scholarly journals Gold Mineralization at the Maletoyvayam Deposit (Koryak Highland, Russia) and Physicochemical Conditions of Its Formation

Minerals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1093
Author(s):  
Evgeny G. Sidorov ◽  
Andrey A. Borovikov ◽  
Nadezhda D. Tolstykh ◽  
Daria S. Bukhanova ◽  
Galina A. Palyanova ◽  
...  

Microthermometry study of fluid inclusions in quartz veins of the Maletoyvayam deposit (Koryak Highland, Russia) was carried out. This epithermal gold deposit contains unique Au compounds including maletoyvayamite, which has not been reported anywhere else. Two paragenetic mineral associations (pyrite-quartz and maletoyvayamite-quartz) with quartz of different generations corresponding to different pulses were also described. Only early generations of quartz (Q1) include ore minerals: pyrite for the first mineral assemblage, and in Au-bearing minerals, sulfosalts, bismuthinite, and others—for the second assemblage. A study on fluid inclusions in quartz showed a salinity (mainly NaCl + KCl) range from 0.2 to 4.3 wt.% NaCl eq., increasing from the first mineral association to the second due to boiling fluids. The obtained temperature variations for quartz crystallization were 295–135 °C, the fluid pressure ranged from 79 to 4 bar. On the other hand, the range of conditions obtained for the gold productive ore association is more narrow: salinity of the fluid inclusions is 4.3 wt.% NaCl eq., the temperatures vary from 255 °C to 245 °C, and the pressure from 39 to 32 bar. These physicochemical characteristics of the Maletoyvayam ore deposit greatly coincide with other HS-type epithermal deposits; however, within the Central Kamchatka Volcanic Belt it is so far the only deposit of this type reported.

2020 ◽  
Author(s):  
Neeraj Kumar Sharma ◽  
Tapas Kumar Biswal

<p>Quartz veins are produced from the crystallization of the last silica enriched hydrothermal phase from granitic magma circulating along the pre-existing fracture of rock. In many instances, these hydrothermal fluid act as a carrier for the ore minerals. The intrusion of quartz veins along fractures depends upon the tectonic stress conditions in the area. Fluid pressure (P<sub>f</sub>) of these ascending liquids should be higher than the normal compressive stress (σ<sub>n</sub>) to dilate the fractures. We are studying the quartz vein intrusion in the Cu‒Pb‒Zn mineralization belt of Ambaji, South Delhi terrane, Aravalli- Delhi mobile belt, NW India. The host rocks include mica schist, amphibolite, calc schist, talc tremolite schist, and four phases of granite intrusion (G<sub>0</sub>‒G<sub>3</sub>). The age of G<sub>0</sub>, G<sub>1</sub>, G<sub>2</sub> and G<sub>3</sub> granite are 960, 860, 800, and 750 Ma respectively. The rocks underwent three phases of folding (F<sub>1</sub>‒F<sub>3</sub>) and show greenschist to amphibolite facies metamorphism. The quartz vein intrusion is related to syn to post F<sub>3</sub> folding and G<sub>3</sub> granite magmatism. This final phase hydrothermal fluid extremely altered host rock and formed biotite-tourmaline-quartz and tremolite-actinolite-talc-chlorite greisen along the contact. The greisen host chalcopyrite-pyrite-galena-sphalerite mineralization suggesting the ore minerals were transported by the quartz vein. Vein orientation, stress condition, fluid pressure fluctuation, and fluid temperature can decide the fracture dilation and mineralization processes. Therefore, this work concentrates on the geometrical distribution of the vein orientation data. From this we deduced (i) girdle distribution pattern of vein data  (ii) σ<sub>1</sub> = 120º/75º, σ<sub>2</sub> = 052º/07º, σ<sub>3</sub> = 323º/07º indicate maximum extension was NW-SE and σ<sub>1</sub>σ<sub>2</sub> plane strikes was N52ºE, (iii) θ<sub>2</sub> =12º, θ<sub>3</sub> = 40º  and (iv) R'(driving pressure ratio) = 0.95, ϕ (tectonic stress ratio) = 0.90 indicates high value for R' leading to dilation of wide range of fractures. Further, the high ϕ value suggests uniaxial extension. Microscopic petrography of fluid inclusions shows three generations of inclusion like primary inclusion, secondary inclusion, and pseudosecondary inclusion. Most of the inclusion has aqueous and vapour phase and some inclusions show solid halite phase. We observed different types of trail bound of inclusion like intragranular inclusion, intergranular inclusion and transgranular inclusion, which suggest deformation and recrystallization in the rock. We are studying microthermometry analysis of fluid inclusion present in the quartz vein and trying to estimate the fluid pressure. With the help of fluid pressure, the 3D Mohr circle will be constructed and paleostress will be quantified. That will help in understanding the stress condition and mineralization in the rock.</p><p>Keywords: Veins, Fractures, Paleostress, 3D Mohr Circle, Mineralisation, Fluid Inclusion, Microthermometry</p>


