scholarly journals Origin of Northeast Fujian Basalts and Limitations on the Heterogeneity of Mantle Sources for Cenozoic Alkaline Magmatism across SE China: Evidence from Zircon U-Pb Dating, Petrological, Whole-Rock Geochemical, and Isotopic Studies

Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 770
Author(s):  
Guishan Zhang ◽  
Ren Peng ◽  
Hongxin Qiu ◽  
Hanjie Wen ◽  
Yonggang Feng ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Mantle Source ◽  
Trace Element Geochemistry ◽  
Alkaline Magmatism ◽  
Element Geochemistry ◽  
Alkali Basalts ◽  
Mantle Sources ◽  
Heavy Rare Earth Elements ◽  
Se China

Cenozoic alkali basalts in Southeast (SE) China generally are genetically related to intracontinental rifting. Hence, they can be used to probe the nature of their underlying mantle sources and aid studies of the tectonic background in this region. This paper focuses on the Shanhoujian alkali basalts located in Bailing County, northeastern Fujian, SE China. We herein report their petrology, whole-rock major, and trace element geochemistry, and Sr-Nd isotopic composition and provide a new zircon U-Pb age for the basalts (~40 Ma, Eocene). These data help to constrain the petrogenesis of alkali basalts, their mantle source, and tectonic settings. The basalts are characterized by high Mg# (58.21–63.52) with Na2O/K2O > 1. MgO content is weakly correlated with CaO and Cr content but shows no correlation with Ni and Fe2O3 (total). Such features suggest that fractionation of clinopyroxene rather than olivine was important. In terms of trace elements, the alkali basalts display: (1) enrichment in La, Ce, Rb, Ba, Nb, and Ta and depletion in K, Pb, Zr, Hf, and Ti and (2) notable fractionation of light rare earth elements from heavy rare earth elements. Determined (87Sr/86Sr)i is in the range of 0.7041–0.7040 and εNd (t) is between +3.2 and +3.3. The Shanhoujian alkali basalts show a notable affinity to oceanic island basalts (OIBs) with little assimilation of crustal materials. They were derived from a pyroxenite and carbonated peridotite mantle source metasomatized by sediments carried by the subduction plate at different depths. The primary magmas of these basalts were derived from partial melting of this metasomatized mantle source during upwelling of the asthenospheric mantle as an intracontinental rift formed through extension in this part of SE China.

scholarly journals Petrogenesis of the Jurassic Guiping Complex in the Southwestern South China Block: Insights into the Subduction Processes of the Paleo-Pacific Slab

Minerals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 807
Author(s):  
Zhao-Ying Lü ◽  
Chang-Qian Ma ◽  
Yuan-Yuan Liu ◽  
Fu-Hao Xiong ◽  
Chang-Xin Wei ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
South China ◽  
Lithospheric Mantle ◽  
Late Jurassic ◽  
Basaltic Magma ◽  
Parental Magma ◽  
Sio2 Content ◽  
Trace Element Geochemistry ◽  
Element Geochemistry

Late Jurassic NE-trending A-type granitoids are widespread in the Shihang belt, South China, though their petrogenesis and geodynamic settings remain controversial. The Guiping complex is located on the southwest margin of the Shihang belt. In this study, the petrography, major and trace element geochemistry, whole-rock Sr-Nd isotopes, and zircon U-Pb geochronology of the Guiping complex were investigated. The Guiping complex is composed of the Fenghuangling and Xishan plutons; both plutons yielded zircon U-Pb ages of ca. 160 Ma. The Fenghuangling pluton has low SiO2 content of 54.26% to 60.31%, whereas the Xishan pluton exhibits high SiO2 content of 65.19% to 71.18%. Both of them are metaluminous and belong to the high-K calc-alkaline series and are enriched in large-ion lithophile elements (LILEs) such as Rb, Th, U, and Pb. The Fenghuangling and Xishan plutons showed enrichment in light rare earth elements (LREEs) and high-field strength elements (Nb, Ta, Zr, and Hf) and depletion in heavy rare earth elements (HREEs). Marked Nb and Ta negative anomalies were not observed. Due to the high contents of Zr + Ce + Nb + Y and high Ga/Al ratios, all the samples belonged to the group of A-type granites. The Fenghuangling and Xishan plutons had low ISr (mainly in the range of 0.7046–0.7058) and high εNd(t) (−0.60 to 1.94) values, though obviously different from those of the Precambrian basement in South China. Furthermore, they lie between the ocean island basalt (OIB) of the asthenosphere and the arc basaltic rocks of the enriched lithospheric mantle. Therefore, we proposed that the basaltic parental magma of the Guiping complex originated from partial melting of the enriched lithospheric mantle, which was metasomatized by asthenosphere-related OIB-type basaltic magma. Mafic microgranular enclaves in the Xishan pluton displayed positive Nb and Ta anomalies, which is consistent with OIB-type basalts. The enclaves also had similar Sr-Nd isotopic compositions to the Xishan pluton. That indicated that the enclaves were probably formed by mixing of the OIB-type basaltic magma and the Xishan pluton. In conclusion, the formation of the Late Jurassic NE-trending A-type granite belt was attributed to back-arc extension as a result of the rollback of the Paleo-Pacific Plate.

