scholarly journals Preliminary Data on the Nanoscale Chemical Characterization of the Inter-Crystalline Organic Matrix of a Calcium Carbonate Biomineral

Minerals ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 223 ◽  
Author(s):  
Alberto Pérez-Huerta ◽  
Fernando Laiginhas
1993 ◽  
Vol 330 ◽  
Author(s):  
Richard Humbert ◽  
M. Sarikayat ◽  
I. A. Aksay ◽  
J. W. Crabb ◽  
C. E. Furlong

ABSTRACTThe nacreous (mother-of-pearl) sections of molluscan shells are natural laminates of aragonitic calcium carbonate platelets and an organic matrix. The multi-edged platelets are sub-micrometer thick and surrounded on all sides by 10–20 nm-thick organic matrix that contains several proteins and polysaccharides. Our goal is to identify the components and structure of the organic matrix and determine their function in shell formation and organization. We have extracted organic material from red abalone-Haliotis rufescens, and chambered nautilus-Nautilus pompilius. From the soluble portion, we have partially purified two proteins and determined their amino acid compositions.


2014 ◽  
Vol 628 ◽  
pp. 115-119 ◽  
Author(s):  
Jun Ma ◽  
Li Ping Ma ◽  
De Hua Zhang ◽  
Bei Yan ◽  
Long Zhou ◽  
...  

Phosphogypsum is a by-product of industrial phosphoric acid producing with wet method, a simple and efficient way to produce high quality CaCO3by phosphogysum is presented in this work. Calcium in the phosphogypsum converts into Ca (OH)2with the addition of NaOH, acid insoluble substances and metal ion which was also separated from calcium in phosphogypsum by HCl and NH3·H2O respectively. The purity and whiteness of CaCO3produced by the carbonization of purified CaCl2solution are 98% and 96%. The optimum mass ratio of phosphogypsum, NaOH and HCl was 25:12:35. Chemical characterization of the resultant CaCO3was performed by XRD, SEM, TG and chemical titration method, which indicate that this method is effective in producing spherical CaCO3at room temperature, moreover, the purity, whiteness and thermostability of calcium carbonate can meet most of application requirements for industrial CaCO3.


2020 ◽  
Vol 27 (10) ◽  
pp. 1950224
Author(s):  
YU LIANG ◽  
SIJIA SUN ◽  
HAO DING ◽  
XIFENG HOU

A method of modifying calcium carbonate particles was investigated by coating sodium stearate or sodium oleate on the surface of calcium carbonate by wet method. The results of FTIR, activation and dispersion index, dispersity in kerosene, surface wettability tests and zeta potential tests show that sodium stearate or sodium oleate has successfully coated on the surfaces of calcium carbonate. The main factors were researched and the optimal parameters were obtained for the best modification effect. Compared with common rubber, the modified calcium carbonate added rubber has larger breaking tensile strength (more than 21%) and larger elongation at break (more than 16%). This research provides a feasible way of modifying calcium carbonate for its use as filler in organic matrix, reduces the cost and has a potential application in large-scale production of modified calcium carbonate.


1981 ◽  
Author(s):  
Birgitta Berglund ◽  
Ulf Berglund ◽  
Thomas Lindvall ◽  
Helene Nicander-Bredberg

1973 ◽  
Vol 74 (2) ◽  
pp. 226-236 ◽  
Author(s):  
Michel Chrétien ◽  
Claude Gilardeau

ABSTRACT A protein isolated from ovine pituitary glands has been purified, and its homogeneity assessed by NH2- and COOH-terminal amino acid determination, ultracentrifugation studies, and polyacrylamide gel electrophoresis after carboxymethylation. Its chemical and immunochemical properties are closely similar to those of beef and pork neurophysins, less similar to those of human neurophysins. It contains no tryptophan (like other neurophysins) or histidine (like all except bovine neurophysin-I and human neurophysins). It has alanine at the NH2-terminus and valine at the COOH-terminus. Its amino acid composition is similar to, but not identical with those of porcine and bovine neurophysins.


Alergologia ◽  
2020 ◽  
Vol 1 (4) ◽  
pp. 7
Author(s):  
Mariana Vieru ◽  
Florin-Dan Popescu ◽  
Laura Haidar ◽  
Carmen Bunu-Panaitescu

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