scholarly journals Freeze–Thaw and Salt Crystallization Durability of Silica Acid Ester Consolidated Porous Limestone from Hungary

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 824
Author(s):  
Zita Pápay ◽  
Nikoletta Rozgonyi-Boissinot ◽  
Ákos Török
Keyword(s):  
Tensile Strength ◽  
Water Saturation ◽  
Sodium Sulphate ◽  
Salt Crystallization ◽  
Strength Increase ◽  
Stone Conservation ◽  
Initial Strength ◽  
Freeze Thaw ◽  
Fine Grained

The durability of consolidated highly porous limestones was tested after salt and freeze–thaw cycles. Three porous limestone lithotypes that were commonly used in construction in the Central-European region during previous centuries were selected for the tests. Specimens of Miocene limestone were consolidated with four different types of ethyl silica-based consolidants (KSE 100, KSE 300, KSE 300 E, KSE 300 HV). After consolidation, the samples were exposed to freeze thaw cycles and salt crystallization tests. Water saturation under atmospherically pressure, capillary water absorption and splitting tensile strength were measured on treated and untreated samples to assess change attributed to consolidation in the open porosity and mechanical parameters. The increase in the tensile strength of the medium-grained samples was higher than that of the consolidated fine-grained lithotypes. The effect of consolidation treatment was very different in terms of pore-size distribution as obtained by Mercury intrusion porosimetry (MIP). Untreated and consolidated samples were subjected to 10 cycles of sodium sulphate crystallization (EN 12370) and 10 freeze–thaw cycles (EN 12371) tests. Experiments concluded that in addition to the initial strength increase after the conservation, the modified pore structure is the crucial factor to evaluate the long-term efficiency of stone conservation.

Damaging effect of salt crystallization on highly porous limestone from Hungary

2020 ◽  
Author(s):  
Nikoletta Rozgonyi-Boissinot ◽  
Mohammad Ali Khodabandeh
Keyword(s):  
Tensile Strength ◽  
Sea Water ◽  
Water Saturation ◽  
Salt Content ◽  
Physical And Mechanical Properties ◽  
Optical Microscope ◽  
Sodium Sulphate ◽  
Capital City ◽  
Salt Crystallization ◽  
Petrophysical Properties

<p>One of the most important weathering processes on stone-built monuments is the crystallization of salts. Since the transport material of these substances is water, the porous rock types are particularly affected. In Hungary many monuments and historic buildings have been constructed from oolithic Miocene limestone. So in this study, the effect of salt crystallization on the physical and mechanical properties of high porous limestone has been investigated. Samples were obtained from Sóskút (near to Budapest, the capital city of Hungary).</p><p>At first the petrophysical properties of the stone were determined. The porosity of the investigated stone type was 26-34 V/V%, the uniaxial compressive strength (4-5 MPa) and the Brazilian tensile strength (0,4-0,5 MPa) were very low. A special proper of this rock type is the large-pore system (2-3mm) between the ooid fragments.</p><p>Sodium chloride (NaCl) and sodium sulphate (Na<sub>2</sub>SO<sub>4</sub>) were used to investigate the effect of salt crystallization. Cylindrical rock samples were exposed to salt solutions of 14 m/m% Na<sub>2</sub>SO<sub>4</sub> (MSZ EN 12370) and 5% NaCl solution (sea water salt content). After 15 salted water saturation- drying cycles the changes of mineralogical and petrophysical properties and indirect tensile strength of the samples were investigated. The damages on the pore walls were determined with scanning electron microscope (SEM) and the building of scaling layers on the stone surfaces were investigated with optical microscope.</p>

scholarly journals Physically Crosslinked Chitosan/PVA Hydrogels Containing Honey and Allantoin with Long-Term Biocompatibility for Skin Wound Repair: An In Vitro and In Vivo Study

2021 ◽  
Vol 12 (4) ◽  
pp. 61
Author(s):  
Mojtaba Koosha ◽  
Hadis Aalipour ◽  
Mohammad Javad Sarraf Shirazi ◽  
Ali Jebali ◽  
Hong Chi ◽  
...  
Keyword(s):  
Wound Healing ◽  
Tensile Strength ◽  
Wound Repair ◽  
Dermal Fibroblast ◽  
Normal Human Dermal Fibroblast ◽  
Gel Content ◽  
Freeze Thaw