2017 ◽  
Vol 54 (5) ◽  
pp. 494-511 ◽  
Author(s):  
Xi-hui Cheng ◽  
Jiu-hua Xu ◽  
Jian-xiong Wang ◽  
Qing-po Xue ◽  
Hui Zhang

The Hamadi gold deposit is located in North Sudan, and occurs in the Neoproterozoic metamorphic strata of the Arabian–Nubian Shield. Two types of gold mineralization can be discerned: gold-bearing quartz veins and altered rock ores near ductile shear zones. The gold-bearing quartz veins are composed of white to gray quartz associated with small amounts of pyrite and other polymetallic sulfide minerals. Wall-rock alterations include mainly beresitization, epidotization, chloritization, and carbonatization. CO2-rich inclusions are commonly seen in gold-bearing quartz veins and quartz veinlets from gold-bearing altered rocks; these include mainly one-phase carbonic (CO2 ± CH4 ± N2) inclusions and CO2–H2O inclusions with CO2/H2O volumetric ratios of 30% to ∼80%. Laser Raman analysis does not show the H2O peak in carbonic inclusions. In quartz veins, the melting temperature of solid CO2 (Tm,CO2) of carbonic inclusions has a narrow range of −59.6 to −56.8 °C. Carbonic inclusions also have CO2 partial homogenization temperatures (Th,CO2) of −28.3 to +23.7 °C, with most of the values clustering between +4.0 and +20 °C; all of these inclusions are homogenized into the liquid CO2 state. The densities range from 0.73 to 1.03 g/cm3. XCH4 of carbonic fluid inclusions ranges from 0.004 to 0.14, with most XCH4 around 0.05. In CO2–H2O fluid inclusions, Tm,CO2 values are recorded mostly at around −57.5 °C. The melting temperature of clathrate is 3.8–8.9 °C. It is suggested that the lowest trapping pressures of CO2 fluids would be 100 to ∼400 MPa, on the basis of the Th,CO2 of CO2-bearing one-phase (LCO2) inclusions and the total homogenization temperatures (Th,tot) of paragenetic CO2-bearing two-phase (LCO2–LH2O) inclusions. For altered rocks, the Tm,CO2 of the carbonic inclusions has a narrow range of −58.4 to ∼−57.0 °C, whereas the Th,CO2 varies widely (−19 to ∼+29 °C). Most carbonic inclusions and the carbonic phases in the CO2–H2O inclusions are homogenized to liquid CO2 phases, which correspond to densities of 0.70 to ∼1.00 g/cm3. Fluid inclusions in a single fluid inclusion assemblage (FIA) have narrow Tm,CO2 and Th,CO2 values, but they vary widely in different FIAs and non-FIAs, which indicates that there was a wide range of trapping pressure and temperature (P–T) conditions during the ore-forming process in late retrograde metamorphism after the metamorphism peak period. The carbonic inclusions in the Hamadi gold deposit are interpreted to have resulted from unmixing of an originally homogeneous aqueous–carbonic mixture during retrogress metamorphism caused by decreasing P–T conditions. CO2 contributed to gold mineralization by buffering the pH range and increasing the gold concentration in the fluids.


