scholarly journals Decoupling of Sr-Nd Isotopic Composition Induced by Potassic Alteration in the Shapinggou Porphyry Mo Deposit of the Qinling–Dabie Orogenic Belt, China

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 910
Author(s):  
Jun He ◽  
Xiaochun Xu ◽  
Zhongyang Fu ◽  
Yuhua An ◽  
Tianhu Chen ◽  
...  

In our previous study on petrogenesis of quartz syenite and granite porphyry, the host rocks of the Late Mesozoic Shapinggou Mo deposit in the Qinling–Dabie orogenic belt, we found that the initial Sr isotopic composition of the host rocks is strongly affected by the degree of K-alteration. Here, we provide further isotopic evidence of the host rocks and their minerals to investigate the geochemical behaviour of trace elements and isotopes during the alteration and to explain the phenomenon of decoupling of Sr–Nd isotopic composition. The quartz syenite and granite porphyry are altered by K-alteration in varying degrees and have high K2O and Rb contents and low Na2O, CaO, Sr, and Ba contents. Rock samples of both quartz syenite and granite porphyry have variable Rb/Sr ratios and initial 87Sr/86Sr values (even < 0.70) but contain quite homogeneous εNd(t) values (−12.8 to −14.8). Minerals from the rocks of moderate to intense K-alteration have very low initial 87Sr/86Sr values (even < −17), while those from the weakly altered rocks have 87Sr/86Sr(t) values of 0.7044 to 0.7084. The same phenomenon of the decoupling in Sr–Nd isotopic composition can be observed from several Mo deposits within the eastern Qinling–Dabie orogenic belt. This fact suggests similar hydrothermal features and a comparable origin for both the magmatic rocks and hydrothermal fluids in this belt. A comparison between porphyry Mo and porphyry Cu deposits shows that elements and the Rb–Sr isotope system have different behaviours during the K-alteration, implying distinct material sources and igneous rocks for porphyry Mo and porphyry Cu deposits, respectively.

2020 ◽  
Vol 57 (2) ◽  
pp. 249-266 ◽  
Author(s):  
Song-Jie Wang ◽  
Hans-Peter Schertl ◽  
Yu-Mao Pang

Late Mesozoic granitic rocks are widely distributed in the Sulu orogenic belt, but the source, tectonic affinity, and associated geodynamic setting that produced the respective magmas remain controversial. To provide insights into these issues, we present field-based petrological, whole-rock major and trace element and Sr–Nd isotope geochemical, zircon U–Pb dating, and Lu–Hf isotope studies on two types of granite porphyry dykes that are newly recognized from the central Sulu belt. U–Pb dating of magmatic zircons from both types yields consistent ages that vary between 124 ± 2 and 118 ± 2 Ma, constraining the timing of intrusion as Early Cretaceous. The granitic rocks have high-K calc-alkaline peraluminous compositions with low Mg# values and are characterized by fractionated rare earth element patterns with strong depletion in high field strength elements. Compared with type I of the granite porphyry dykes, type II exhibits higher SiO2 but slightly lower Na2O and K2O abundances, contains higher Rb/Sr and 87Sr/86Sr ratios, and shows more pronounced negative Eu, Sr, and Ba anomalies. Both types I and II have high initial 87Sr/86Sr ratios of 0.709–0.711 and negative εNd(t) values of −19.8 to −18.4. The magmatic zircons possess negative εHf(t) values of −29.1 to −20.8, with mostly Neoarchean Hf model ages of 3001–2478 Ma. These features, together with the presence of Neoproterozoic inherited zircons, indicate that the two types of granite porphyries successively crystallized from a joint granite magma that derived from partial melting of the continental crust of the Yangtze Craton. Therefore, an interrelationship between the granite porphyry dykes and massive magmatic granitoids from adjacent regions in the Sulu belt may be documented, recording evidence of a joint ancient crustal reworking and recycling in a fossilized continental subduction zone during the Early Cretaceous.


