scholarly journals Geochemical and Geochronological Constraints on the Genesis of Ion-Adsorption-Type REE Mineralization in the Lincang Pluton, SW China

Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1116
Author(s):  
Lei Lu ◽  
Yan Liu ◽  
Huichuan Liu ◽  
Zhi Zhao ◽  
Chenghui Wang ◽  
...  
Keyword(s):  
Host Rock ◽  
Chemical Weathering ◽  
Modern Society ◽  
Late Triassic ◽  
Granitic Magma ◽  
Ion Adsorption ◽  
Lree Enrichment ◽  
Heavy Rare Earth Elements ◽  
Geochronological Constraints ◽  
Ree Patterns

Granites are assumed to be the main source of heavy rare-earth elements (HREEs), which have important applications in modern society. However, the geochemical and petrographic characteristics of such granites need to be further constrained, especially as most granitic HREE deposits have undergone heavy weathering. The LC batholith comprises both fresh granite and ion-adsorption-type HREE deposits, and contains four main iRee (ion-adsorption-type REE) deposits: the Quannei (QN), Shangyun (SY), Mengwang (MW), and Menghai (MH) deposits, which provide an opportunity to elucidate these characteristics The four deposits exhibit light REE (LREE) enrichment, and the QN deposit is also enriched in HREEs. The QN and MH deposits were chosen for study of their petrology, mineralogy, geochemistry, and geochronology to improve our understanding of the formation of iRee deposits. The host rock of the QN and MH deposits is granite that includes REE accessory minerals, with monazite, xenotime, and allanite occurring as euhedral inclusions in feldspar and biotite, and thorite, fluorite(–Y), and REE fluorcarbonate occurring as anhedral filling in cavities in quartz and feldspar. Zircon U–Pb dating analysis of the QN (217.8 ± 1.7 Ma, MSWD = 1.06; and 220.3 ± 1.2 Ma, MSWD = 0.71) and MH (232.2 ± 1.7 Ma, MSWD = 0.58) granites indicates they formed in Late Triassic, with this being the upper limit of the REE-mineral formation age. The host rock of the QN and MH iRee deposits is similar to most LC granites, with high A/CNK ratios (>1.1) and strongly peraluminous characteristics similar to S-type granites. The LC granites (including the QN and MH granites) have strongly fractionated REE patterns (LREE/HREE = 1.89–11.97), negative Eu anomalies (Eu/Eu* = 0.06–0.25), and are depleted in Nb, Zr, Hf, P, Ba, and Sr. They have high 87Sr/86Sr ratios (0.710194–0.751763) and low 143Nd/144Nd ratios (0.511709–0.511975), with initial Sr and Nd isotopic compositions of (87Sr/86Sr)i = 0.72057–0.72129 and εNd(220 Ma) = −9.57 to −9.75. Their initial Pb isotopic ratios are: 206Pb/204Pb = 18.988–19.711; 208Pb/204Pb = 39.713–40.216; and 207Pb/204Pb = 15.799–15.863. The Sr–Nd–Pb isotopic data and TDM2 ages suggest that the LC granitic magma had a predominantly crustal source. The REE minerals are important features of these deposits, with feldspars and micas altering to clay minerals containing Ree3+ (exchangeable REE), whose concentration is influenced by the intensity of weathering; the stronger the chemical weathering, the more REE minerals are dissolved. Secondary mineralization is also a decisive factor for Ree3+ enrichment. Stable geology within a narrow altitudinal range of 300–600 m enhances Ree3+ retention.

