scholarly journals Micro-Raman—A Tool for the Heavy Mineral Analysis of Gold Placer-Type Deposits (Pianu Valley, Romania)

Minerals ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 988
Author(s):  
Andreea Elena Maftei ◽  
Andrei Buzatu ◽  
Gheorghe Damian ◽  
Nicolae Buzgar ◽  
Harald G. Dill ◽  
...  

In the current study, different heavy minerals typical of gold placer deposits were identified by means of micro-Raman spectroscopy, and their chemical composition analyzed and discussed (garnet, kyanite, staurolite, zircon, allanite, monazite, xenotime, rutile, anatase, cassiterite, titanite, barite). Even complex solid solution series, such as those of garnets, can be deciphered with the aid of systematic trends observed in Raman line frequencies. The ν1 mode in garnets will shift from high to low frequencies as a function of the ionic radius of the X2+ cation, from Mg2+, to Fe2+ and Mn2+, while the presence of Ca2+ will make the band to be shifted strongly to even lower wavenumbers. This approach has successfully been taken to differentiate between polymorph triplets such as kyanite-sillimanite-andalusite and rutile-anatase-brookite. Minerals under consideration with high contents of REE, U and Th are affected by intensive metamictization, particularly zircon and titanite. Raman peak features, such as shape, symmetry and intensity, respond to this radiation damage of the lattice and enable fine-tuning of these heavy minerals, such as in the case of fluorite (fetid fluorite).

Geologos ◽  
2013 ◽  
Vol 19 (1-2) ◽  
pp. 5-23 ◽  
Author(s):  
Bogusław Marcinkowski ◽  
Elżbieta Mycielska-Dowgiałło

Abstract The composition of heavy-mineral assemblages is one of the main textural features of sediments because they can have significant value for the interpretation of, among others, their depositional environment, their depositional processes, and their stratigraphic position. Distinctive features of heavy minerals include their resistance to chemical weathering and mechanical abrasion, their habit, and their density. These parameters are the most widely used in the heavy-mineral research of Quaternary deposits in Poland, as well as in such research in other countries conducted by Polish scientists. Several other heavy-mineral parameters can also be used in various types of interpretation. It is discussed whether heavy-mineral analysis is decisive in the evaluation of deposits or whether it plays mainly a role that may support evidence obtained by other types of analysis. The attention is mainly devoted to transparent heavy minerals; the significance of opaque heavy minerals for interpretational purposes is only mentioned.


1992 ◽  
Vol 129 (5) ◽  
pp. 573-580 ◽  
Author(s):  
A. C. Morton ◽  
J. R. Davies ◽  
R. A. Waters

AbstractA pilot study has demonstrated that heavy mineral analysis is a useful guide to the provenance of Silurian turbidites in the Southern Welsh Basin. The results confirm the sedimentological evidence for two distinct source areas of coarse clastic detritus, one lying to the south and the other to the east. They also provide mineralogical criteria by which the two source areas may be distinguished. The southern area provided material with relatively low mineral diversity, and is characteristic in having low rutile/zircon ratios, whereas the eastern source provided more diverse assemblages, generally with high rutile/zircon ratios. The southern source shows variations in terms of apatite/tourmaline ratio, with the older Aberystwyth Grits Group tending to contain relatively low apatite compared with the younger Cwmystwyth Grits Group (Rhuddnant and Pysgotwr Grits formations). There is evidence for polycyclic material and volcanic detritus in both southerly and easterly derived samples; however, easterly-sourced sandstones apparently tapped a more lithologically-diverse terrain.


2016 ◽  
Vol 1 (2) ◽  
Author(s):  
Noor C.D. Aryanto ◽  
Joni Widodo ◽  
Purnomo Raharjo

Berdasarkan hasil analisa unsur terhadap 7 contoh sedimen permukaan dasar laut di Perairan Pantai Gundi, Bangka Barat, yang kemudian dianalisa dengan menggunakan metode Inductively Coupled Plasma (ICP) dapat diketahui konsentrasi kandungan unsur Niobium (Nb) dan unsur Tantalum (Ta). Selain itu dilakukan pula analisa mineral berat dengan menggunakan larutan pemisah bromoform (BJ 2,83) terhadap 15 contoh. Konsentrasi kandungan unsur jarang seperti Niobium dapat mencerminkan keberadaan mineral berat ekonomis, yaitu mineral berat yang resisten terhadap pelapukan dan mengandung unsur Titanium (Ti), seperti mineral Ilmenit (FeTiO3) dan rutil (TiO2). Juga dapat dibuktikan, di daerah selidikan bahwa keberadaan unsur Niobium dan Tantalum di alam hampir dapat dipastikan selalu berasosiasi. Di daerah selidikan asosiasi ini berupa mineral columbite-tantalite (Fe,Mn)Nb2O6-(Fe,Mn)Ta2O6 dan pyrochlore (Na, Ca, Ce…)2 Nb2O6F. Selain itu masih dengan memperhatikan asosiasi kedua unsur ini dapat diketahui pula asal batuan sumber dari sedimen-sedimen dimana mineral tersebut terakumulasi, karena asosiasi antara unsur Niobium dan Tantalum merupakan penciri untuk daerah pegmatis. Based on element analysis of 7 surface sediment samples from Gundi Waters, Western Bangka by using Inductively Coupled Plasm (ICP), the content of rare element Niobium (Nb) and Tantalum (Ta) can be identified. On the other hand heavy mineral analysis with float-sink method using bromoform as separator liquid has been applied for 15 samples. Based on observations the concentration of Niobium (Nb) element reflects the present of heavy minerals consisted of Titanium (Ti) element, such as Ilmenit (FeTiO2) and Rutil (TiO2). It is can also be proved that in the investigated area Niobium (Nb) and Tantalum (Ta) elements are occure in association. In the study area, this association shows as columbite-tantalite (Fe,Mn)Nb2O6-(Fe,Mn)Ta2O6 and pyrochlore (Na, Ca, Ce…)2 Nb2O6F minerals. Moreover, based on this association, it can be recognized the source rocks of the sediment where the minerals accumulate as association of these two elements are specific for pegmatic area.


