scholarly journals Origin of Qinxi Silver Polymetallic Deposit in Southeast Coast, China: Evidences from H–O–S–Pb Isotopes and Mineral Rb–Sr Geochronology

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 45
Author(s):  
Senfang Zhong ◽  
Wenhao Liu ◽  
Jun Zhang ◽  
Qiuling Gan

The Qinxi silver deposit is located in eastern Fujian Province, South China. It is hosted in the late Jurassic Nanyuan volcanic unit and controlled spatially by structural alteration zone. The origins of the deposit are understood poorly. In this study, systematic field geology, precise sulfide geochronology, and H–O–S–Pb isotope analyses were carried out. The symbiotic minerals and ore assemblages are interpreted as evidence that Qinxi ore is a typical middle to low temperature hydrothermal deposit. Galena and sphalerite from the ore yield a Rb–Sr isochronal age of 130 ± 2.0 Ma (MSWD = 1.7), and single galena samples yield a Rb–Sr isochronal age of 130 ± 7.1 Ma (MSWD = 2) and are evidence that the ore was formed in the early Cretaceous period. The silver-bearing quartz vein has O:H and 18O:16O ratios intermediately between magmatic and meteoric water (δ18 Owater-smow from −2.50‰ to −0.1‰ and δDv-smow from −73.6‰ to −60.7‰). The δ34 S values of metal sulfide are close to the primitive mantle sulfur values (δ34S = −1.7 to 7.1‰, avg. = 0.92‰). The Pb isotopic compositions from the ore are similar to those of the hosted volcanic unit, with a value between the upper crust and mantle isotope composition (206Pb/204Pb = 18.421~18.605, 207Pb/204Pb = 15.580~15.772, 208Pb/204Pb = 38.591~39.183). Lead–zinc sulfides have mature crustal-derived Sr isotopic features ((87Sr/86Sr)i = 0.7103). Thus, the metallogenic source materials mainly came from the crust. Moreover, regional geological studies suggest that the Qinxi ore deposit was likely formed in an extensional terrane.

Lithos ◽  
2015 ◽  
Vol 233 ◽  
pp. 131-138
Author(s):  
Yiefei Jia ◽  
Robert Kerrich

2019 ◽  
Vol 60 (10) ◽  
pp. 1881-1902 ◽  
Author(s):  
Juliana Troch ◽  
Ben S Ellis ◽  
Chris Harris ◽  
Peter Ulmer ◽  
Anne-Sophie Bouvier ◽  
...  

Abstract Quantifying the relative contributions of crustal versus mantle-derived melt is important for understanding how silicic magmas are generated, stored, and interact with country rock in trans-crustal magmatic systems. Low-δ18O rhyolitic ignimbrites and lavas erupted during Miocene volcanic activity in the central Snake River Plain (14–6 Ma) have been inferred to be the result of large-scale partial or bulk melting of pre-existing hydrothermally altered lithologies of the Idaho batholith and Challis volcanic field. In this study, we assess the melting behaviour of heterogeneously altered source materials via partial melting experiments over a range of run times at conditions of 750–1000°C and 1–2 kbar, and apply our observations to current models for the petrogenesis of low-δ18O rhyolites along the Yellowstone hotspot track. Partial melt produced in the experiments inherits the bulk oxygen isotope composition from hydrothermally altered peraluminous source materials independent of the melt fraction, excluding the possibility for preferential, disequilibrium melting of 18O-depleted mineral phases during incipient melting. We propose a new model to explain the generation of low-δ18O rhyolites in the central Snake River Plain, whereby mantle-derived magmas assimilate ∼30–40% of crustal material that was hydrothermally altered at high temperatures in two stages: (1) a preceding episode of hydrothermal alteration during intrusion of Eocene plutons (‘pre-existing source’); (2) syn-magmatic hydrothermal alteration within a nested caldera complex. During assimilation, dilution of peraluminous crustal lithologies with mantle-derived magma maintains the metaluminous character of rhyolites erupted along the Yellowstone hotspot track. These results link previous models favouring melting of either pre-existing or syn-magmatically altered lithologies for the generation of low-δ18O rhyolites along the Yellowstone hotspot track and provide direct experimental observation of the chemical processes occurring during assimilation processes in magmatic environments.


