scholarly journals Nonlinear Mixing Characteristics of Reflectance Spectra of Typical Mineral Pigments

Minerals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 626
Author(s):  
Shuqiang Lyu ◽  
Die Meng ◽  
Miaole Hou ◽  
Shuai Tian ◽  
Chunhao Huang ◽  
...  
Keyword(s):  
Nonlinear Model ◽  
Experimental Approach ◽  
Spectral Characteristics ◽  
Chinese Painting ◽  
Mixing Models ◽  
Nonlinear Mixing ◽  
Shortwave Infrared ◽  
Fully Constrained Least Squares ◽  
Spectral Mixing ◽  
Continuum Removal

Hyperspectral technology has been used to identify pigments that adhere to the surfaces of polychrome artifacts. However, the colors are often produced by the mixing of pigments, which requires that the spectral characteristics of the pigment mixtures be considered before pigment unmixing is conducted. Therefore, we proposed an experimental approach to investigate the nonlinear degree of spectral reflectance, using several mixing models, and to evaluate their performances in the study of typical mineral pigments. First, five mineral pigments of azurite, malachite, cinnabar, orpiment, and calcite were selected to form five groups of samples, according to their different mass ratios. Second, a fully constrained least squares algorithm based on the linear model and three algorithms based on the nonlinear model were employed to calculate the proportion of each pigment in the mixtures. We evaluated the abundance accuracy as well as the similarity between the measured and reconstructed spectra produced by those mixing models. Third, we conducted pigment unmixing on a Chinese painting to verify the applicability of the nonlinear model. Fourth, continuum removal was also introduced to test the nonlinearity of mineral pigment mixing. Finally, the results indicated that the spectral mixing of different mineral pigments was more in line with the nonlinear mixing model. The spectral nonlinearity of mixed pigments was higher near to the wavelength corresponding to their colors. Meanwhile, the nonlinearity increased with the wavelength increases in the shortwave infrared bands.

scholarly journals Hazardous Noxious Substance Detection Based on Ground Experiment and Hyperspectral Remote Sensing

2021 ◽  
Vol 13 (2) ◽  
pp. 318
Author(s):  
Jae-Jin Park ◽  
Kyung-Ae Park ◽  
Pierre-Yves Foucher ◽  
Philippe Deliot ◽  
Stephane Le Floch ◽  
...  
Keyword(s):  
Near Infrared ◽  
Spectral Characteristics ◽  
Chemical Properties ◽  
Principal Component ◽  
Component Analysis ◽  
Noise Removal ◽  
Vertex Component Analysis ◽  
Shortwave Infrared ◽  
Spectral Mixture ◽  
Physical And Chemical

With an increase in the overseas maritime transport of hazardous and noxious substances (HNSs), HNS-related spill accidents are on the rise. Thus, there is a need to completely understand the physical and chemical properties of HNSs. This can be achieved through establishing a library of spectral characteristics with respect to wavelengths from visible and near-infrared (VNIR) bands to shortwave infrared (SWIR) wavelengths. In this study, a ground HNS measurement experiment was conducted for artificially spilled HNS by using two hyperspectral cameras at VNIR and SWIR wavelengths. Representative HNSs such as styrene and toluene were spilled into an outdoor pool and their spectral characteristics were obtained. The relative ratio of HNS to seawater decreased and increased at 550 nm and showed different constant ratios at the SWIR wavelength. Noise removal and dimensional compression procedures were conducted by applying principal component analysis on HNS hyperspectral images. Pure HNS and seawater endmember spectra were extracted using four spectral mixture techniques—N-FINDR, pixel purity index (PPI), independent component analysis (ICA), and vertex component analysis (VCA). The accuracy of detection values of styrene and toluene through the comparison of the abundance fraction were 99.42% and 99.56%, respectively. The results of this study are useful for spectrum-based HNS detection in marine HNS accidents.

scholarly journals Deriving seasonal dynamics in ecosystem properties of semi-arid savanna grasslands from in situ-based hyperspectral reflectance

2015 ◽  
Vol 12 (15) ◽  
pp. 4621-4635 ◽  
Author(s):  
T. Tagesson ◽  
R. Fensholt ◽  
S. Huber ◽  
S. Horion ◽  
I. Guiro ◽  
...  
Keyword(s):  
Seasonal Dynamics ◽  
Near Infrared ◽  
Spectral Characteristics ◽  
Arid Ecosystems ◽  
Hyperspectral Reflectance ◽  
Data Set ◽  
Ecosystem Properties ◽  
Shortwave Infrared ◽  
Semi Arid

