scholarly journals Geochemistry of Sphalerite from the Permian Volcanic-Hosted Massive Sulphide (VHMS) Deposits in the Tasik Chini Area, Peninsular Malaysia: Constraints for Ore Genesis

Minerals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 728
Author(s):  
Mohd Basril Iswadi Basori ◽  
Sarah E. Gilbert ◽  
Khin Zaw ◽  
Ross R. Large
Keyword(s):  
Variable Temperature ◽  
Mineral Chemistry ◽  
Peninsular Malaysia ◽  
Massive Sulphide ◽  
Compositional Variation ◽  
Volcanic Origin ◽  
Sedimentary Deposits ◽  
Depositional Processes ◽  
Tasik Chini ◽  
Vhms Deposits

The Bukit Botol and Bukit Ketaya deposits are two examples of volcanic-hosted massive sulphide (VHMS) deposits that occur in the Tasik Chini area, Central Belt of Peninsular Malaysia. The mineralisation is divided into subzones distinguished by spatial, mineralogical, and textural characteristics. The primary sulphide minerals include pyrite, chalcopyrite, sphalerite, and galena, with lesser amounts of Sn- and Ag-bearing minerals, with Au. However, pyrrhotite is absent from both deposits. This study presents the results of sphalerite chemistry analysed by using an electron microprobe. Two types of sphalerite are recognised: sphalerite from the Bukit Botol deposit reveals a range of <DL to 24.0 mole% FeS, whereas sphalerite from the Bukit Ketaya deposit shows a range of <DL to 3 mole% FeS. Significant variations are shown in Zn, Cu, Cd, and Ag levels. Although the sphalerite has a wide variation in composition, a discernible decreasing Fe trend is exhibited from the stringer zone towards massive sulphide. This compositional variation in sphalerites may in part reflect variable temperature and activity of sulphur in the hydrothermal fluids during ore formation. Alternatively, the bimodal composition variations suggest that mineral chemistry relates to contrasting depositional processes. The Zn/Cd ratios for sphalerite from both these deposits are similar to those exhibited by volcano−sedimentary deposits with a volcanic origin. Therefore, the consistently low Cd concentrations and moderate to high Zn/Cd ratios suggest mixing of seawater and minor magmatic fluids controlling the chemistry of sphalerite at both deposits during their formation.

scholarly journals Sulfur isotope characteristics of the Permian VHMS deposits in Tasik Chini district, Central Belt of Peninsular Malaysia

2017 ◽  
Vol 26 ◽  
pp. 91-103 ◽  
Author(s):  
Mohd Basr BASORI ◽  
Khin ZAW ◽  
Robert Ross LARGE ◽  
Wan Fuad W. HASSAN
Keyword(s):  
Sulfur Isotope ◽  
Peninsular Malaysia ◽  
Central Belt ◽  
Tasik Chini ◽  
Vhms Deposits

Microthermometric evidence for the formation of Permian VHMS deposits in Tasik Chini area, Central Belt of Peninsular Malaysia

2019 ◽  
Vol 111 ◽  
pp. 102947 ◽  
Author(s):  
Mohd Basril Iswadi Basori ◽  
Khin Zaw ◽  
Terrence Patrick Mernagh ◽  
Ross Raymond Large
Keyword(s):  
Peninsular Malaysia ◽  
Central Belt ◽  
Tasik Chini ◽  
Vhms Deposits

scholarly journals New insight on tide-dominated estuary and delta in the Eocene-Miocene Mrayt Group, North-Western Rif, Morocco

2021 ◽  
Author(s):  
Hamoumi Naima ◽  
choukri chacrone ◽  
Silvia Spezzaferri
Keyword(s):  
Sedimentary Facies ◽  
Carbonate Sediments ◽  
Sedimentary Deposits ◽  
Depositional Processes ◽  
Sea Level Fluctuation ◽  
The Subject ◽  
Depositional Systems ◽  
New Interpretation ◽  
Petrographic Study ◽  
North Western