2020 ◽  
Vol 115 (8) ◽  
pp. 1799-1826
Author(s):  
M. Christopher Jenkins ◽  
James E. Mungall ◽  
Michael L. Zientek ◽  
Paul Holick ◽  
Kevin Butak

Abstract In this contribution, we analyze 30 years of mine development data and quantitatively identify the processes that control the grade and tenor of the mineralized rock. An assay database of more than 60,000 samples was used to examine variations in ore grade and tenor of the sulfide mineralization in the J-M reef horizon of the Stillwater Complex along the strike and down the dip of the deposit in the area of the Stillwater mine. We compare these results with data from the East Boulder mine and whole-rock lithogeochemistry of samples collected along the entire strike length of the complex. We find significant variation in the composition of the reef sulfides in different spatial domains of the Stillwater mine area and between the Stillwater and East Boulder mines. Most of the variation in the grade and tenor can be explained by a variation in the mass of silicate magma with which the sulfide liquid equilibrated (i.e., R factor); however, geochemical and textural evidence suggests that parts of the reef may have experienced significant S loss following initial sulfide melt segregation. Some variability in the reef tenor and grade can be attributed to variable amounts of sulfur loss due to low-temperature hydrothermal fluids and the overestimation or underestimation of metal concentrations in reef assays due to the nugget effect. Furthermore, we address the Pd/Pt ratio of the reef samples and suggest that the lower solubility of Pt in the parental silicate melt may have caused the crystallization and removal of Pt alloys at some point before the melt reached sulfide saturation and Pt could partition into the sulfide liquid. This disparity between the prior evolution of Pt and Pd in the silicate melt resulted in the observed Pd/Pt ratio of ~3.65 across all areas of the reef—a value significantly larger than anticipated for primitive mantle-derived magmas.


2001 ◽  
Vol 172 (6) ◽  
pp. 675-686 ◽  
Author(s):  
Ismaila Ngounouno ◽  
Christian Moreau ◽  
Bernard Deruelle ◽  
Daniel Demaiffe ◽  
Raymond Montigny

Abstract The Cameroon Line was created by the rejuvenation, at the beginning of the opening of the Atlantic Ocean, of a Pan-African N070 degrees E fracture zone [Moreau et al., 1987], which acted as a huge lithospheric crack taping a hot asthenospheric zone [Deruelle et al., 1998; Marzoli et al., 2000]. The Kokoumi anorogenic pluton belongs to the E-W Garoua rift structure, which represents the easternmost extension of the Benue trough. The Garoua rift opened during the Neocomian-Lower Aptian ages [Benkhelil, 1988] through the rejuvenation of Pan-African normal faults. The rift subsided, was partially filled by conglomerates and sandstones, and the ensemble was folded in the Cretaceous period [Guiraud, 1993]. Post-Cretaceous faulting affected these sediments. Intrusion of the Kokoumi anorogenic complex through the Cretaceous sandstones was favoured by N-S, N070 degrees E, E-W and N135 degrees E faults and N030 degrees E extension [Moreau et al., 1987]. The Kokoumi complex was first described by Koch [1959]. It is composed of a plutonic gabbro-nepheline monzosyenite-nepheline syenite series and of lamprophyric dykes (monchiquites and camptonites). One trachyte dyke is also observed. The gabbros are olivine (Fo 70 )-, nepheline-, or kaersutite-bearing gabbros. They also contain Ti-Al-rich diopside, Ti-rich biotite, titanite, ilmenite, Ti-magnetite and apatite. The nepheline monzosyenites contain diopside, Fe-diopside, kaersutite, Fe-kaersutite, titanite and apatite. The nepheline syenites contain aegirine-augite, F-rich arfvedsonite and aenigmatite. Kaersutite and clinopyroxene predominate in the lamprophyres. Monchiquites and gabbros, camptonites and monzosyenites, display respective similar mineralogy. Monchiquites contain carbonate ocelli. The trachyte does not contain ferromagnesian minerals. For gabbros and monchiquites, equilibrium Fe-Ti oxide temperatures are between 650 and 750 degrees C (+ or -40 degrees C) and oxygen fugacities between 10 (super -15) and 10 (super -14) (+ or -0.5 X 10 (super -15) ) atmospheres, according to Spencer and Lindsley [1981]. Nepheline crystallized below 700 degrees C, according to Hamilton [1961]. All the rocks (except the trachyte) are nepheline normative (Ne 6 to Ne 40 ). Major and trace element distributions in MgO-element diagrams for the two series merge together into a single trend, from monchiquites to nepheline syenites. Nevertheless, the monchiquites trends have different slopes. We deduce the evolution from gabbros to nepheline syenites on the one hand and from monchiquites to camptonites on the other from primitive mantle normalized multi-element diagrams. Multi-element diagrams for the trachyte and the nepheline syenite are strictly similar. Patterns for Kokoumi gabbros are similar to those for basalts of the Kapsiki plateau [Ngounouno et al., 2000] and the Garoua rift [Ngounouno et al., 1997] with typical negative K and positive Zr and Ti anomalies. Patterns for nepheline monzosyenites display negative anomalies in Sr, P, Eu and Ti and those for nepheline syenites and trachyte display greater anomalies in these elements and Ba. Compared to gabbros, nepheline monzosyenites are enriched in all REE with a concave upward pattern and no Eu-anomaly. Nepheline syenites have a range of broadly similar REE patterns to nepheline monzosyenites with steep slope from La to Sm, strong Eu negative anomaly (Eu/Eu (super *) nearly equal 0.15) and heavy-REE spoon-shape. REE patterns for monchiquites, camptonites, and trachyte are respectively similar to those for gabbros, monzosyenites, and nepheline syenite. Initial Sr-isotope ratios of 0.7033 (recalculated from the measured ratios for an age of 39 Ma for plutonic rocks and 20 Ma for the lamprophyres and the trachyte) are similar to those obtained for basalts from the continental segment of the Cameroon Line [Halliday et al., 1988; Ngounouno et al., 2000; Demaiffe et al., unpubl.], whereas nepheline syenites and trachyte are distinctly more radiogenic with values between 0.7128 and 0.7251. Amphibole and whole-rock K-Ar analyses (table III) yield 39.0+ or -0.9 Ma and 36.6+ or -0.9 Ma respectively. Since amphibole is a reliable chronometer in K-Ar dating, we propose the first age as the probable time of emplacement of the gabbros. Whole-rock analysis of nepheline syenite 99 displays an age of 33.1+ or -0.5 Ma. Field and geochemical observations suggest that gabbros and nepheline syenite are cogenetic and hence contemporaneous.