The petrological and geochemical study of granitoid rocks from Mashhad area, Iran: Evidence for the Late Triassic Collisional Belt Northeast of Iran

2021 ◽  
Author(s):  
Banafsheh Vahdati ◽  
Seyed Ahmad Mazaheri
Keyword(s):  
Subduction Zones ◽  
Tectonic Setting ◽  
Crustal Contamination ◽  
Oceanic Lithosphere ◽  
Late Triassic ◽  
Common Belief ◽  
Thrust Tectonics ◽  
Wide Range ◽  
Lree Enrichment ◽  
Granitoid Rocks

<p>Mashhad granitoid complex is part of the northern slope of the Binalood Structural Zone (BSZ), Northeast of Iran, which is composed of granitoids and metamorphic rocks. This research presents new petrological and geochemical whole-rock major and trace elements analyses in order to determine the origin of granitoid rocks from Mashhad area. Field and petrographic observations indicate that these granitoid rocks have a wide range of lithological compositions and they are categorized into intermediate to felsic intrusive rocks (SiO<sub>2</sub>: 57.62-74.39 Wt.%). Qartzdiorite, tonalite, granodiorite and monzogranite are common granitoids with intrusive pegmatite and aplitic dikes and veins intruding them. Based on geochemical analyses, the granitoid rocks are calc-alkaline in nature and they are mostly peraluminous. On geochemical variation diagrams (major and minor oxides versus silica) Na<sub>2</sub>O and K<sub>2</sub>O show a positive correlation with silica while Al<sub>2</sub>O<sub>3</sub>, TiO<sub>2</sub>, CaO, Fe<sub>2</sub>O<sub>3</sub>, and MgO show a negative trend. Therefore fractional crystallization played a considerable role in the evolution of Mashhad granitoids. Based on the spider diagrams, there are enrichments in LILE and depletion in HFSE. Low degrees of melting or crustal contamination may be responsible for LILE enrichment. Elements such as Pb, Sm, Dy and Rb are enriched, while Ba, Sr, Nd, Zr, P, Ti and Yb (in monzogranites) are all depleted. LREE enrichment and HREE depletion are observed in all samples on the Chondrite-normalized REE diagram. Similar trends may be evidence for the granitoids to have the same origin. Besides, LREE enrichment relative to HREE in some samples can indicate the presence of garnet in their source rock. Negative anomalies of Eu and Yb are observed in monzogranites. Our results show that Mashhad granitoid rocks are orogenic related and tectonic discrimination diagrams mostly indicate its syn-to-post collisional tectonic setting. No negative Nb anomaly compared with MORB seems to be an indication of non-subduction zone related magma formation. According to the theory of thrust tectonics of the Binalood region, the oceanic lithosphere of the Palo-Tethys has subducted under the Turan microplate. Since the Mashhad granitoid outcrops are settled on the Iranian plate, this is far from common belief that these granitoid rocks are related to the subduction zones and the continental arcs. The western Mashhad granitoids show more mafic characteristics and are possibly crystallized from a magma with sedimentary and igneous origin. Thus, Western granitoid outcrops in Mashhad are probably hybrid type and other granitoid rocks, S and SE Mashhad are S-type. Evidences suggest that these continental collision granitoid rocks are associated with the late stages of the collision between the Iranian and the Turan microplates during the Paleo-Tethys Ocean closure which occurred in the Late Triassic.</p>

The Coles Hill Uranium Deposit, Virginia, USA: Geology, Geochemistry, Geochronology, and Genetic Model

2022 ◽  
Vol 117 (2) ◽  
pp. 273-304
Author(s):  
S. M. Hall ◽  
J. S. Beard ◽  
C. J. Potter ◽  
R. J. Bodnar ◽  
L. A. Neymark ◽  
...  
Keyword(s):  
Shear Zone ◽  
Titanium Oxide ◽  
River Basin ◽  
Host Rock ◽  
Uranium Deposit ◽  
Uranium Mineralization ◽  
Late Triassic ◽  
Pb Isotope ◽  
Igneous Complex ◽  
Mineralizing Fluids