The sedimentary deposits of Eocene-Miocene Mrayt Group, North-Western Rif, Morocco has been the subject of controversy by previous authors regarding their depositional environment. Detailed sedimentological study based on petrographic and sedimentary facies analysis, ichnofacies interpretation and paleocurrent measurements, leads to several results and new insights. Petrographic study provided the first evidence of mixed siliciclastic and carbonate sediments and their nomenclature: silty micrites, micritic siltstones, micritic sandstones, sandy micrite, and allochemic sandstones, as well as the nature of the sources and its geological context. Twenty two sedimentary facies that have never been described before are identified, and based on their succession and association a new interpretation of depositional processes and depositional systems are proposed. The paleoenvironments of the Mrayt Group are interpreted as littoral and shallow marine settings: tides- dominated estuary, tides-dominated delta systems and open coast tidal flat, under complex hydrodynamics strongly influenced by river discharge, tidal currents, waves and storms action.Sedimentation occurred in “the Maghrebian basin” under the interplay of: i) tectonics related to the Cenozoic collision of the African and Eurasian continental plates, ii) Cenozoic alternation of warm climate and cooling due to the increasing influence of Antarctica glaciation, iii) sediments supplies induced by rejuvenation of sedimentary sources and iv) sea level fluctuation related to the advance and retreat of ice-sheet on Antarctica.

scholarly journals Changes in Halogen (F, Cl, Br, and I) and S Ratios in Rock-Forming Minerals as Monitors for Magmatic Differentiation, Volatile-Loss, and Hydrothermal Overprint: The Case for Peralkaline Systems

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 995 ◽  
Author(s):  
Hans G.M. Eggenkamp ◽  
Michael A.W. Marks ◽  
Petya Atanasova ◽  
Thomas Wenzel ◽  
Gregor Markl
Keyword(s):  
Mineral Chemistry ◽  
Hydrothermal Systems ◽  
Fluid Loss ◽  
Volatile Components ◽  
Compositional Variation ◽  
Magmatic Differentiation ◽  
Charge Balance ◽  
Rock Interaction ◽  
Eudialyte Group ◽  
Volatile Loss

We determined the halogen (F, Cl, Br, and I) and sulfur (S) concentrations in Cl-rich rock-forming minerals from five peralkaline complexes. We investigated sodalite (N = 42), eudialyte-group minerals (N = 84), and tugtupite (N = 8) from representative rock samples derived from Ilímaussaq (South Greenland), Norra Kärr (Sweden), Tamazeght (Morocco), Lovozero, and Khibina (Russian Federation). Taken together, sodalite and eudialyte-group minerals dominate the Cl and Br budget of the investigated rocks. For F, however, several other phases (e.g., amphibole, fluorite, villiaumite, and minerals of the rinkite group and the apatite supergroup) are additional sinks, and parts of the S may be scavenged in generally rare sulfides. The investigated minerals contain Cl at the wt.% level, F and S concentrations are in the hundreds to thousands of µg/g-range, Br is less common (0.2–200 µg/g) and I is rare (mostly well below 1 µg/g). Normalized to Cl, sodalite prefers Br relative to eudialyte-group minerals, while F is always enriched in the latter. Our data show that both F and S may represent important components in eudialyte-group minerals, sometimes at similar levels as Cl, which normally dominates. Sulfur reveals redox-dependent behavior: Under reduced crystallization conditions, S is more compatible in eudialyte-group minerals (EGM) than in sodalite, which flips to the opposite under water-rich and presumably more oxidized conditions. We investigate the applicability of F/Cl, Br/Cl, and S/Cl ratios in these minerals in peralkaline systems to better understand the interplay of magmatic differentiation, fluid loss and hydrothermal overprint. Similar to apatite in metaluminous systems, fractionation of sodalite, and eudialyte-group minerals in peralkaline magmas leads to decreasing Br/Cl ratios. The data presented in this study bear implications for the mineral chemistry and compositional variation of sodalite and especially EGM in general. Volatile components in EGM that are not normally considered, such as F and S, can reach concentrations of thousands of µg/g. Especially in the case of F, with its low atomic weight, the results obtained in this study indicate that it is very significant for formulae calculations, neutral charge-balance, and similar aspects at such concentration levels. This study demonstrates that halogen contents and ratios are sensitive monitors for a variety of processes in magmatic-hydrothermal systems, including magmatic fractionation, volatile loss, and fluid–rock interaction.

Sign in / Sign up

Export Citation Format

Share Document