2021 ◽  
Vol 9 ◽  
Author(s):  
Tong Ha Lee ◽  
Jung Hun Seo ◽  
Bong Chul Yoo ◽  
Bum Han Lee ◽  
Seung Hee Han ◽  
...  

Haman, Gunbuk, and Daejang deposits are neighboring vein-type hydrothermal Cu deposits located in the SE part of the Korean Peninsula. These three deposits are formed by magmatic-hydrothermal activity associated with a series of Cretaceous granodioritic intrusions of the Jindong Granitoids, which have created a series of veins and alterations in a hornfelsed shale formation. The copper deposits have common veining and alteration features: 1) a pervasive chlorite-epidote alteration, cut by 2) Cu-Pb-Zn-bearing quartz veins with a tourmaline-biotite alteration, and 3) the latest barren calcite veins. Chalcopyrite, pyrite, and pyrrhotite are common ore minerals in the three deposits. Whereas magnetite is a dominant mineral in the Haman and Gunbuk deposits, no magnetite is present, but sphalerite and galena are abundant in the Daejang deposit. Ore-bearing quartz veins have three types of fluid inclusions: 1) liquid-rich, 2) vapor-rich, and 3) brine inclusions. Hydrothermal temperatures obtained from the brine inclusion assemblages are about 340–600, 250–500, and 320–460°C in the Haman, Gunbuk, and Daejang deposits, respectively. The maximum temperatures (from 460 to 600°C) recorded in the fluid inclusions of the three deposits are higher than those of the Cu ore precipitating temperature of typical porphyry-like deposits (from 300 to 400°C). Raman spectroscopy of vapor inclusions showed the presence of CO2 and CH4 in the three deposits, which indicates relatively reduced hydrothermal conditions as compared with typical porphyry deposits. The Rb/Sr ratios and Cs concentrations of brine inclusions suggest that the Daejang deposit was formed by a later and more fractionated magma than the Haman and Gunbuk deposits, and the Daejang deposit has lower Fe/Mn ratios in brine inclusions than the Haman and Gunbuk deposits, which indicates contrasting redox conditions in hydrothermal fluids possibly caused by an interaction with a hosting shale formation. In brines, concentrations of base metals do not change significantly with temperature, which suggests that significant ore mineralization precipitation is unlikely below current exposure levels, especially at the Haman deposit. Ore and alteration mineral petrography and fluid inclusions suggest that the Haman deposit was formed near the top of the deep intrusion center, whereas the Gunbuk deposit was formed at a shallower intrusion periphery. The Daejang deposit was formed later at a shallow depth by relatively fractionated magma.


2015 ◽  
Vol 7 (2) ◽  
pp. 75
Author(s):  
Arifudin Idrus ◽  
Fahmi Hakim ◽  
I Wayan Warmada ◽  
Mochammad Aziz ◽  
Jochen Kolb ◽  
...  