Abstract The Coles Hill uranium deposit, with an indicated resource of about 130 Mlb of U3O8, is the largest unmined uranium deposit in the United States. The deposit is hosted in the Taconian (approx. 480–450 Ma) Martinsville igneous complex, which consists of the Ordovician Leatherwood Granite (granodiorite) and the Silurian Rich Acres Formation (diorite). The host rock was metamorphosed to orthogneiss during the Alleghanian orogeny (approx. 325–260 Ma), when it also underwent dextral strike-slip movement along the Brookneal shear zone. During the Triassic, extensional tectonics led to the development of the Dan River Basin that lies east of Coles Hill. The mineralized zone is hosted in brittle structures in the footwall of the Triassic Chatham fault that forms the western edge of the basin. Within brittle fracture zones, uranium silicate and uranium-bearing fluorapatite with traces of brannerite form veins and breccia-fill with chlorite, quartz, titanium oxide, pyrite, and calcite. Uranium silicates also coat and replace primary titanite, zircon, ilmenite, and sulfides. Sodium metasomatism preceded and accompanied uranium mineralization, pervasively altering host rock and forming albite from primary feldspar, depositing limpid albite rims on igneous feldspar, altering titanite to titanium oxide and calcite, and forming riebeckite. Various geothermometers indicate temperatures of less than ~200°C during mineralization. In situ U-Pb analyses of titanite, Ti-oxide, and apatite, along with Rb/Sr and U/Pb isotope systematics of whole-rock samples, resolve the timing of geologic processes affecting Coles Hill. The host Leatherwood Granite containing primary euhedral titanite is dated at 450 to 445 Ma, in agreement with previously obtained ages from zircon in the Martinsville igneous complex. A regional metamorphic event at 330 to 310 Ma formed anhedral titanite and some apatite, reequilibrated whole-rock Rb/Sr and U-Pb isotopes, and is interpreted to have coincided with movement along the Brookneal shear zone. During shearing and metamorphism, primary refractory uranium-bearing minerals including titanite, zircon, and uranothorite were recrystallized, and uranium was liberated and mixed locally with hematite, clay, and other fine-grained minerals. Uranium mineralization was accompanied by a metasomatic episode between 250 and 200 Ma that reset the Rb-Sr and U-Pb isotope systems and formed titanium oxide and apatite that are associated and, in places, intimately intergrown with uranium silicate dating mineralization. This event coincides with rifting that formed the Dan River Basin and was a precursor to the breakup of Pangea. The orientation of late-stage tectonic stylolites is compatible with their formation during Late Triassic to Early Jurassic basin inversion, postdating the main stage of uranium mineralization and effectively dating mineralization as Mesozoic. Based on the close spatial and temporal association of uranium with apatite, we propose that uranium was carried as a uranyl-phosphate complex. Uranium was locally reduced by coupled redox reactions with ferrous iron and sulfide minerals in the host rock, forming uranium silicates. The release of calcium during sodium metasomatic alteration of primary calcic feldspar and titanite in the host rock initiated successive reactions in which uranium and phosphate in mineralizing fluids combined with calcium to form U-enriched fluorapatite. Based on the deposit mineralogy, oxygen isotope geochemistry, and trace element characteristics of uranium silicate and gangue minerals, the primary mineralizing fluids likely included connate and/or meteoric water sourced from the adjacent Dan River Basin. High heat flow related to Mesozoic rifting may have driven these (P-Na-F-rich) fluids through local aquifers and into basin margin faults, transporting uranium from the basin or mobilizing uranium from previously formed U minerals in the Brookneal shear zone, or from U-enriched older basement rock.

scholarly journals Geological, Geochronological, and Geochemical Insights into the Formation of the Giant Pulang Porphyry Cu (–Mo–Au) Deposit in Northwestern Yunnan Province, SW China

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 191 ◽  
Author(s):  
Qun Yang ◽  
Yun-Sheng Ren ◽  
Sheng-Bo Chen ◽  
Guo-Liang Zhang ◽  
Qing-Hong Zeng ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Yunnan Province ◽  
Oceanic Lithosphere ◽  
Late Triassic ◽  
Porphyry Cu ◽  
Icp Ms ◽  
Heavy Rare Earth Elements ◽  
Granodiorite Porphyry ◽  
Northwestern Yunnan

