scholarly journals The Solution Interaction of Tetrathionate Ions and Sodium Isobutyl Xanthate and Its Effect on the Flotation of Galena and Chalcopyrite

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 204
Author(s):  
Ngoni Mhonde ◽  
Leena Pitkänen ◽  
Kirsten Corin ◽  
Nóra Schreithofer
Keyword(s):  
Sulphide Mineral ◽  
Mineral Surface ◽  
Sulphide Ore ◽  
Sulphide Ores ◽  
Ore Processing ◽  
Rest Potential ◽  
Processing Plants ◽  
Lead Zinc ◽  
Flotation Performance ◽  
High Concentrations

Tetrathionates have been found in significantly high concentrations in recycled process waters from massive sulphide ore processing plants. These polythionates react with xanthate added to flotation pulps thus reducing xanthate dosages in solution potentially affecting flotation performance. The current study focused on the effect of the tetrathionate-xanthate reaction on sulphide mineral recoveries. Ore dissolution studies confirmed the generation of tetrathionates by copper-lead-zinc ores. In 20 min, the tetrathionates consumed more than half of the xanthate in solution at pH 7. Rest potential measurements and Fourier transform infrared spectroscopy (FTIR) showed that the degree of collector-mineral interactions of xanthate and both galena and chalcopyrite was greatly reduced in the presence of a 2000 mg/L tetrathionate solution. Microflotation tests showed that chalcopyrite recovery was less sensitive to tetrathionates as indicated by small changes in mineral recoveries. Galena was sensitive to the action of tetrathionates on the mineral surface as the galena recovery significantly declined when floated with xanthate as a collector in both a 500 mg/L tetrathionate solution and a 2000 mg/L tetrathionate solution. These fundamental results lay a sound base on which more discussion into the significance and the effect of tetrathionates on flotation performance of sulphide ores can be developed.

Experimental Research on Rough Flotation of Lead in Bainiuchang Lead-Zinc Mines

2014 ◽  
Vol 926-930 ◽  
pp. 108-110
Author(s):  
Qi Fu Zhang ◽  
Zhuo Yue Lan ◽  
Xing Ke Shang
Keyword(s):  
Experimental Research ◽  
Recovery Rate ◽  
Zinc Sulfate ◽  
Zinc Sulphide ◽  
Sodium Hexametaphosphate ◽  
Sulphide Ore ◽  
Lead Recovery ◽  
Lead Zinc ◽  
Flotation Performance ◽  
Plant Practice

Containing Pb (1.09% ) and Zn (1.97%),the lead-zinc sulphide ore of Bainiuchang mine is a refractory resource in Yunnan Mengzi. The flotation performance of lead is ineffective in plant practice. This research is carried out to enhance the rough flotation performance of lead. With the dosage of lime and zinc sulfate as depressors, sodium hexametaphosphate as dispersant, and ethyl thio carbamate and MA as combined collector, the grinding fineness of 85% , a lead concentrate with lead grade of 17.68%, lead recovery rate of 75.59%, and zinc grade of 7.16% was obtained. The performance of rough flotation of lead is improved.

Microorganisms in Bioflotation and Bioflocculation: Potential Application and Research Needs

2009 ◽  
Vol 71-73 ◽  
pp. 319-328 ◽  
Author(s):  
K. Hanumantha Rao ◽  
Annamaria Vilinska ◽  
I.V. Chernyshova
Keyword(s):  
Energy Charge ◽  
Surface Reactivity ◽  
Basic Knowledge ◽  
Primary Data ◽  
Great Promise ◽  
Mineral Surface ◽  
Processing Technologies ◽  
Ore Processing ◽  
Charge Potential ◽  
Mineral Beneficiation

Conventionally, physico-chemical methods are used in mineral processing for recovering value minerals from ores. The ageing of ore processing tailings and waste rocks, and mining tailings contamination by chemical reagents constitute a major threat to the environment. It is imperative to develop novel economically more efficient and environmentally benign methods of flotation and waste processing, exploiting the intriguing and exciting ability of bacteria to selectively modify the surface properties of solids. Microorganisms have not only facilitate hydrometallurgical leaching operations but have also show a great promise in mineral beneficiation processes such as flotation and flocculation. Several laboratory investigations revealed that microorganisms could function similar to traditional reagents. Microorganisms have a tremendous influence on their environment through the transfer of energy, charge, and materials across a complex biotic mineral-solution interface. The bio-modification of mineral surfaces involves the complex action of microorganism on the mineral surface. The manner, in which bacteria affect the surface reactivity and the mechanism of bacteria adsorption, is still unknown and accumulation of the primary data in this area is only starting. The bio-flotation and bio-flocculation processes concern the mineral response to the bacterium presence, which is essentially interplay between microorganism and the physicochemical properties of the mineral surface, such as the atomic and electronic structure, the net charge/potential, acid-base properties, and wettability of the surface. There is an urgent need for developing basic knowledge that would underpin biotechnological innovations in the natural resource (re)processing technologies that deliver competitive solutions.