1962 ◽  
Vol S7-IV (2) ◽  
pp. 264-272 ◽  
Author(s):  
Jean Demangeot ◽  
M. Ters

Abstract Heavy mineral analysis of samples from the Adriatic side of the Abruzzi mountains gives an indication of the age of the surface of the Gran Sasso plateaus and of the Quaternary continental formations. The absence of heavy minerals characteristic of the Pontian molasse suggests the possibility that the plateaus were never completely covered by the Pontian sea. The isolated molasse deposits which have been reported from the Gran Sasso may have been deposited in small gulfs along the shore of the sea. The Quaternary marine sediments have been dated by their fossil content. The majority of the Quaternary deposits, however, are gravels, breccias and eolian loams which contain neither fossils nor pollen. Cinder showers from Quaternary eruptions on the Tyrrhenian side of Abruzzi were carried by the wind and deposited volcanic minerals which were incorporated in the Quaternary material of the central Apennines. Heavy mineral analysis of the deposits containing these minerals reveals associations which provide a basis for determining the chronology of the Quaternary strata.


2020 ◽  
pp. 1-10
Author(s):  
Péter Kelemen ◽  
Gábor Csillag ◽  
István Dunkl ◽  
Andrea Mindszenty ◽  
Ivett Kovács ◽  
...  

Abstract In the Transdanubian Range, Pannonian Basin, Hungary, karstic sinkholes on a planation surface of Triassic carbonates are filled by grey clayey–silty kaolin deposits. The provenance and accumulation age of these strongly altered terrestrial karst-filling sediments are constrained by X-ray powder diffraction, heavy mineral analysis and zircon U–Pb dating. The heavy minerals of the Southern Bakony Mountains samples are dominated by the ultra-stable zircon–rutile–tourmaline association. Zircon U–Pb data indicate accumulation between 20 and 16 Ma. Furthermore, Archaean to Palaeogene grains were also determined, reflecting the principally fluvial recycling of Eocene bauxites and their cover sequences. In contrast, the sample from the Keszthely Hills consists almost exclusively of airborne material including zircons of 18–14 Ma, reflecting a dominant contribution from the Carpathian–Pannonian Neogene volcanism. The shift in the Miocene age components is inferred to have been caused by the landscape evolution and burial history of the planation surface remnants controlled by local block tectonics.


1976 ◽  
Vol 6 (3) ◽  
pp. 425-444 ◽  
Author(s):  
Fekri A. Hassan

Heavy mineral analysis is a useful tool in tracing the changes in the hydrographic setting of the Nile through time. Analyses by the writer and others are presented to differentiate between a former Nilotic system, a Proto-Nile, and the modern Nile system, and to demonstrate the changes undergone by the modern Nile.The Proto-Nile was almost totally dependent upon discharge from equatorial and sub-equatorial tributaries in East Africa and from local Sudano-Egyptian affluents. The modern Nile system, in contrast, is dominated by contributions from the Blue Nile and the Atbara River, which drain the Ethiopian Plateau. The discharge of these rivers is governed by the monsoonal rains which are responsible for the summer floods in the Lower Nile Basin. It has been generally believed that this riverine system is very recent, perhaps not much older than 20,000 years. The evidence presented in this paper indicates that the Modern Nile system was well established by the later part of the Middle Pleistocene. In its early stage, the modern Nile was characterized by greater contributions from the non-Ethiopian East African and Sudano-Egyptian tributaries than at present.


Minerals ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 385 ◽  
Author(s):  
Lünsdorf ◽  
Kalies ◽  
Ahlers ◽  
Dunkl ◽  
von Eynatten

A significant amount of information on sedimentary provenance is encoded in the heavy minerals of a sediment or sedimentary rock. This information is commonly assessed by optically determining the heavy-mineral assemblage, potentially followed by geochemical and/or geochronological analysis of specific heavy minerals. The proposed method of semi-automated heavy-mineral analysis by Raman spectroscopy (Raman-HMA) aims to combine the objective mineral identification capabilities of Raman spectroscopy with high-resolution geochemical techniques applied to single grains. The Raman-HMA method is an efficient and precise tool that significantly improves the comparability of heavy-mineral data with respect to both overall assemblages and individual compositions within solid solution series. Furthermore, the efficiency of subsequent analysis is increased due to identification and spatial referencing of the heavy minerals in the sample slide. The method is tested on modern sediments of the Fulda river (central Germany) draining two Miocene volcanic sources (Vogelsberg, Rhön) resting on top of Lower Triassic siliciclastic sediments. The downstream evolution of the volcanic detritus is documented and the capability to analyze silt-sized grains has revealed an additional eolian source. This capability also poses the possibility of systematically assessing the heavy-mineral assemblages of shales, which are often disregarded in sedimentary provenance studies.