Low suphidation (LS) epithermal gold deposits were recently found in the Paningkaban area, Central Java province, Indonesia, with more than five hundred artisanal gold miners currently operating in the area. This study is aimed to understand the geological factors controlling the gold mineralization and to characterize the alteration and ore mineralogy of the deposit. Several epithermal veins/veinlets trending N–S, NW–SE, and NE–SW are hosted by Tertiary turbiditic volcanoclastic sedimentary rocks of the Halang formation. This formation is composed of looping gradation of sandstone and siltstone units. Pre- and syn-mineralization structures such as extension joints, normal sinitral fault and sinitral fault control the gold mineralization. Fault movements formed dilational jogs manifested by NW-SE-trending en-echelon tension gash veins. Four main alteration zones are identified: (a) phyllic, (b) argillic, (c) sub propylitic and (d) weak subpropylitic. Ore minerals consist of native gold, electrum, native silver, pyrite, chalcopyrite, sphalerite, galena, arsenopyrite, cubanite, marcasite, covellite and tennantite, which are commonly associated withargillic alteration. Vein structures such as massive, swarm and low angle veins, stockwork and veins dispersed in diatreme breccia are present. Normal banded, cockade, crustiform, bladed carbonates as well as, comb and saccharoidal features are the typical vein textures. It is noteworthy that the veins are basically composed of carbonate with minor quartz at gold grades of up to 83 g/t Au. Based on the vein structures and textures, four stages of ore mineralization were developed consisting of (a) early stage (fluidized breccia and quartz vein), (b) middle stage (carbonate base metal), (c) late stage (late carbonate), and supergene stage. Gold mineralization originated mainly during middle and late stages, particularly in association with cockade, crustiform, bladed carbonate base metal veins. Based on those various features, the LS epithermal deposit in the study area is categorized as carbonate-base metalgold mineralization type.


Author(s):  
Arifudin Idrus ◽  
Sukamandaru Prihatmoko ◽  
Ernowo Harjanto ◽  
Franz Michael Meyer ◽  
Irzal Nur ◽  
...  

In Indonesia, gold is commonly mined from epithermal-, porphyry-, and skarn-type deposits that are commonly found in volcanic belts along island arcs or active continental margin settings. Numerous gold prospects, however, were recently discovered in association with metamorphic rocks. This paper focuses on metamorphic rock-hosted gold mineralization in Eastern Indonesia, in particular the Bombana (SE Sulawesi) and Buru Island (Maluku) prospects. At Bombana, gold-bearing quartz-veins are hosted by the Pompangeo metamorphic complex. Sheared, segmented veins vary in thickness from 2 cm to 2 m. Gold is mainly present in the form of ‘free gold’ among silicate minerals and closely related to cinnabar, stibnite, tripuhyite, and in places, minor arsenopyrite. The gold distribution is erratic, however, ranging from below detection limit up to 134 g/t. At least three generations of veins are identified. The first is parallel to the foliation, the second crosscuts the first generation of veins as well as the foliation, and the late-stage laminated deformed quartz-calcite vein represents the third mineralization stage. The early veins are mostly massive to crystalline, occasionally brecciated, and sigmoidal, whereas the second-stage veins are narrower than the first ones and less subjected to brecciation. Gold grades in the second- and third-stage veins are on average higher than that in the earlier veins. Microthermometric and Raman spectrometric studies of fluid inclusions indicate abundant H2O-NaCl and minor H2O-NaCl-CO2 fluids. Homogenization temperatures and salinities vary from 114 to 283 ºC and 0.35 to 9.08 wt.% NaCl eq., respectively. Crush-leach analysis of fluid inclusions suggests that the halogen fluid chemistry is not identical to sea water, magmatic or epithermal related fluids, but tends to be similar to fluids in mesothermal-type gold deposits. In Buru Island (Gunung Botak and Gogorea prospects), two distinct generations of quartz veins are identified. Early quartz veins are segmented, sigmoidal discontinuous and parallel to the foliation of the host rock. This generation of quartz veins is characterized by crystalline relatively clear quartz, and weakly mineralized with low sulfide and gold contents. The second type of quartz veins occurs within the ‘mineralized zone’ of about 100 m in width and ~1,000 m in length. Gold mineralization is intensely overprinted by argillic alteration. The mineralization-alteration zone is probably parallel to the mica schist foliation and strongly controlled by N-S or NE-SW-trending structures. Gold-bearing quartz veins are characterized by banded texture particularly following host rock foliation and sulphide banding, brecciated and rare bladed-like texture. Alteration types consist of propylitic (chlorite, calcite, sericite), argillic and carbonation represented by graphite banding and carbon flakes. Ore mineral comprises pyrite, native gold, pyrrhotite, and arsenopyrite. Cinnabar and stibnite are present in association with gold. Ore chemistry indicates that 11 out of 15 samples yielded more than 1 g/t Au, in which 6 of them graded in excess of 3 g/t Au. All high-grade samples are composed of limonite or partly contain limonitic material. This suggests the process of supergene enrichment. Interestingly, most of the high-grade samples contain also high concentrations of As (up to 991ppm), Sb (up to 885ppm), and Hg (up to 75ppm). Fluid inclusions in both quartz vein types consist of 4 phases including L-rich, V-rich, L-V-rich and L1-L2-V (CO2)-rich phases. The mineralizing hydrothermal fluid typically is CO2-rich, of moderate temperature (300-400 ºC), and low salinity (0.36 to 0.54 wt.% NaCl eq). Based on those key features, gold mineralization in Bombana and Buru Island tends to meet the characteristics of orogenic, mesothermal types of gold deposit. Metamorphic rock-hosted gold deposits could represent the new targets for gold exploration particularly in Eastern Indonesia.


