

Abstract Primary rubies in the Ailao Shan of Yunnan Province, China, are found in three layers of marble. However, the origin and source rocks of placer rubies in the Yuanjiang area remains unclear. Trace element geochemistry and inclusion mineralogy within these materials can provide information on their petrogenesis and original source. Zircon, rutile, mica group minerals, titanite, and apatite group minerals were the main solid inclusions identified within the placer Yuanjiang rubies, along with other mineral inclusions such as pyrite, pyrrhotite, plagioclase group minerals, and scapolite group minerals. Laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) measurements showed that the placer rubies are characterized by average values of Mg (31 ppmw), Ti (97 ppmw), V (77 ppmw), Cr (3326 ppmw), Fe (71 ppmw), and Ga (66ppmw). A trace-element oxide diagram, Fe values (<350 ppmw), and the mineral inclusion assemblage suggest marble sources for the placer ruby. Therefore, the Yuanjiang rubies (both primary and placer) are metamorphic, and this fits well with the observations that skarn and related minerals are mostly absent in this deposit. Yuanjiang rubies can be readily separated from the high-iron rubies of different geological types by their Fe content (<1000 ppmw). The discriminators Mg, Ga, Cr, V, Fe, and Ti have potential in separating Yuanjiang rubies from some other marble-hosted deposits, such as Snezhnoe. Nevertheless, geographic origin determination remains a challenge when considering the similarities in compositional features between the Yuanjiang rubies and rubies from some other marble-hosted deposits worldwide (e.g., Luc Yen). The presence of kaolinite group minerals and clusters of euhedral, prismatic zircon crystals in ruby suggest a Yuanjiang origin.

scholarly journals Ore Mineralogy, Trace Element Geochemistry and Geochronological Constraints at the Mollehuaca and San Juan de Chorunga Au-Ag Vein Deposits in the Nazca-Ocoña Metallogenic Belt, Arequipa, Peru

Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1112
Author(s):  
Jorge Crespo ◽  
Elizabeth Holley ◽  
Katharina Pfaff ◽  
Madeleine Guillen ◽  
Roberto Huamani
Keyword(s):  
Inductively Coupled Plasma ◽  
Geological Mapping ◽  
Small Scale ◽  
Trace Element Geochemistry ◽  
San Juan ◽  
Element Geochemistry ◽  
Gold Mines ◽  
Inductively Coupled ◽  
Metallogenic Belt ◽  
Geochronological Constraints

The Mollehuaca and San Juan de Chorunga deposits are hosted in the poorly explored gold and copper trends of the Nazca-Ocoña metallogenic belt in Arequipa, Perú, which extends from Trujillo (9 °S) to Nazca-Ocoña (14 °S). The aim of this study is to characterize the age, occurrence, and distribution of quartz vein-hosted Au-Ag mineralization and associated trace elements (e.g., Hg, Pb, Cu, Zn, and Bi) in these deposits. Here, we present geological mapping, geochemical whole rock inductively coupled plasma (ICP)-MS data of the veins, petrographic observations, backscattered electron images, quantitative SEM-based automated mineralogy, and electron microprobe analyses (EMPA). Despite the fact that there are numerous small-scale gold mines in the Nazca-Ocoña metallogenic belt, there have been few studies that document the origin and geological evolution of these deposits or the implications for decision-making in exploration, metallurgical processing, and environmental management. In this research, we document the host rock age of the mineralized veins (129.2 ± 1.0 Ma; U-Pb in zircon), the mineralization age (95.86 ± 0.05 Ma; 40Ar/39Ar in secondary biotite), the occurrence and distribution of Au-Ag in the veins, the mineral zonation present in the vein system, and the zircon geochemistry, in order to provide tools for natural resource management in the metallogenic belt.

Significance of zircon trace element geochemistry, the Shihu gold deposit, western Hebei Province, North China

2011 ◽  
Vol 29 (3) ◽  
pp. 277-286 ◽  
Author(s):  
Ye CAO ◽  
Shengrong LI ◽  
Huafeng ZHANG ◽  
Xiaobin LIU ◽  
Zhenzhen LI ◽  
...  
Keyword(s):  
Trace Element ◽  
Gold Deposit ◽  
North China ◽  
Hebei Province ◽  
Trace Element Geochemistry ◽  
Element Geochemistry

scholarly journals Trace-element geochemistry of molybdenite from porphyry Cu deposits of the Birgilda-Tomino ore cluster (South Urals, Russia)

2018 ◽  
Vol 82 (S1) ◽  
pp. S281-S306 ◽  
Author(s):  
Olga Y. Plotinskaya ◽  
Vera D. Abramova ◽  
Elena O. Groznova ◽  
Svetlana G. Tessalina ◽  
Reimar Seltmann ◽  
...  
Keyword(s):  
Trace Element ◽  
Inductively Coupled Plasma ◽  
Porphyry Copper ◽  
Mass Spectrometry Data ◽  
South Urals ◽  
Trace Element Geochemistry ◽  
Porphyry Copper Deposits ◽  
Element Geochemistry ◽  
Inductively Coupled ◽  
Plasma Mass Spectrometry

ABSTRACTMineralogical, electron microprobe analysis and laser ablation-inductively coupled plasma-mass spectrometry data from molybdenite within two porphyry copper deposits (Kalinovskoe and Birgilda) of the Birgilda-Tomino ore cluster (South Urals) are presented.† The results provide evidence that molybdenites from these two sites have similar trace-element chemistry. Most trace elements (Si, Fe, Co, Cu, Zn, Ag, Sb, Te, Pb, Bi, Au, As and Se) form mineral inclusions within molybdenite. The Re contents in molybdenite vary from 8.7 ppm to 1.13 wt.%. The Re distribution within single molybdenite flakes is always extremely heterogeneous. It is argued that a temperature decrease favours the formation of Re-rich molybdenite. The high Re content of molybdenite observed points to a mantle-derived source.

scholarly journals Supplemental Material: Testing models of Laramide orogenic initiation by investigation of Late Cretaceous magmatic-tectonic evolution of the central Mojave sector of the California arc

2021 ◽  
Author(s):  
R.C. Economos ◽  
et al.
Keyword(s):  
Inductively Coupled Plasma ◽  
National Park ◽  
Granitic Rocks ◽  
Trace Element Geochemistry ◽  
Element Geochemistry ◽  
Inductively Coupled ◽  
Joshua Tree National Park ◽  
Icp Ms ◽  
Plasma Mass Spectrometry ◽  
Shrimp Zircon

<div>Table S1: SHRIMP zircon U-Pb geochronology data for six samples from the Cadiz Valley batholith. Table S2: SHRIMP zircon U-Pb geochronology data for six samples from the Federal 2-26 Cajon Pass drill core. Table S3: Whole-rock major- and trace-element geochemistry of granitic rocks from Joshua Tree National Park and the Cadiz Valley batholith measured by X-ray fluorescence (XRF) and inductively coupled plasma–mass spectrometry (ICP-MS). Table S4: Rb/Sr and Sm/Nd isotope data from the Joshua Tree National Park and Cadiz Valley batholith. Table S5: Locations, data, and references used to generate histograms in Figure 5.<br></div>

Characteristics of the hydrothermal system of the porphyry copper (gold) deposit at Shaxi, Eastern China

2021 ◽  
pp. 683-685
Author(s):  
Qijang Ren ◽  
Bing Fu ◽  
Wenxuan Hu ◽  
Wenyi Xu ◽  
Zhenhao Duan ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Hydrothermal System ◽  
Porphyry Copper ◽  
Eastern China ◽  
Copper Gold
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