scholarly journals Paleoproterozoic Adakitic Rocks in Qingchengzi District, Northeastern Jiao-Liao-Ji Belt: Implications for Petrogenesis and Tectonism

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 684
Author(s):  
Jian Li ◽  
Hanlun Liu ◽  
Keyong Wang ◽  
Wenyan Cai
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Tectonic Setting ◽  
Active Continental Margin ◽  
Biotite Granite ◽  
Granitic Rocks ◽  
Geochemical Data ◽  
Trace Element Geochemistry ◽  
Element Geochemistry ◽  
Magmatic Rocks

Herein, zircon U-Pb geochronology, Lu-Hf isotopes, and whole-rock major and trace element geochemistry are presented for two Palaeoproterozoic granitic rocks in Qingchengzi district, northeastern Jiao-Liao-Ji Belt (JLJB). These new geochronological and geochemical data provide reference clues for exploring the petrogenesis and tectonic setting of Paleoproterozoic magmatic rocks in the Qingchengzi district, which further constrain the tectonic nature of the JLJB. Our zircon U-Pb dating denotes that the Paleoproterozoic magmatic events in the Qingchengzi district were emplaced at ~2163 Ma and ~1854 Ma, represented by granite porphyry and biotite granite, respectively. Geochemically, these Palaeoproterozoic rocks are characterized by high Sr (760–842 ppm), SiO2 (69.72–70.89 wt.%), and Al2O3 (15.53–16.78 wt.%) contents, low Y (2.1–9.0 ppm) and Yb (0.25–0.80 ppm) contents, which indicate an adakite affinity. Combined with Hf isotopic composition (εHf(t) = −1.5~+4.8; TDM2 = 3109~2560 Ma), we believe that the Paleoproterozoic adakitic magma originated from partial melting of the thickened lower crust material in the Meso-Neoarchean. Moreover, these rocks are enriched in light rare earth elements and large ion lithophilic elements (e.g., K, Rb, and Cs), and depleted in heavy rare earth elements and high field strength elements (e.g., Nb and Ta). These features are similar to magmatic rocks formed in an arc environment (either island arc or active continental margin) and are not consistent with an intraplate/intracontinental environment. According to this study and previous research results, we conclude that the arc–continent collision model is conducive to the Paleoproterozoic tectonic attribute of the JLJB, and the oceanic crust subduction between the Namgrim and Longgang blocks may have induced the widespread occurrence of magmatic events in the region.

scholarly journals Petrochemical features of tholeiites from the Shaka ridge (South Atlantic)

2021 ◽  
Vol 248 ◽  
pp. 223-231
Author(s):  
Natalia Rumyantseva ◽  
Boris Vanshteyn ◽  
Sergey Skublov
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Classical Method ◽  
Field Research ◽  
Fluorescence Analysis ◽  
Original Data ◽  
South Atlantic ◽  
Trace Element Geochemistry ◽  
Element Geochemistry

The article presents original data of chemical composition of tholeiitic basaltoids and andesites, dredged from the Shaka Ridge (South Atlantic) in the course of field research in spring 2016 on the scientific expedition vessel “Akademik Fedorov”. The analytical part of the work on estimating the contents of petrogenic, trace and rare-earth elements was carried out using the classical method (“wet chemistry”), X-ray fluorescence analysis (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). The studied samples demonstrate elevated concentrations of large-ion lithophile elements, or LILE, (Ba, Rb, Pb) and light rare earth elements, or LREE, (La, Ce, Nd, Sm) relative to high field strength elements, or HFSE, (Nb, Ta) and heavy rare earth elements, or HREE, (Dy, Yb, Lu). The specifics of trace element geochemistry suggest a significant contribution of crustal or subduction components to the magmas of the Shaka Ridge. Discrimination diagrams of basaltoids and allied rocks with fields of different geodynamic settings indicate that they were formed in the setting of the mid-ocean ridge basalt (MORB). The reason behind the appearance of subduction and crustal marks in the rocks is possibly associated with assimilation of crustal matter by magmas or lies in their inheritance from the mantle source.

scholarly journals Intrinsically weak magnetic anisotropy of cerium in potential hard-magnetic intermetallics

2021 ◽  
Vol 6 (1) ◽  
Author(s):  
Anna Galler ◽  
Semih Ener ◽  
Fernando Maccari ◽  
Imants Dirba ◽  
Konstantin P. Skokov ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Magnetic Anisotropy ◽  
High Performance ◽  
Kondo Effect ◽  
Quantitative Description ◽  
Many Body ◽  
Heavy Rare Earth Elements ◽  
Fe Intermetallics ◽  
Full Temperature

AbstractCerium-based intermetallics are currently attracting much interest as a possible alternative to existing high-performance magnets containing scarce heavy rare-earth elements. However, the intrinsic magnetic properties of Ce in these systems are poorly understood due to the difficulty of a quantitative description of the Kondo effect, a many-body phenomenon where conduction electrons screen out the Ce-4f moment. Here, we show that the Ce-4f shell in Ce–Fe intermetallics is partially Kondo screened. The Kondo scale is dramatically enhanced by nitrogen interstitials suppressing the Ce-4f contribution to the magnetic anisotropy, in striking contrast to the effect of nitrogenation in isostructural intermetallics containing other rare-earth elements. We determine the full temperature dependence of the Ce-4f single-ion anisotropy and show that even unscreened Ce-4f moments contribute little to the room-temperature intrinsic magnetic hardness. Our study thus establishes fundamental constraints on the potential of cerium-based permanent magnet intermetallics.