Minerals ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 470 ◽  
Author(s):  
Dill Harald G.

Gemstones form in metamorphic, magmatic, and sedimentary rocks. In sedimentary units, these minerals were emplaced by organic and inorganic chemical processes and also found in clastic deposits as a result of weathering, erosion, transport, and deposition leading to what is called the formation of placer deposits. Of the approximately 150 gemstones, roughly 40 can be recovered from placer deposits for a profit after having passed through the “natural processing plant” encompassing the aforementioned stages in an aquatic and aeolian regime. It is mainly the group of heavy minerals that plays the major part among the placer-type gemstones (almandine, apatite, (chrome) diopside, (chrome) tourmaline, chrysoberyl, demantoid, diamond, enstatite, hessonite, hiddenite, kornerupine, kunzite, kyanite, peridote, pyrope, rhodolite, spessartine, (chrome) titanite, spinel, ruby, sapphire, padparaja, tanzanite, zoisite, topaz, tsavorite, and zircon). Silica and beryl, both light minerals by definition (minerals with a density less than 2.8–2.9 g/cm3, minerals with a density greater than this are called heavy minerals, also sometimes abbreviated to “heavies”. This technical term has no connotation as to the presence or absence of heavy metals), can also appear in some placers and won for a profit (agate, amethyst, citrine, emerald, quartz, rose quartz, smoky quartz, morganite, and aquamarine, beryl). This is also true for the fossilized tree resin, which has a density similar to the light minerals. Going downhill from the source area to the basin means in effect separating the wheat from the chaff, showcase from the jeweler quality, because only the flawless and strongest contenders among the gemstones survive it all. On the other way round, gem minerals can also be used as pathfinder minerals for primary or secondary gemstone deposits of their own together with a series of other non-gemmy material that is genetically linked to these gemstones in magmatic and metamorphic gem deposits. All placer types known to be relevant for the accumulation of non-gemmy material are also found as trap-site of gemstones (residual, eluvial, colluvial, alluvial, deltaic, aeolian, and marine shelf deposits). Running water and wind can separate minerals according to their physical-chemical features, whereas glaciers can only transport minerals and rocks but do not sort and separate placer-type minerals. Nevertheless till (unconsolidated mineral matter transported by the ice without re-deposition of fluvio-glacial processes) exploration is a technique successfully used to delineate ore bodies of, for example, diamonds. The general parameters that matter during accumulation of gemstones in placers are their intrinsic value controlled by the size and hardness and the extrinsic factors controlling the evolution of the landscape through time such as weathering, erosion, and vertical movements and fertility of the hinterland as to the minerals targeted upon. Morphoclimatic processes take particular effect in the humid tropical and mid humid mid-latitude zones (chemical weathering) and in the periglacial/glacial and the high-altitude/mountain zones, where mechanical weathering and the paleogradients are high. Some tectono-geographic elements such as unconformities, hiatuses, and sequence boundaries (often with incised valley fills and karstic landforms) are also known as planar architectural elements in sequence stratigraphy and applied to marine and correlative continental environments where they play a significant role in forward modeling of gemstone accumulation. The present study on gems and gemstone placers is a reference example of fine-tuning the “Chessboard classification scheme of mineral deposits” [1] and a sedimentary supplement to the digital maps that form the core of the overview “Gemstones and geosciences in space and time” [2].


2020 ◽  
Vol 23 (3-4) ◽  
Author(s):  
Jasper VERHAEGEN

The Neogene units of Belgium cannot always be easily distinguished based on visual inspection and correlation across the basin is not straightforward. To aid in the stratigraphic interpretation of units, the discriminatory potential of heavy minerals has been determined. In this study, heavy mineral composition is combined with grain size analysis, providing information on the bulk sediment. Based on heavy mineral composition important interpretations could be made, such as (1) a different provenance between the Dessel Member and the Hageland Diest sand, making it improbable that they were deposited at the same time, (2) the Kasterlee-sensu-Gulinck unit of the eastern Antwerp Campine should be redefined as a lower Mol Formation unit or as a lateral equivalent of the typical Kasterlee Formation to the west, affected strongly by southern continental sediment input, and (3) the Waubach Member in the Ruhr Valley Graben should be split into two separate units, with the upper unit correlated with the Mol Formation and the lower unit, possibly the Inden Formation, correlated with the Diest Formation and Kasterlee Formation. The ‘X’ unit of the Maaseik core is likely a local transitional unit which cannot be directly correlated with a unit in the Campine Basin.


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