scholarly journals Petrography, Mineralogy, and Geochemistry of Thermally Altered Coal in the Tashan Coal Mine, Datong Coalfield, China

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1024
Author(s):  
Xiaoxia Song ◽  
Hongtao Ma ◽  
Benjamin M. Saalidong ◽  
Kaijie Li

A suite of coal samples near a diabase dike were collected to investigate the petrographic, mineralogical, and geochemical characteristics of thermally altered coal in Datong Coalfield, China. Proximate analysis, vitrinite reflectance measurement, and petrographic analysis were applied to identify and characterize the alteration halo; optical microscope observation, qualitative X-ray diffractometry, and SEM-EDS were applied to study the phases, occurrence, and composition of minerals; XRF, ICP-MS, and AFS were applied to determine concentrations of major and trace elements; and the occurrence modes of elements were studied by correlation and hierarchical cluster analysis as well as SEM-EDS. The results demonstrated that the 3.6 m dike has caused an alteration halo of approximately 2 m in diameter. In addition, the thermally altered coals were characterized by high vitrinite reflectance, low volatile matter, and the occurrence of thermally altered organic particles. Dolomite and ankerite in the thermally altered coal may be derived from hydrothermal fluids, while muscovite and tobelite may be transformed from a kaolinite precursor. The average concentration of Sr in the Tashan thermally altered coal reached 1714 μg/g, which is over 12 times that of the Chinese coal; the phosphate minerals and Sr-bearing kaolinite account for this significant enrichment. The cluster analysis classified elements with geochemical associations into four groups: group 1 and 2 were associated with aluminosilicates, clays, and carbonates and exhibited enrichment in the coal/rock contact zone, indicating that the dike may be the source of the elements; group 3 included P2O5, Sr, Ba, and Be, which fluctuate in coals, suggesting that their concentrations were influenced by multiple-factors; group 4 did not manifest obvious variations in coals, implying that the coal itself was the source.

2021 ◽  
Vol 56 (4) ◽  
pp. 484-490
Author(s):  
Irfan Marwanza ◽  
Chairul Nas ◽  
Masagus Ahmad Azizi ◽  
Riskaviana Kurniawati ◽  
Ardiansyah

Coal is a sedimentary rock containing approximately 50% to 70% carbon derived from the accumulation of plant residue that had undergone chemical and physical changes. In this research, the petrographic analysis method of coal was conducted based on the following parameters, measuring vitrinite reflectance (Ro%), estimation of moisture, volatile matter, and carbon-hydrogen content. This study aims to determine the zonation of coal rank through the vitrinite reflectance analysis in Maura Enim Formation. The samples observed were obtained from the Muara Enim Formation, which had undergone certain geological events to form lignite and anthracite coal ranks, then analyzed using the descriptive method. The results showed that the reflectance value of vitrinite was between 0.20% - 0.44%, which was utilized in the sorting of coal from lignite - sub-bituminous, according to ASTM D2798-06 (2006). Furthermore, in the Southwest region, coal is formed through greater pressure than those in the Northeast. Generally, the level of difference is caused by pressure, temperature, and time factor. Therefore, this study is recommended as a guideline in determining coal rank through vitrinite reflectance analysis in different formations.


2013 ◽  
Vol 807-809 ◽  
pp. 2215-2219
Author(s):  
Xiao Mei Wang ◽  
Yang Quan Jiao ◽  
Xiao Ming Wang ◽  
Li Qun Wu ◽  
Lei Qiao ◽  
...  

The concentration of fourteen environmentally important trace elements (Be, V, Cr, Co, Ni, Cu, Zn, Mo, Sn, Ba, Tl, Pb, Th and U) was studied in thirteen coal samples from Xinan coalfield, Henan province. In addition, virtrinite reflectance analysis, proximate analysis and elemental analysis were also conducted on these samples. The vitrinite reflectance values (Ro) ranges from 2% to 2.35%, revealing that these samples are lean coal. The coals have low moisture content, with Madvalue ranging from 0.57 to 0.95%. The ash and volatile matter content vary between 8.11-22.61% and 10.36-14.64%, respectively. Carbon, hydrogen, sulphur and nitrogen content vary between 71.51-83.54%, 3.068-3.879%, 0.494-2.326% and 0.953-1.38%, respectively. In comparison with the crustal average (Clarke value), some potentially hazardous elements are moderately enriched in the coals from Xinan coalfield, such as Pb, Th, U, Sn and Mo. The average concentration of most of the elements in Xinan coalfield coals is in the range of Chinese coals and world coals. No elements with the abnormally high concentrations analyzed are found.