Selective recovery of heavy rare earth elements from apatite with an adsorbent bearing immobilized tridentate amido ligands

2016 ◽  
Vol 159 ◽  
pp. 157-160 ◽  
Author(s):  
Takeshi Ogata ◽  
Hirokazu Narita ◽  
Mikiya Tanaka ◽  
Mihoko Hoshino ◽  
Yoshiaki Kon ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Heavy Rare Earth ◽  
Amido Ligands ◽  
Selective Recovery ◽  
Heavy Rare Earth Elements

Geochemical characteristics and geologic significance of rare earth elements in oil shale of the Yan’an Formation in the Tanshan area, in the Liupanshan Basin, China

2021 ◽  
pp. 1-41
Author(s):  
Lianfu Hai ◽  
Qinghai Xu ◽  
Caixia Mu ◽  
Rui Tao ◽  
Lei Wang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Oil Shale ◽  
Sedimentary Environment ◽  
Moderate Degree ◽  
Material Source ◽  
Icp Ms ◽  
Ree Distribution ◽  
Heavy Rare Earth Elements ◽  
Degree Of Differentiation

In the Tanshan area, which is at the Liupanshui Basin, abundant oil shale resources are associated with coals. We analyzed the cores, geochemistry of rare earth elements (REE) and trace element of oil shale with ICP-MS technology to define the palaeo-sedimentary environment, material source and geological significance of oil shale in this area. The results of the summed compositions of REE, and the total REE contents (SREE), in the Yan'an Formation oil shale are slightly higher than the global average of the composition of the upper continental crustal (UCC) and are lower than that of North American shales. The REE distribution pattern is characterized by right-inclined enrichment of light rare earth elements (LREE) and relative loss of heavy rare earth elements (HREE), which reflects the characteristics of crustal source deposition. There is a moderate degree of differentiation among LREE, while the differences among HREE are not obvious. The dEu values show a weak negative anomaly and the dCe values show no anomaly, which are generally consistent with the distribution of REE in the upper crust. The characteristics of REE and trace elements indicate that the oil shale formed in an oxygen-poor reducing environment and that the paleoclimatic conditions were relatively warm and humid. The degree of differentiation of REE indicates that the sedimentation rate in the study area was low, which reflected the characteristics of relatively deep sedimentary water bodies and distant source areas. The results also proved that the source rock mainly consisted of calcareous mudstone, and a small amount of granite was also mixed in.

scholarly journals Effect of acid mine drainage on dissolved rare earth elements geochemistry along a fluvial–estuarine system: the Tinto-Odiel Estuary (S.W. Spain)

2012 ◽  
Vol 43 (3) ◽  
pp. 262-274 ◽  
Author(s):  
J. Borrego ◽  
B. Carro ◽  
N. López-González ◽  
J. de la Rosa ◽  
J. A. Grande ◽  
...  
Keyword(s):  
Rare Earth ◽  
Acid Mine Drainage ◽  
Rare Earth Elements ◽  
Mine Drainage ◽  
Drainage System ◽  
Estuarine System ◽  
Mixing Zone ◽  
Heavy Rare Earth ◽  
Acid Mine ◽  
Heavy Rare Earth Elements

The concentration of rare earth elements together with Sc, Y, and U, as well as rare earth elements fractionation patterns, in the water of an affected acid mine drainage system were investigated. Significant dissolved concentrations of the studied elements were observed in the fluvial sector of this estuary system (Sc ∼ 31 μg L−1, Y ∼ 187 μg L−1, U ∼ 41 μg L−1, Σ rare earth elements ∼621 μg L−1), with pH values below 2.7. In the mixing zone of the estuary, concentrations are lower (Sc ∼ 2.1 μg L−1; Y ∼ 16.7 μg L−1; U ∼ 4.8 μg L−1; Σ rare earth elements ∼65.3 μg L−1) and show a strong longitudinal gradient. The largest rare earth elements removal occurs in the medium-chlorinity zone and it becomes extreme for heavy rare earth elements, as observed for Sc. Samples of the mixing zone show a North American Shale normalized pattern similar to the fluvial zone water, while the samples located in the zone with pH between 6.5 and 7.7 show a depletion of light rare earth elements relative to middle rare earth elements and heavy rare earth elements, similar to that observed in samples of the marine estuary.

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