Chitosan/PVA hydrogel films crosslinked by the freeze–thaw method and containing honey and allantoin were prepared for application as wound dressing materials. The effects of the freeze–thaw process and the addition of honey and allantoin on the swelling, the gel content and the mechanical properties of the samples were evaluated. The physicochemical properties of the samples, with and without the freeze–thaw process, were compared using FTIR, DSC and XRD. The results showed that the freeze–thaw process can increase the crystallinity and thermal stability of chitosan/PVA films. The freeze–thaw process increased the gel content but did not have a significant effect on the tensile strength. The presence of honey reduced the swelling and the tensile strength of the hydrogels due to hydrogen bonding interactions with PVA and chitosan chains. Long-term cell culture experiments using normal human dermal fibroblast (NHDF) cells showed that the hydrogels maintained their biocompatibility, and the cells showed extended morphology on the surface of the hydrogels for more than 30 days. The presence of honey significantly increased the biocompatibility of the hydrogels. The release of allantoin from the hydrogel was studied and, according to the Korsmeyer–Peppas and Weibull models, the mechanism was mainly diffusional. The results for the antimicrobial activity against E. coli and S. aureus bacteria showed that the allantoin-containing samples had a more remarkable antibacterial activity against S. aureus. According to the wound healing experiments, 98% of the wound area treated by the chitosan/PVA/honey hydrogel was closed, compared to 89% for the control. The results of this study suggest that the freeze–thaw process is a non-toxic crosslinking method for the preparation of chitosan/PVA hydrogels with long term biocompatibility that can be applied for wound healing and skin tissue engineering.

scholarly journals Effects of Water on Natural Stone in the Built Environment—A Review

Geosciences ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 459
Author(s):  
Carlos Alves ◽  
Carlos A. M. Figueiredo ◽  
Jorge Sanjurjo-Sánchez ◽  
Ana C. Hernández
Keyword(s):  
Built Environment ◽  
Salt Crystallization ◽  
Salt Weathering ◽  
Laboratory Studies ◽  
Physical Damage ◽  
Stone Conservation ◽  
Running Water ◽  
Freeze Thaw ◽  
Clastic Rocks ◽  
The Impact

The present work reviews studies with information on the effects of water by itself on stones of the built environment both to assess the impact of this substance and to discuss possible implications for conservation. The analysis concerns empirical results from previous publications dealing with the effects, on several rock types, of freeze–thaw, wetting, erosion by running water and substances resulting from the water–stone interaction. Laboratory studies have shown that water freezing can cause physical damage even in low porosity rocks. As far as we know, this is the first review that considers comparative laboratory studies of freeze–thaw and salt crystallization on the same rock specimens, and these point to lower erosive effects than salt weathering, as freeze–thaw can provoke catastrophic cracking. Wetting has shown strong damaging effects on some fine-grained clastic rocks. Erosive features have been reported for rain exposition and for some fountain settings albeit, in these field studies, it could be difficult to assess the contribution of pollutants transported by water (this assessment could have meaningful implications for stone conservation, especially in fountain settings). Water also interacts with stone constituents, namely sulfides and soluble salts, releasing substances that could impact those stones. Sulfides are a relatively frequent issue for slates and granites, and our observations suggest that for this last rock type, this issue is mostly associated with the presence of enclaves and, hence, avoiding the surface exposition of such enclaves could solve the problem.