2014 ◽  
Vol 59 (2) ◽  
pp. 509-516
Author(s):  
Andrzej Olajossy

Abstract Methane sorption capacity is of significance in the issues of coalbed methane (CBM) and depends on various parameters, including mainly, on rank of coal and the maceral content in coals. However, in some of the World coals basins the influences of those parameters on methane sorption capacity is various and sometimes complicated. Usually the rank of coal is expressed by its vitrinite reflectance Ro. Moreover, in coals for which there is a high correlation between vitrinite reflectance and volatile matter Vdaf the rank of coal may also be represented by Vdaf. The influence of the rank of coal on methane sorption capacity for Polish coals is not well understood, hence the examination in the presented paper was undertaken. For the purpose of analysis there were chosen fourteen samples of hard coal originating from the Upper Silesian Basin and Lower Silesian Basin. The scope of the sorption capacity is: 15-42 cm3/g and the scope of vitrinite reflectance: 0,6-2,2%. Majority of those coals were of low rank, high volatile matter (HV), some were of middle rank, middle volatile matter (MV) and among them there was a small number of high rank, low volatile matter (LV) coals. The analysis was conducted on the basis of available from the literature results of research of petrographic composition and methane sorption isotherms. Some of those samples were in the form (shape) of grains and others - as cut out plates of coal. The high pressure isotherms previously obtained in the cited studies were analyzed here for the purpose of establishing their sorption capacity on the basis of Langmuire equation. As a result of this paper, it turned out that for low rank, HV coals the Langmuire volume VL slightly decreases with the increase of rank, reaching its minimum for the middle rank (MV) coal and then increases with the rise of the rank (LV). From the graphic illustrations presented with respect to this relation follows the similarity to the Indian coals and partially to the Australian coals.


2015 ◽  
pp. 125-138 ◽  
Author(s):  
I. V. Goncharenko

In this article we proposed a new method of non-hierarchical cluster analysis using k-nearest-neighbor graph and discussed it with respect to vegetation classification. The method of k-nearest neighbor (k-NN) classification was originally developed in 1951 (Fix, Hodges, 1951). Later a term “k-NN graph” and a few algorithms of k-NN clustering appeared (Cover, Hart, 1967; Brito et al., 1997). In biology k-NN is used in analysis of protein structures and genome sequences. Most of k-NN clustering algorithms build «excessive» graph firstly, so called hypergraph, and then truncate it to subgraphs, just partitioning and coarsening hypergraph. We developed other strategy, the “upward” clustering in forming (assembling consequentially) one cluster after the other. Until today graph-based cluster analysis has not been considered concerning classification of vegetation datasets.


Author(s):  
Nikunj D. Patel ◽  
Niranjan S. Kanaki

Background: Numerous Ayurvedic formulations contains tugaksheeree as key ingredient. Tugaksheereeis the starch gained from the rhizomes of two plants, Curcuma angustifoliaRoxb. (Zingiberaceae) and Marantaarundinacea (MA) Linn. (Marantaceae). Objective: The primary concerns in quality assessment of Tugaksheeree occur due to adulteration or substitution. Method: In current study, Fourier transform infrared (FTIR) technique with attenuated total reflectance (ATR) facility was used to evaluate tugaksheeree samples. Total 10 different samples were studied and transmittance mode was kept to record the spectra devoid of pellets of KBR. Further treatment was given with multi component tools by considering fingerprint region of the spectra. Multivariate analysis was performed by various chemometric methods. Result: Multi component methods like Principal Component Analysis (PCA), and Hierarchical Cluster Analysis (HCA)were used to discriminate the tugaksheeree samples using Minitab software. Conclusion: This method can be used as a tool to differentiate samples of tugaksheeree from its adulterants and substitutes.


Author(s):  
Milan Radojicic ◽  
Aleksandar Djokovic ◽  
Nikola Cvetkovic

Unpredictable and uncontrollable situations have happened throughout history. Inevitably, such situations have an impact on various spheres of life. The coronavirus disease 2019 has affected many of them, including sports. The ban on social gatherings has caused the cancellation of many sports competitions. This paper proposes a methodology based on hierarchical cluster analysis (HCA) that can be applied when a need occurs to end an interrupted tournament and the conditions for playing the remaining matches are far from ideal. The proposed methodology is based on how to conclude the season for Serie A, a top-division football league in Italy. The analysis showed that it is reasonable to play 14 instead of the 124 remaining matches of the 2019–2020 season to conclude the championship. The proposed methodology was tested on the past 10 seasons of the Serie A, and its effectiveness was confirmed. This novel approach can be used in any other sport where round-robin tournaments exist.


BMJ Open ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. e033290
Author(s):  
Karel Blondeel ◽  
Sonia Dias ◽  
Martina Furegato ◽  
Armando Seuc ◽  
Ana Gama ◽  
...  

ObjectivesPortugal has the highest HIV incidence rate in Western Europe. The proportion assigned to sexual contact between men recently increased to more than 30% of all HIV infections. Men who have sex with men (MSM) are vulnerable to the acquisition of other sexually transmitted infections (STIs), increasing the per-contact risk of HIV infection. Building on syndemic theory, the aim of this analysis was to identify patterns of current sexual behaviour in MSM, and explore their relationship with self-reported current, past STI diagnoses and HIV positive serostatus.DesignA cross-sectional behavioural survey was conducted in Portugal among MSM, using a community-based participatory research approach. Hierarchical cluster analysis was used to identify patterns including behavioural and demographic factors.ResultsThe analysis resulted in six clusters. Three clusters showed higher rates of current STI diagnosis (ranging from 11.7% to 17.1%), past STI diagnosis (ranging from 25.5% to 41.5%) and HIV positive serostatus (ranging from 13.0% to 16.7%). From the three clusters scoring lower on current and past STI and HIV diagnoses, one was characterised by a high number of sexual partners (62% had more than 12 partners in the last year), a high proportion (94.6%) of frequent visits to gay venues to meet sexual partners and high alcohol use (46.1%). The other two clusters scored lower on high risk sexual behaviour.ConclusionFactors other than sexual behaviour appear to reinforce the vulnerability to STIs and HIV of some MSM in this study, suggesting a syndemic of STIs, HIV and other adverse conditions. More research is needed to better understand the drivers of the STI/HIV epidemic in Portuguese MSM, using a concept that goes beyond risk behaviour, to develop effective combination prevention interventions.


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