2010 ◽  
Vol 82 (8) ◽  
pp. 1719-1733 ◽  
Author(s):  
Willi A. Brand ◽  
Sergey S. Assonov ◽  
Tyler B. Coplen

Measurements of δ(13C) determined on CO2 with an isotope-ratio mass spectrometer (IRMS) must be corrected for the amount of 17O in the CO2. For data consistency, this must be done using identical methods by different laboratories. This report aims at unifying data treatment for CO2 IRMS by proposing (i) a unified set of numerical values, and (ii) a unified correction algorithm, based on a simple, linear approximation formula. Because the oxygen of natural CO2 is derived mostly from the global water pool, it is recommended that a value of 0.528 be employed for the factor λ, which relates differences in 17O and 18O abundances. With the currently accepted N(13C)/N(12C) of 0.011 180(28) in VPDB (Vienna Peedee belemnite) reevaluation of data yields a value of 0.000 393(1) for the oxygen isotope ratio N(17O)/N(16O) of the evolved CO2. The ratio of these quantities, a ratio of isotope ratios, is essential for the 17O abundance correction: [N(17O)/N(16O)]/[N(13C)/N(12C)] = 0.035 16(8). The equation [δ(13C) ≍ 45δVPDB-CO2 + 2 17R/13R (45δVPDB-CO2 – λ46δVPDB-CO2)] closely approximates δ(13C) values with less than 0.010 ‰ deviation for normal oxygen-bearing materials and no more than 0.026 ‰ in extreme cases. Other materials containing oxygen of non-mass-dependent isotope composition require a more specific data treatment. A similar linear approximation is also suggested for δ(18O). The linear approximations are easy to implement in a data spreadsheet, and also help in generating a simplified uncertainty budget.


Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 370
Author(s):  
Hans G. M. Eggenkamp ◽  
Michael A. W. Marks ◽  
Pascale Louvat ◽  
Gregor Markl

We determined the bromine isotope compositions of magmatic and hydrothermal sodalite (Na8Al6Si6O24Cl2) and tugtupite (Na8Al2Be2Si8O24Cl2) from the Ilímaussaq intrusion in South Greenland, in order to constrain the Br isotope composition of the melt and hydrothermal fluids from which these minerals were formed. Early formed magmatic sodalite has high Br contents (138 ± 10 µg/g, n = 5) and low δ81Br values (+0.23 ± 0.07‰). Late stage hydrothermal sodalite has lower Br contents (53±10 µg/g, n = 5) and higher δ81Br values (+0.36 ± 0.08‰). Tugtupite that forms at even later stages shows the lowest Br contents (26 ± 2 µg/g, n = 2) and the highest δ81Br values (+0.71 ± 0.17‰). One hydrothermal sodalite has a Br concentration of 48 ± 9 µg/g and an exceptionally high δ81Br of 0.82 ± 0.12‰, very similar to the δ81Br of tugtupites. We suggest that this may be a very late stage sodalite that possibly formed under Be deficient conditions. The data set suggests that sodalite crystallises with a negative Br isotope fractionation factor, which means that the sodalite has a more negative δ81Br than the melt, of −0.3 to −0.4‰ from the melt. This leads to a value of +0.5 to +0.6‰ relative to SMOB for the melt from which sodalite crystallises. This value is similar to a recently published δ81Br value of +0.7‰ for very deep geothermal fluids with very high R/Ra He isotope ratios, presumably derived from the mantle. During crystallisation of later stage hydrothermal sodalite and the Be mineral tugtupite, δ81Br of the residual fluids (both melt and hydrothermal fluid) increases as light 79Br crystallises in the sodalite and tugtupite. This results in increasing δ81Br values of later stage minerals that crystallise with comparable fractionation factors from a fluid with increasingly higher δ81Br values.