2019 ◽  
Vol 17 (1) ◽  
pp. 23-35 ◽  
Author(s):  
Ye Qiu ◽  
Xiao-Lin Wang ◽  
Xian Liu ◽  
Jian Cao ◽  
Yi-Feng Liu ◽  
...  

AbstractWe re-evaluate the Raman spectroscopic quantification of the molar ratio and pressure for CH4–CO2 mixtures. Firstly, the Raman quantification factors of CH4 and CO2 increase with rising pressure at room temperature, indicating that Raman quantification of CH4/CO2 molar ratio can be applied to those fluid inclusions (FIs) with high internal pressure (i.e., > 15 MPa). Secondly, the v1(CH4) peak position shifts to lower wavenumber with increasing pressure at constant temperature, confirming that the v1(CH4) peak position can be used to calculate the fluid pressure. However, this method should be carefully calibrated before applying to FI analyses because large discrepancies exist among the reported v1(CH4)-P curves, especially in the high-pressure range. These calibrations are applied to CH4-rich FIs in quartz veins of the Silurian Longmaxi black shales in southern Sichuan Basin. The vapor phases of these FIs are mainly composed of CH4 and minor CO2, with CO2 molar fractions from 4.4% to 7.4%. The pressure of single-phase gas FI ranges from 103.65 to 128.35 MPa at room temperature, which is higher than previously reported. Thermodynamic calculations supported the presence of extremely high-pressure CH4-saturated fluid (218.03–256.82 MPa at 200 °C), which may be responsible for the expulsion of CH4 to adjacent reservoirs.


Minerals ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 740 ◽  
Author(s):  
Erik Tharalson ◽  
Thomas Monecke ◽  
T. Reynolds ◽  
Lauren Zeeck ◽  
Katharina Pfaff ◽  
...  

High-grade ore zones in low-sulfidation epithermal deposits are commonly associated with the occurrence of banded quartz veins. The ore minerals in these veins are heterogeneously distributed and are mostly confined to ginguro bands, which can be identified in hand specimen based on their distinct dark gray to black color. Micro-X-ray fluorescence element maps obtained on representative samples of banded quartz veins show that Au occurs together with Ag minerals in some of the ginguro bands, but Au can also be present in quartz bands that are light gray to white and cannot be macroscopically distinguished from barren bands. The occurrence of compositionally distinct ginguro and gankin bands, the latter being a new term coined here for colloform quartz bands containing primarily electrum or native gold, can be explained by temporal changes in the composition of the ore-forming thermal waters or variations in the conditions of ore deposition. Textural relationships, including the dendritic shape of ore minerals that appear to have grown in a matrix of silica microspheres, suggest that the ginguro and gankin bands have formed as a result of rapid deposition associated with vigorous boiling or flashing of the thermal waters.


Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 399 ◽  
Author(s):  
Zheng ◽  
Yang ◽  
Gao ◽  
Chen ◽  
Liu ◽  
...  