scholarly journals Assessment of Environmental Geochemistry of Lead-Zinc Mining at Ishiagu Area, Lower Benue Trough, Southeastern Nigeria

2020 ◽  
Vol 9 (1) ◽  
pp. 31 ◽  
Author(s):  
Odika, P.O. ◽  
Anike, O.L. ◽  
Onwuemesi, A.G. ◽  
Odika, N.F. ◽  
Ejeckam, R.B.
Keyword(s):  
Heavy Metals ◽  
Flow Direction ◽  
Environmental Geochemistry ◽  
Zinc Sulphide ◽  
Mining Activities ◽  
Southeastern Nigeria ◽  
Rock Types ◽  
Sulphide Ores ◽  
Lead Zinc ◽  
Concentration Levels

Mining activities have long been recognized as a major source of environmental contamination associated with heavy metals and metalloids. This study evaluated the relationship between the occurrence and mining of lead-zinc sulphide ores at Ishiagu, Nigeria, and heavy metal and metalloid contamination. A comparative study of two zones in the area, with and without mining activities was also made Water, soil, stream sediment and ore samples were analyzed, after acid digestion, using atomic absorption spectrophotometer (AAS).  The concentration levels of seven heavy metals and a metalloid namely Pb, Cu, Ni, Zn, Mn, Co, Cd and as were evaluated. While the highest concentration levels of As, Co and Pb (5.20 mg/l, 0.54 mg/l and 3.40 mg/l respectively) were found in water, those of Ni and Mn (2.26 mg/l and 5.48 mg/l respectively) occurred in soil.  For Cu and Zn, highest levels of concentration (2.80 mg/l and 0.41 mg/l respectively) occurred in stream sediments. The variations in the concentration levels of these elements in varying geologic media (soil, water and sediment) indicate influence of rock types, human activities and media physiochemical characteristics. Geostatistical analyses using QQPlot, semivariogram and kriging showed normal distribution of these elements. Distribution and dispersion patterns of the heavy metals indicated increase in concentration levels in the local stream flow direction. Pb, Cu, As, Cd, Mn, and Ni concentrations had reached pollutant levels in water based on WHO standards, while Zn level is below. Since the local people use untreated surface water and groundwater for drinking and other domestic purposes, soil for farming and lead for cosmetics, long term exposure poses significant health risk for humans, animals and plants.

scholarly journals Designs of new operating copper processing plants: process types, equipment selection, industry trends

2021 ◽  
pp. 44-52
Author(s):  
V. F. Baranov
Keyword(s):  
Large Scale ◽  
High Capacity ◽  
Process Intensification ◽  
Processing Plant ◽  
Advantages And Disadvantages ◽  
Sulphide Ores ◽  
Flotation Cells ◽  
Ore Preparation ◽  
Processing Plants ◽  
Technical Solutions

The article describes the largest operating processing plants for lowgrade copper sulphide ores of our time: 10 plants using the semi-autogenous grinding (SAG) technology and 10 plants using high-pressure grinding rolls (HPGR), with the output of 18 to 100 Mtpa. The unfavorable natural and economic factors are balanced by improved ore preparation and concentration technologies and high-capacity equipment units, combined with cost-saving layout solutions. The ore preparation sector is currently divided between the competing technologies of semi-autogenous grinding and HPGR. The article contains an overview of their advantages and disadvantages. The world’s largest monosection with the capacity of 55.5 Mtpa, that uses the SAG technology, is described. The role of the Drop Weght Test JKSimMet (A×b) parameter in the selection of the ore preparation method and the trend for using HPGR in the processing of strong ores are shown. Examples are provided for the consequences of an inadequate assessment of the feed strength in SAG-based plant designs. Examples of ore preparation process intensification through the use of HPGR in semi-autogenous grinding circuits are also given. The volume of impeller flotation cells installed has reached 600 m3. An overview of the two largest processing plants of our time with the output of 88 and 100 Mtpa of ore is presented. The innovative technical solutions of a newest low-capacity copper plant are highlighted. Based on the results of the overview, a future processing plant is predicted to use ∅12.8–13 m SAG mills, HPGRs with the roll diameter of 3 m, vertical VTM-7000 mills in ore grinding cycles, large fine screens, large-scale impeller flotation cells, and staged SFR and DFR flotation reactors.

Selection of Binding Agents for Dust Prevention at Tailings Ponds at Apatite–Nepheline Ore Processing Plants

2018 ◽  
Vol 54 (2) ◽  
pp. 329-338
Author(s):  
V. A. Masloboev ◽  
A. V. Svetlov ◽  
O. T. Konina ◽  
G. V. Mitrofanova ◽  
A. V. Turtanov ◽  
...  
Keyword(s):  
Ore Processing ◽  
Binding Agents ◽  
Processing Plants ◽  
Tailings Ponds ◽  
Selection Of

Dust suppression in iron ore processing plants

2005 ◽  
Vol 22 (4) ◽  
pp. 177-191 ◽  
Author(s):  
C. R. Copeland ◽  
S. K. Kawatra
Keyword(s):  
Iron Ore ◽  
Dust Suppression ◽  
Iron Ore Processing ◽  
Ore Processing ◽  
Processing Plants

scholarly journals Mineralogical Prediction of Flotation Performance for a Sediment-Hosted Copper–Cobalt Sulphide Ore