2020 ◽  
Vol 118 (1) ◽  
pp. e2015211118
Author(s):  
Andrea Giuliani ◽  
Matthew G. Jackson ◽  
Angus Fitzpayne ◽  
Hayden Dalton

The noble gas isotope systematics of ocean island basalts suggest the existence of primordial mantle signatures in the deep mantle. Yet, the isotopic compositions of lithophile elements (Sr, Nd, Hf) in these lavas require derivation from a mantle source that is geochemically depleted by melt extraction rather than primitive. Here, this apparent contradiction is resolved by employing a compilation of the Sr, Nd, and Hf isotope composition of kimberlites—volcanic rocks that originate at great depth beneath continents. This compilation includes kimberlites as old as 2.06 billion years and shows that kimberlites do not derive from a primitive mantle source but sample the same geochemically depleted component (where geochemical depletion refers to ancient melt extraction) common to most oceanic island basalts, previously called PREMA (prevalent mantle) or FOZO (focal zone). Extrapolation of the Nd and Hf isotopic compositions of the kimberlite source to the age of Earth formation yields a143Nd/144Nd-176Hf/177Hf composition within error of chondrite meteorites, which include the likely parent bodies of Earth. This supports a hypothesis where the source of kimberlites and ocean island basalts contains a long-lived component that formed by melt extraction from a domain with chondritic143Nd/144Nd and176Hf/177Hf shortly after Earth accretion. The geographic distribution of kimberlites containing the PREMA component suggests that these remnants of early Earth differentiation are located in large seismically anomalous regions corresponding to thermochemical piles above the core–mantle boundary. PREMA could have been stored in these structures for most of Earth’s history, partially shielded from convective homogenization.


Geology ◽  
2020 ◽  
Vol 48 (10) ◽  
pp. 1028-1032
Author(s):  
Luc S. Doucet ◽  
Oscar Laurent ◽  
Dmitri A. Ionov ◽  
Nadine Mattielli ◽  
Vinciane Debaille ◽  
...  

Abstract The Archean continental lithosphere consists of a dominantly felsic continental crust, made of tonalite-trondhjemite-granodiorite (TTG) and subordinate granitoids, and a cratonic lithospheric mantle, made of highly refractory peridotites. Whether they stemmed from the same process of differentiation from the primitive mantle, or were two distinct components that were physically juxtaposed, remains debated. Metal stable isotope ratios are sensitive to magmatic and metamorphic processes and do not evolve with time. Therefore, stable isotope ratios are complementary to radiogenic isotope ratios, and they allow direct comparisons to be made between different terrestrial components without age corrections. Isotopes of iron and zinc, metals ubiquitous in Earth’s lithosphere, can be tracers of lithospheric formation and evolution because they are affected by partial melting (Fe, Zn), redox state (Fe), and the presence of sulfides (Fe, Zn). Here, using stable Fe and Zn isotopic data from Archean samples of the lithospheric mantle and the continental crust, we show that Fe and Zn isotopes define a linear array, best explained by their coupled fractionation behavior during magmatic processes. Our data show that high degrees of partial melting (>30%) during the formation of the cratonic mantle and mafic protocrust, and reworking of the early crust significantly fractionate Fe and Zn isotopes. Conversely, Fe and Zn isotope ratios in the TTG are similar to those in Archean mafic rocks, suggesting an origin by fractional crystallization of basalt, and implying limited Fe and Zn isotopic fractionation, instead of partial melting of mafic crust. Moreover, the absence of Fe and Zn isotope decoupling due to redox effects, melt (fluid)–rock or sediment-rock interaction, and decarbonation indicates that subduction, at least as we understand it now, is not required to explain the Fe and Zn isotope composition of the Archean lithosphere.


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