The Nibao gold deposit, which includes both fault-controlled and strata-bound gold orebodies, constitutes an important part of the Yunnan–Guizhou–Guangxi “Golden Triangle” region. Defining the mineralization age of these gold orebodies may provide additional evidence for constraining the formation ages of low-temperature orebodies and their metallogenic distribution in South China. Petrographic studies of gold-bearing pyrites and ore-related quartz veins indicate that these pyrites coexist with quartz or filled in vein-like quartz, which suggests a possible genetic relationship between the two from Nibao gold deposit. Minerals chemistry shows that Rb and Sr are usually hosted in fluid inclusions in quartz ranging from 0.0786 to 2.0760 ppm and 0.1703 to 2.1820 ppm, respectively. The Rb–Sr isotopic composition of gold-bearing quartz-hosted fluid inclusions from the Nibao gold deposit were found to have Rb–Sr isochron ages of 142 ± 3 and 141 ± 2 Ma for both fault-controlled and strata-bound orebodies, respectively, adding more evidence to previous studies and thus revealing a regional gold mineralization age of 148–134 Ma. These results also confirm the Middle-Late Yanshanian mineralizing events of Carlin-type gold deposits in Yunnan, Guizhou, and Guangxi Provinces of Southwest China. In addition, previous studies indicated that antimony deposits in the region which were formed at ca. 148–126 Ma have a close affinity with gold deposits. This illustrates that the regional low-temperature hydrothermal gold mineralization is related in space and time to the Yanshanian (ca. 146–115 Ma) magmatic activity. Specifically, the large-scale gold and antimony mineralization are considered to be inherently related to mantle-derived mafic and ultramafic magmatic rocks associated with an extensional tectonic environment. Based on the initial 87Sr/86Sr ratios of 0.70844 ± 0.00022 (2σ) and 0.70862 ± 0.00020 (2σ) for gold-bearing quartz veins from fault-controlled and strata-bound gold orebodies, respectively, at the Nibao gold deposit, as well as the C, H, O, and S isotopic characteristics of gold deposits located in the Golden Triangle region, we suggest that the mantle-derived material can be involved in the formation of the Nibao gold deposit and that the ore-forming fluid can be derived from a mixed crust–mantle source.


2020 ◽  
Vol 58 (2) ◽  
pp. 191-201 ◽  
Author(s):  
Ana C. Mugas Lobos ◽  
María Florencia Márquez-Zavalía ◽  
Laura B. Hernández

ABSTRACT The Cerro Moro deposit is located at 48°5′55″S, 66°39′1.6″W and 100 m.o.s.l. in Santa Cruz province, southern Argentina. It is a low sulfidation Au-Ag epithermal mineralization hosted by numerous NW–SE structurally controlled quartz veins developed in close spatial and temporal proximity to the products of Jurassic extension and magmatism. The Escondida vein is the most significant mineralized structure, as it hosts the base metal-rich and Au-Ag high grade mineralization. In this vein and the Zoe ore-shoot, ore minerals are abundant (sphalerite, galena, chalcopyrite, acanthite, and less abundant pyrite and marcasite) and frequently related to dark grey, fine-grained quartz with massive, porous, crustiform, and banded textures; variable quantities of fine-grained flakes of muscovite are locally present. The Ag- and Au-bearing mineral association is represented by acanthite, argyrodite, polybasite, pearceite, stromeyerite, mckinstryite, and jalpaite. Abundant acanthite occurs commonly associated with gold and silver; copper enrichments were detected and interpreted as nanoinclusions of Cu-bearing minerals. The occurrence of Se- and Te-enriched minerals (acanthite, argyrodite, polybasite, pearceite, stromeyerite, and mckinstryite), rather than silver selenides and/or tellurides, indicates the presence of reduced mineralizing fluids and may be ascribed to partial substitution of S by Se or Te. Polybasite and pearceite were differentiated by their chemistry. Although the presence of argyrodite in epithermal deposits with silver sulfosalts is relatively common, this first mention in Cerro Moro is highly encouraging for exploration for germanium, a critical element, which is also considered strategic by countries such as the USA and China.


Sign in / Sign up

Export Citation Format

Share Document