2019 ◽  
Vol 56 (4) ◽  
pp. 380-398 ◽  
Author(s):  
Jing-gui Sun ◽  
Yun-peng He ◽  
Ji-long Han ◽  
Zhong-yu Wang

The Wuxing Pt–Pd-rich Cu–Ni sulfide deposit in Heilongjiang Province, Northeast China, is located to the northeast of the Dunhua–Mishan fracture of the eastern Central Asian Orogenic Belt. The mafic–ultramafic complex consist of early-period hornblende–olivine pyroxenite, diopsidite, and hornblende pyroxenite and late-period gabbro and diabase units. An early-period hornblende pyroxenite yielded a zircon U–Pb age of 208.2 ± 2.6 Ma and a late-period diabase yielded a U–Pb age of 205.6 ± 1.1 Ma, with zircon εHf(t) values of +1.24 to +8.13. The early- and late-period lithofacies are relatively enriched in LILE (Rb, Ba, and Sr) and LREE, and variably depleted in HFSE (Nb, Ta). The whole-rock and single-mineral analyses of the early-period lithofacies yield (87Sr/86Sr)i ratios of 0.7055–0.7083 and εNd(t) ratios of −7.98–+3.10. These geochemical data suggest that the parental magmas of the Wuxing complex are high-Mg subalkaline basaltic in nature and were derived from an enriched mantle source. The magmas chamber formed after the injection of magma into the crust along with crustal contamination, producing early crystalline minerals and ore-bearing magmas. The rupturing of the magma chamber released evolved magmas, which then ascended and generated Pt–Pd-bearing lithofacies and Cu–Ni sulfide orebodies by fractional crystallization, accumulation, and liquation. During the late period, the residual magma invaded the early lithofacies and Cu–Ni orebodies. The fluids exsolved from the gabbroic magmas concentrated the mineralized metal elements and enhanced the precipitation of Pt–Pd-bearing veinlet-disseminated orebodies and Pt–Pd–Cu–Ni orebodies.


2012 ◽  
Vol 03 (03) ◽  
pp. 463-468
Author(s):  
Chris Anani ◽  
Daniel Asiedu ◽  
Johnson Manu ◽  
Prosper Nude ◽  
Jacob Kutu ◽  
...  

2020 ◽  
pp. 1-17
Author(s):  
Zhendong Wang ◽  
Yuanyuan Zhang ◽  
Xiangjiang Yu ◽  
Zhaojie Guo

Abstract The Duobagou Permian–Triassic granites of the Dunhuang orogenic belt are of great importance in understanding the tectonic evolution of the southernmost Central Asian Orogenic Belt. LA-ICP-MS U–Pb zircon ages indicate that Permian–Triassic granitic intrusions from the Duobagou area formed at 276–274 Ma and 246 ± 1 Ma. These granites have high SiO2, Na2O and K2O, but low Al2O3, CaO and MgO contents and belong mainly to the high-K calc-alkaline I-type granite series. Based on whole-rock geochemistry and Sr–Nd and zircon Hf isotopes, the Duobagou Permian–Triassic granites were dominantly derived from the partial melting of lower continental crust formed during late Palaeoproterozoic to Mesoproterozoic times in a post-collisional extensional setting. Permian granites with zircon ϵHf(t) values of −5.4 to +3.1 and Hf model ages of TDM2 = 1.14–1.70 Ga indicate the involvement of a mantle component in their petrogenesis. Triassic granites with higher zircon ϵHf(t) values (+0.5 to +3.8) and TDM2 = 1.08–1.31 Ga suggest more juvenile sources caused by a greater contribution of mantle-derived melts, indicating a significant crustal growth. Regional extension from lithospheric delamination and heating from asthenospheric upwelling were proposed to have triggered the partial melting of lower crust, resulting in the generation of the Permian–Triassic magmatism. This may have been the mechanism for the significant crustal growth during Permian and Triassic times in the southernmost Central Asian Orogenic Belt.


1990 ◽  
Vol 85 (1-2) ◽  
pp. 119-134 ◽  
Author(s):  
G.W. Eberz ◽  
I.A. Nicholls ◽  
R. Maas ◽  
M.T. McCulloch ◽  
D.J. Whitford

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