Abstract. This paper investigates how hyperspectral reflectance (between 350 and 1800 nm) can be used to infer ecosystem properties for a semi-arid savanna grassland in West Africa using a unique in situ-based multi-angular data set of hemispherical conical reflectance factor (HCRF) measurements. Relationships between seasonal dynamics in hyperspectral HCRF and ecosystem properties (biomass, gross primary productivity (GPP), light use efficiency (LUE), and fraction of photosynthetically active radiation absorbed by vegetation (FAPAR)) were analysed. HCRF data (ρ) were used to study the relationship between normalised difference spectral indices (NDSIs) and the measured ecosystem properties. Finally, the effects of variable sun sensor viewing geometry on different NDSI wavelength combinations were analysed. The wavelengths with the strongest correlation to seasonal dynamics in ecosystem properties were shortwave infrared (biomass), the peak absorption band for chlorophyll a and b (at 682 nm) (GPP), the oxygen A band at 761 nm used for estimating chlorophyll fluorescence (GPP and LUE), and blue wavelengths (ρ412) (FAPAR). The NDSI with the strongest correlation to (i) biomass combined red-edge HCRF (ρ705) with green HCRF (ρ587), (ii) GPP combined wavelengths at the peak of green reflection (ρ518, ρ556), (iii) LUE combined red (ρ688) with blue HCRF (ρ436), and (iv) FAPAR combined blue (ρ399) and near-infrared (ρ1295) wavelengths. NDSIs combining near infrared and shortwave infrared were strongly affected by solar zenith angles and sensor viewing geometry, as were many combinations of visible wavelengths. This study provides analyses based upon novel multi-angular hyperspectral data for validation of Earth-observation-based properties of semi-arid ecosystems, as well as insights for designing spectral characteristics of future sensors for ecosystem monitoring.

scholarly journals Study on the Effect of Surface Roughness on the Spectral Unmixing of Mixed Pixels

2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Haonan Zhang ◽  
Xingping Wen ◽  
Junlong Xu ◽  
Dayou Luo ◽  
Ping He
Keyword(s):  
Surface Roughness ◽  
Spectral Decomposition ◽  
Spectral Characteristics ◽  
Mixing Model ◽  
Spectral Unmixing ◽  
Mirror Reflection ◽  
Reflectance Measurement ◽  
Mixed Pixel ◽  
Mixed Pixels ◽  
Spectral Mixing

In the spectrum measurement experiment, the roughness of the object surface is an essential factor that cannot be ignored. In this experiment, a group of mixed pixel samples with different mixing ratios were designed, and these samples were printed on four kinds of papers with different roughness. The spectral characteristics of mixed pixels with different roughness are quantitatively analyzed by using the measured spectral data. The linear spectral mixture model is used for spectral decomposition, and the effect of roughness on the unmixing precision of mixed pixels was studied. The surface roughness will affect the reflectivity of the mixed pixel. Specifically, the higher the roughness is, the higher the reflectivity of the sample is. This phenomenon is more noticeable when the proportion of white endmember (PWE) is large, and as the white area ratio decreases, the reflectance difference gradually decreases. When the surface roughness of the sample is less than 3.339 μm, the spectral decomposition is performed using a linear spectral mixing model in the visible light band. The average error of the unmixing is less than 0.53%, which is lower than the conventional standard spectral measurement error. In other words, when the surface roughness of the sample is controlled within a specific range, the effect of roughness on the unmixing accuracy of the mixed pixels is small, and this effect can be almost ignored. Multiple scattering within the pixels is the key to model selection and unmixing accuracy, when using the ASD FieldSpec3 spectrometer to perform spectral reflectance measurement and linear spectral unmixing experiments. If the surface roughness of the sample to be measured is less than the maximum wavelength of the spectrometer, the experimental results believe that the photon energy is mainly mirror reflection on the surface of the object and diffuse reflection. At this time, it is still a better choice to use a linear spectral mixing model to decompose the mixed pixels.

scholarly journals Evaluation of Two Applications of Spectral Mixing Models to Image Fusion

2000 ◽  
Vol 71 (3) ◽  
pp. 272-281 ◽  
Author(s):  
Gary D. Robinson ◽  
Harry N. Gross ◽  
John R. Schott
Keyword(s):  
Image Fusion ◽  
Mixing Models ◽  
Spectral Mixing

scholarly journals Spectral Characteristics of the Antarctic Vegetation: A Case Study of Barton Peninsula

2021 ◽  
Vol 13 (13) ◽  
pp. 2470
Author(s):  
Junhwa Chi ◽  
Hyoungseok Lee ◽  
Soon Gyu Hong ◽  
Hyun-Cheol Kim
Keyword(s):  
Remote Sensing ◽  
Spectral Characteristics ◽  
Remote Sensing Data ◽  
Ground Truth ◽  
Spectral Unmixing ◽  
Polar Regions ◽  
Spectral Library ◽  
Sensing Data ◽  
Barton Peninsula ◽  
Shortwave Infrared