ATI 6-2-4-2

Alloy Digest ◽  
2020 ◽  
Vol 69 (8) ◽  
Keyword(s):  
Tensile Strength ◽  
Titanium Alloy ◽  
High Temperature ◽  
Creep Strength ◽  
High Strength ◽  
Heat Treating ◽  
Good Combination ◽  
Long Term Stability ◽  
Temperature Performance

Abstract ATI 6-2-4-2 is a near-alpha, high strength, titanium alloy that exhibits a good combination of tensile strength, creep strength, toughness, and long-term stability at temperatures up to 425 °C (800 °F). Silicon up to 0.1% frequently is added to improve the creep resistance of the alloy. This datasheet provides information on composition, physical properties, hardness, and tensile properties as well as creep. It also includes information on high temperature performance as well as forming, heat treating, machining, and joining. Filing Code: Ti-169. Producer or Source: ATI.

scholarly journals Domain randomization-enhanced deep learning models for bird detection

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Xin Mao ◽  
Jun Kang Chow ◽  
Pin Siang Tan ◽  
Kuan-fu Liu ◽  
Jimmy Wu ◽  
...  
Keyword(s):  
Deep Learning ◽  
Continuous Monitoring ◽  
Bird Species ◽  
Training Data ◽  
Learning Models ◽  
Fine Grained ◽  
Bird Detection ◽  
Relationship Of ◽  
The Relationship

AbstractAutomatic bird detection in ornithological analyses is limited by the accuracy of existing models, due to the lack of training data and the difficulties in extracting the fine-grained features required to distinguish bird species. Here we apply the domain randomization strategy to enhance the accuracy of the deep learning models in bird detection. Trained with virtual birds of sufficient variations in different environments, the model tends to focus on the fine-grained features of birds and achieves higher accuracies. Based on the 100 terabytes of 2-month continuous monitoring data of egrets, our results cover the findings using conventional manual observations, e.g., vertical stratification of egrets according to body size, and also open up opportunities of long-term bird surveys requiring intensive monitoring that is impractical using conventional methods, e.g., the weather influences on egrets, and the relationship of the migration schedules between the great egrets and little egrets.

scholarly journals Non-Local and Multi-Scale Mechanisms for Image Inpainting

Sensors ◽  
2021 ◽  
Vol 21 (9) ◽  
pp. 3281
Author(s):  
Xu He ◽  
Yong Yin
Keyword(s):  
Markov Random Fields ◽  
Receptive Fields ◽  
Image Inpainting ◽  
Long Distance ◽  
Visual Appearance ◽  
Fine Grained ◽  
Multi Scale ◽  
Non Local ◽  
Relationship Of

Recently, deep learning-based techniques have shown great power in image inpainting especially dealing with squared holes. However, they fail to generate plausible results inside the missing regions for irregular and large holes as there is a lack of understanding between missing regions and existing counterparts. To overcome this limitation, we combine two non-local mechanisms including a contextual attention module (CAM) and an implicit diversified Markov random fields (ID-MRF) loss with a multi-scale architecture which uses several dense fusion blocks (DFB) based on the dense combination of dilated convolution to guide the generative network to restore discontinuous and continuous large masked areas. To prevent color discrepancies and grid-like artifacts, we apply the ID-MRF loss to improve the visual appearance by comparing similarities of long-distance feature patches. To further capture the long-term relationship of different regions in large missing regions, we introduce the CAM. Although CAM has the ability to create plausible results via reconstructing refined features, it depends on initial predicted results. Hence, we employ the DFB to obtain larger and more effective receptive fields, which benefits to predict more precise and fine-grained information for CAM. Extensive experiments on two widely-used datasets demonstrate that our proposed framework significantly outperforms the state-of-the-art approaches both in quantity and quality.

Influence of Alkalinity and Ambient Temperature on Long-Term Properties of GFRP Reinforcement

2018 ◽  
Vol 760 ◽  
pp. 213-218
Author(s):  
František Girgle ◽  
Lenka Bodnárová ◽  
Ondřej Januš ◽  
Vojtěch Kostiha
Keyword(s):  
Tensile Strength ◽  
Ambient Temperature ◽  
Mechanical Characteristics ◽  
Current Problem ◽  
Concrete Structures ◽  
Experimental Program ◽  
Glass Fibres ◽  
Metallic Reinforcement ◽  
Gfrp Reinforcement

The article deals with the current problem of determining long-term reliability of non-metallic reinforcement in concrete structures. The alkaline environment of concrete with a pH higher than 12.0 affects the glass fibres degradative, whereas this degradation presents by reduction of their mechanical characteristics, resulting in a decrease in the tensile strength of the whole composite. The article summarizes the results of the ongoing experimental program so far, which aims to quantify this influence.

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