Minerals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 474 ◽  
Author(s):  
Laurens T. Tijsseling ◽  
Quentin Dehaine ◽  
Gavyn K. Rollinson ◽  
Hylke J. Glass
Keyword(s):  
Cross Validation ◽  
Democratic Republic Of Congo ◽  
Sulphide Minerals ◽  
Quantitative Correlation ◽  
Sulphide Ore ◽  
Mineralogical Characteristics ◽  
Cobalt Sulphide ◽  
Quantitative Understanding ◽  
Flotation Performance ◽  
Leave One Out

As part of a study investigating the influence of mineralogical variability in a sediment hosted copper–cobalt deposit in the Democratic Republic of Congo on flotation performance, the flotation of nine sulphide ore samples was investigated through laboratory batch kinetics tests and quantitative mineral analyses. Using a range of ore samples from the same deposit the influence of mineralogy on flotation performance was studied. Characterisation of the samples through QEMSCAN showed that bornite, chalcopyrite, chalcocite and carrollite are the main copper-bearing sulphide minerals while carrollite is the only cobalt-bearing mineral. Mineralogical characteristics were averaged per sample to allow for a quantitative correlation with flotation performance parameters. Equilibrium recoveries, rate constants and final grades of the samples were correlated to the feed mineralogy through Multiple Linear Regression (MLR). Target sulphide minerals content and particle size, magnesiochlorite content, carrollite liberation and association of the copper and cobalt minerals with magnesiochlorite and dolomite were used to predict flotation performance. Leave One Out Cross Validation (LOOCV) revealed that the final copper and cobalt grades are predicted with an R2 of 0.80 and 0.93 and Root Mean Square Error of Cross Validation (RMSECV) of 4.41% and 1.34%. The recovery of cobalt and copper with time can be predicted with an R2 of 0.94 for both and an overall test error of 4.70% and 5.14%. Overall, it was shown that quantitative understanding of changes in mineralogy allows for prediction of changes in flotation performance.

Concentrations and speciation of lead, zinc and cadmium in seawater-like smelter effluent and adjacent marine environments, Port Pirie, South Australia

1983 ◽  
Vol 34 (3) ◽  
pp. 375 ◽  
Author(s):  
J Ferguson
Keyword(s):  
South Australia ◽  
Tidal Channel ◽  
Significant Extent ◽  
Dissolved Metals ◽  
Metal Concentrations ◽  
Near Surface ◽  
Unicellular Algae ◽  
Particulate Metal ◽  
Lead Zinc ◽  
High Concentrations

High concentrations of particulate and dissolved lead, zinc and cadmium (total dissolved Pb, 750�g l-1; Zn, 4300�g 1-1; Cd, 64 �g l-1; particulate Pb, 236 �g l-1; Zn, 64 �g l-1; Cd, < 1 �g l-1) occur in seawater- like effluent from a lead-zinc smelting complex at Port Pirie. This effluent is discharged through a silled tidal channel into the offshore marine environment, where dilution by seawater eventually reduces the metal concentrations to values similar to those in near-surface seawater in Spencer Gulf, remote from centres of industrial activity (average total dissolved Pb, 0 4 �g 1-1; Zn, < 10 μg l-1; Cd, 0 3 �g l-1; average particulate Pb, <0.05 �g l-1; Zn, 0 21 �g I-1). Precipitation of dissolved metals or conversion of originally weakly complexed dissolved metals to more strongly complexed species does not occur to a significant extent. Particulate metal concentrations are influenced by resuspension of metal-rich sediments and by uptake of dissolved cadmium by unicellular algae that grow in the tidal channel.

Mineral deposits and chalcogen gases

1993 ◽  
Vol 57 (389) ◽  
pp. 599-606 ◽  
Author(s):  
Martin Hale
Keyword(s):  
Ore Deposits ◽  
Anomalous Dispersion ◽  
Mineral Deposits ◽  
Oxidation Reactions ◽  
Sulphide Minerals ◽  
Sulphide Ore ◽  
Dispersion Patterns ◽  
Sulphide Deposits ◽  
High Concentrations ◽  
And Migration

AbstractSulphide minerals and their analogues yield gases as a result of oxidation reactions. Even where sulphide minerals are in contact with mildly reducing groundwaters, S2- ions pass into solution and their dispersion patterns can be detected in soil as acid-released H2S. In more oxidising conditions, the metastable gases COS and CS2 are generated. Anomalous dispersion patterns of COS have been reported in soils above more than ten sulphide ore deposits, many of them concealed beneath transported exotic overburden. High concentrations of CS2 occur in the soils over several of the same deposits and uniquely reflect others. Anomalies of SO2 over sulphide deposits are confined to arid terrains. Certain anomalous dispersion patterns of arsenic and tellurium in soils are attributed to the generation and migration of unspecified gases from the oxidation of arsenide and telluride minerals.

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