The giant Pulang porphyry Cu (–Mo–Au) deposit in Northwestern Yunnan Province, China, is located in the southern part of the Triassic Yidun Arc. The Cu orebodies are mainly hosted in quartz monzonite porphyry (QMP) intruding quartz diorite porphyry (QDP) and cut by granodiorite porphyry (GP). New LA-ICP-MS zircon U–Pb ages indicate that QDP (227 ± 2 Ma), QMP (218 ± 1 Ma, 219 ± 1 Ma), and GP (209 ± 1 Ma) are significantly different in age; however, the molybdenite Re–Os isochron age (218 ± 2 Ma) indicates a close temporal and genetic relationship between Cu mineralization and QMP. Pulang porphyry intrusions are enriched in light rare-earth elements (LREEs) and large ion lithophile elements (LILEs), and depleted in heavy rare-earth elements (HREEs) and high field-strength elements (HFSEs), with moderately negative Eu anomalies. They are high in SiO2, Al2O3, Sr, Na2O/K2O, Mg#, and Sr/Y, but low in Y, and Yb, suggesting a geochemical affinity to high-silica (HSA) adakitic rocks. These features are used to infer that the Pulang HSA porphyry intrusions were derived from the partial melting of a basaltic oceanic-slab. These magmas reacted with peridotite during their ascent through the mantle wedge. This is interpreted to indicate that the Pulang Cu deposit and associated magmatism can be linked to the synchronous westward subduction of the Ganzi–Litang oceanic lithosphere, which has been established as Late Triassic.

Metamorphic sole rocks and their mafic dykes in the eastern Tauride belt ophiolites (southern Turkey): implications for OIB-type magma generation following slab break-off

2007 ◽  
Vol 144 (5) ◽  
pp. 849-866 ◽  
Author(s):  
ÖMER FARUK ÇELİK
Keyword(s):  
Hydrothermal Alteration ◽  
Mineral Assemblage ◽  
Carbonate Platform ◽  
Chemical Compositions ◽  
Metamorphic Temperature ◽  
Southern Turkey ◽  
Lree Enrichment ◽  
Structural Levels ◽  
Ree Patterns ◽  
Subduction Component

The metamorphic sole rocks observed between the Pozantı–Karsantı ophiolite and the melange unit are located on the eastern part of the Tauride carbonate platform. They consist of ortho-amphibolites at the top and metasedimentary lithologies at the base. Amphibolites from the metamorphic sole rocks are represented by OIB, MORB and IAT based on their major, trace and REE compositions. The isolated dolerite dykes intrude both the metamorphic sole rocks and the ophiolitic unit at different structural levels. The dolerite dykes cutting the metamorphic sole rocks are enriched in LILE and depleted in HFSE. Enrichment in LILE such as Th, relative to HFSE, is indicative of the presence of a subduction component. Flat-lying REE patterns of the dolerite dykes also confirm an IAT source. Pyroxenite and albitite dykes also cut the metamorphic sole rocks. REE patterns of pyroxenite dykes show prominent LREE enrichment, similar to that observed in within-plate alkaline basalts. The alkaline isolated pyroxenite dykes were probably the result of late-stage magmatism fed by melts that originated from an OIB source, shortly before the emplacement of the Pozantı–Karsantı ophiolite onto the Tauride carbonate platform. A hydrothermal alteration stage is characterized by albitite formation in the joints of the metamorphic sole rocks and by secondary mineralization along the contact zones of dolerite dykes. Mineral parageneses in the metamorphic sole rocks exhibit amphibolite and greenschist-facies assemblages. Geothermobarometric studies based on a newly recognized mineral assemblage (e.g. kyanite) and chemical compositions of minerals in the metamorphic sole rocks indicate that the metamorphic temperature during the metamorphism was 570–580°C and the pressure was around 5–6 kbar.

scholarly journals Metallogenic Epoch and Tectonic Setting of Saima Niobium Deposit in Fengcheng, Liaoning Province, NE China

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 80 ◽  
Author(s):  
Nan Ju ◽  
Yun-Sheng Ren ◽  
Sen Zhang ◽  
Zhong-Wei Bi ◽  
Lei Shi ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Nepheline Syenite ◽  
Large Scale ◽  
Tectonic Setting ◽  
Liaoning Province ◽  
Late Triassic ◽  
Ne China ◽  
The North ◽  
Heavy Rare Earth Elements