Spectral information is a proxy for understanding the characteristics of ground targets without a potentially disruptive contact. A spectral library is a collection of this information and serves as reference data in remote sensing analyses. Although widely used, data of this type for most ground objects in polar regions are notably absent. Remote sensing data are widely used in polar research because they can provide helpful information for difficult-to-access or extensive areas. However, a lack of ground truth hinders remote sensing efforts. Accordingly, a spectral library was developed for 16 common vegetation species and decayed moss in the ice-free areas of Antarctica using a field spectrometer. In particular, the relative importance of shortwave infrared wavelengths in identifying Antarctic vegetation using spectral similarity comparisons was demonstrated. Due to the lack of available remote sensing images of the study area, simulated images were generated using the developed spectral library. Then, these images were used to evaluate the potential performance of the classification and spectral unmixing according to spectral resolution. We believe that the developed library will enhance our understanding of Antarctic vegetation and will assist in the analysis of various remote sensing data.

scholarly journals Spektroskopi Reflektansi Sampel Tanah dan Batuan yang Mengandung Mineral Pembawa Unsur Tanah Jarang dan Radioaktif

EKSPLORIUM ◽  
2019 ◽  
Vol 40 (2) ◽  
pp. 89
Author(s):  
Arie Naftali Hawu Hede ◽  
Muhammad Anugrah Firdaus ◽  
Yogi La Ode Prianata ◽  
Mohamad Nur Heriawan ◽  
Syafrizal Syafrizal ◽  
...  
Keyword(s):  
Remote Sensing ◽  
Rare Earth ◽  
Optical Sensors ◽  
Near Infrared ◽  
Spectral Characteristics ◽  
Infrared Range ◽  
Basic Principles ◽  
Spectral Signatures ◽  
Shortwave Infrared ◽  
Remote Sensing Methods

ABSTRAKSpektroskopi reflektansi merupakan salah satu metode nondestruktif untuk identifikasi mineral dan sebagai dasar dalam analisis pengindraan jauh (indraja) sensor optik. Penelitian ini bertujuan melakukan kajian penerapan spektroskopi reflektansi pada panjang gelombang 350–2.500 nm untuk sampel tanah dan batuan pembawa unsur tanah jarang (rare earth element-REE) dan radioaktif. Sampel diambil dari beberapa lokasi di Bangka Selatan dan Mamuju yang sebelumnya telah diidentifikasi memiliki potensi REE dan unsur radioaktif. Kurva reflektansi hasil analisis sampel dari Bangka Selatan menunjukan adanya kenampakan absorpsi yang menjadi karakteristik untuk kehadiran REE, dalam bentuk mineral monasit, zirkon, dan xenotime khususnya pada sampel yang berasal dari material tailing dan konsentrat bijih timah. Panjang gelombang yang menjadi kunci khususnya berada pada rentang visible-near infrared (VNIR; 400–1.300 nm). Sedangkan untuk sampel yang berasal dari Mamuju, yang merupakan daerah prospeksi mineral radioaktif, karakteristik spektral memperlihatkan beberapa panjang gelombang kunci terutama pada rentang shortwave infrared (1.300–2.500 nm). Hasil interpretasi menunjukkan mineral mayor berupa mineral lempung, sulfat, spesies NH4, dan mineral yang mengandung Al-OH lainnya, sedangkan untuk beberapa sampel pada panjang gelombang VNIR diidentifikasi mengandung mineral besi oksida/hidroksida. Hasil penelitian ini diharapkan dapat berguna untuk pemetaan eksplorasi REE dan radioaktif dengan menggunakan metode indraja.ABSTRACTReflectance spectroscopy is one of the nondestructive methods of mineral identification and is one of the basic principles in the remote sensing analysis using optical sensors. This research aimed at applying reflectance spectroscopy at 350–2,500 nm wavelength range for samples containing rare earth elements (REE) and radioactive minerals. Samples were taken from several locations in South Bangka and Mamuju that had previously been identified as potential location of REE and radioactive-bearing minerals. Reflectance data shows that there are absorption characteristics for REE-bearing minerals; monazite, zircon, and xenotime minerals especially from tailings and tin ore concentrate for the samples from South Bangka. The key wavelengths are specifically in the visible-near infrared range (VNIR; 400–1300 nm). For the samples from Mamuju, which is known as radioactive mineral prospecting areas, spectral characteristics provide information that there are spectral signatures in the shortwave infrared range (1,300–2,500 nm). The results of major mineral interpretations include clay minerals, sulfates, NH4 species, and other minerals containing Al-OH. However, some samples at the VNIR wavelength identified as iron oxide/hydroxide minerals. It is hoped that these results can be useful for REE and radioactive exploration mapping using remote sensing methods.

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