The Saima deposit is a newly discovered niobium deposit which is located in the eastern of Liaoning Province, NE China. Its mineralization age and geochemical characteristics are firstly reported in this study. The Nb orebodies are hosted by the grey–brown to grass-green aegirine nepheline syenite. Detailed petrographical studies show that the syenite consists of orthoclase (~50%), nepheline (~30%), biotite (~15%) and minor arfvedsonite (~3%) and aegirine (~2%), with weak hydrothermal alteration dominated by silicification. In situ LA-ICP-MS zircon U-Pb dating indicates that the aegirine nepheline syenite was emplaced in the Late Triassic (229.5 ± 2.2 Ma), which is spatially, temporally and genetically related to Nb mineralization. These aegirine nepheline syenites have SiO2 contents in the range of 55.86–63.80 wt. %, low TiO2 contents of 0.36–0.64 wt. %, P2O5 contents of 0.04–0.11 wt. % and Al2O3 contents of more than 15 wt. %. They are characterized by relatively high (K2O + Na2O) values of 9.72–15.51 wt. %, K2O/Na2O ratios of 2.42–3.64 wt. % and Rittmann indexes (σ = [ω(K2O + Na2O)]2/[ω(SiO2 − 43)]) of 6.84–17.10, belonging to the high-K peralkaline, metaluminous type. These syenites are enriched in large ion lithophile elements (LILEs, e.g., Cs, Rb and Ba) and light rare earth elements (LREEs) and relatively depleted in high field strength elements (HFSEs, e.g., Nb, Zr and Ti) and heavy rare earth elements (HREEs), with transitional elements showing an obvious W-shaped distribution pattern. Based on these geochronological and geochemical features, we propose that the ore-forming intrusion associated with the Nb mineralization was formed under post-collision continental-rift setting, which is consistent with the tectonic regime of post-collision between the North China Craton and Paleo-Asian oceanic plate during the age in Ma for Indosinian (257–205 Ma). Intensive magmatic and metallogenic events resulted from partial melting of lithospheric mantle occurred during the post-collisional rifting, resulting in the development of large-scale Cu–Mo mineralization and rare earth deposits in the eastern part of Liaoning Province.

Origin, tectonic environment and age of the Bibole banded iron formations, northwestern Congo Craton, Cameroon: geochemical and geochronological constraints

2021 ◽  
pp. 1-19
Author(s):  
Arlette Pulcherie Djoukouo Soh ◽  
Sylvestre Ganno ◽  
Lianchang Zhang ◽  
Landry Soh Tamehe ◽  
Changle Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Atmospheric Oxygen ◽  
Banded Iron Formations ◽  
True Negative ◽  
Low Concentrations ◽  
Heavy Rare Earth Elements ◽  
Geochronological Constraints ◽  
Geochemical Studies ◽  
Iron Formations

Abstract The newly discovered Bibole banded iron formations are located within the Nyong Group at the northwest of the Congo Craton in Cameroon. The Bibole banded iron formations comprise oxide (quartz-magnetite) and mixed oxide-silicate (chlorite-magnetite) facies banded iron formations, which are interbedded with felsic gneiss, phyllite and quartz-chlorite schist. Geochemical studies of the quartz-magnetite banded iron formations and chlorite-magnetite banded iron formations reveal that they are composed of >95 wt % Fe2O3 plus SiO2 and have low concentrations of Al2O3, TiO2 and high field strength elements. This indicates that the Bibole banded iron formations were not significantly contaminated by detrital materials. Post-Archaean Australian Shale–normalized rare earth element and yttrium patterns are characterized by positive La and Y anomalies, a relative depletion of light rare earth elements compared to heavy rare earth elements and positive Eu anomalies (average of 1.86 and 1.15 for the quartz-magnetite banded iron formations and chlorite-magnetite banded iron formations, respectively), suggesting the influence of low-temperature hydrothermal fluids and seawater. The quartz-magnetite banded iron formations display true negative Ce anomalies, while the chlorite-magnetite banded iron formations lack Ce anomalies. Combined with their distinct Eu anomalies consistent with Algoma- and Superior-type banded iron formations, we suggest that the Bibole banded iron formations were deposited under oxic to suboxic conditions in an extensional basin. SIMS U–Pb data indicate that the Bibole banded iron formations were deposited at 2466 Ma and experienced metamorphism and metasomatism at 2078 Ma during the Eburnean/Trans-Amazonian orogeny. Overall, these findings suggest that the studied banded iron formations probably marked the onset of the rise of atmospheric oxygen, also known as the Great Oxidation Event in the Congo Craton.

The retrograde hydration of the continental granitoid crust as seen from epidote-bearing veins: Trace elements and microstructures

2020 ◽  
Author(s):  
Veronica Peverelli ◽  
Alfons Berger ◽  
Thomas Pettke ◽  
Holger Stunitz ◽  
Pierre Lanari ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Continental Crust ◽  
Host Rock ◽  
Geochemical Characteristics ◽  
Geochemical Data ◽  
Massif Central ◽  
Eu Anomaly ◽  
Aar Massif ◽  
Ree Patterns

<p>The widespread presence of epidote-bearing veins and hydrous minerals such as micas in meta-granitoid rocks attests to the large extent of hydration of the exhuming continental crust. The ability of epidote (Ca<sub>2</sub>Al<sub>3</sub>Si<sub>3</sub>O<sub>12</sub>(OH) – Ca<sub>2</sub>Al<sub>2</sub>Fe<sup>3+</sup>Si<sub>3</sub>O<sub>12</sub>(OH)) to incorporate a wide variety of trace elements renders this mineral a promising geochemical tracer of circulating fluid(s).</p><p>We report trace element and microstructural data on epidote-bearing veins from the Aar Massif (Central Alps) and from the Albula Pass (Eastern Alps). We characterized and classified the epidote-bearing veins based on their extent of deformation, shape and size of the epidote grains, coexisting minerals, and degree of dynamic recrystallization of associated quartz. Laser ablation ICP-MS data of individual epidote crystals reveal prominent zoning, confirmed by electron probe maps for Sr and Mn. Overall, low to very low Th/U ratios (down to 0.0005 in the Aar Massif veins and 0.001 in the Albula ones) with Th often below limits of detection (< 0.1 µg/g at 16 µm beam size) go along with variably LREE-depleted patterns (and CI Chondrite-normalized La<sub>N</sub>/Yb<sub>N</sub> ~0.35 in the Aar Massif veins and ~0.60 in the Albula Pass veins). Strontium contents are variable (hundreds to thousands of µg/g) and mostly high (up to 10100 µg/g in the Aar Massif samples and 12800 µg/g in the Albula Pass samples). The in-situ geochemical data are linked to the microstructures in order to assess whether microstructures can be related to variations in trace elements, also considering the role of coexisting phases. Moreover, trace element data of samples from the Aar Massif are compared to metamorphic host-rock epidotes and cleft epidotes from the same massif.</p><p>We find that REE patterns of Aar Massif vein epidotes are clearly different than those of metamorphic host-rock epidotes and of cleft epidotes. In addition, REE patterns vary based on the microstructural characteristics of veins. Overall REE patterns of the Albula Pass vein epidotes resemble those from the Aar Massif. Different veins and microstructures define clusters in Sr vs. Y, Eu anomaly vs. Th/U ratios, and Eu anomaly vs. U values. Geochemical heterogeneities are observed among sampling localities within the Aar Massif.</p><p>The fact that the geochemical characteristics of retrograde hydrothermal vein epidotes are clearly different than those of high-grade metamorphic and metamorphic host-rock epidotes, and the relationship between geochemical characteristics and microstructures support the hypothesis that the deformation did not alter the original geochemical record through neomineralization. Our data argue for the potential of epidote as a powerful fluid tracer in the granitoid continental crust.</p>

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