scholarly journals Geochronology, Geochemistry, and Pb–Hf Isotopic Composition of Mineralization-Related Magmatic Rocks in the Erdaohezi Pb–Zn Polymetallic Deposit, Great Xing’an Range, Northeast China

Minerals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 274
Author(s):  
Zhitao Xu ◽  
Jinggui Sun ◽  
Xiaolong Liang ◽  
Zhikai Xu ◽  
Xiaolei Chu

Late Mesozoic intermediate–felsic volcanics and hypabyssal intrusions are common across the western slope of the Great Xing’an Range (GXAR). Spatiotemporally, these hypabyssal intrusions are closely associated with epithermal Pb–Zn polymetallic deposits. However, few studies have investigated the petrogenesis, contributions and constraints of these Pb–Zn polymetallic mineralization-related intrusions. Therefore, we examine the representative Erdaohezi deposit and show that these mineralization-related hypabyssal intrusions are composed of quartz porphyry and andesite porphyry with concordant zircon U–Pb ages of 160.3 ± 1.4 Ma and 133.9 ± 0.9 Ma, respectively. These intrusions are peraluminous and high-K calc-alkaline or shoshonitic with high Na2O + K2O contents, enrichment in large ion lithophile elements (LILEs; e.g., Rb, Th, and U), and depletion in high field strength elements (HFSEs; e.g., Nb, Ta, Zr, and Hf), similar to continental arc intrusions. The zircon εHf(t) values range from 3.1 to 8.0, and the 176Hf/177Hf values range from 0.282780 to 0.282886, with Hf-based Mesoproterozoic TDM2 ages. No differences exist in the Pb isotope ratios among the quartz porphyry, andesite porphyry and ore body sulfide minerals. Detailed elemental and isotopic data imply that the quartz porphyry originated from a mixture of lower crust and newly underplated basaltic crust, while the andesite porphyry formed from the partial melting of Mesoproterozoic lower crust with the minor input of mantle materials. Furthermore, a magmatic–hydrothermal origin is favored for the Pb–Zn polymetallic mineralization in the Erdaohezi deposit. Integrating new and published tectonic evolution data, we suggest that the polymetallic mineralization-related magmatism in the Erdaohezi deposit occurred in a back-arc extensional environment at ~133 Ma in response to the rollback of the Paleo-Pacific Plate.

Minerals ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 104 ◽  
Author(s):  
Fan Yang ◽  
Jinggui Sun ◽  
Yan Wang ◽  
Junyu Fu ◽  
Fuchao Na ◽  
...  

The recently discovered Weilasituo Sn-polymetallic deposit in the Great Xing’an Range is an ultralarge porphyry-type deposit. The mineralization is closely associated with an Early Cretaceous quartz porphyry. Analysis of quartz porphyry samples, including zircon U-Pb dating and Hf isotopies, geochemical and molybdenite Re-Os isotopic testing, reveals a zircon U-Pb age of 138.6 ± 1.1 Ma and a molybdenite Re-Os isotopic age of 135 ± 7 Ma, suggesting the concurrence of the petrogenetic and metallogenic processes. The quartz porphyry has high concentrations of SiO2 (71.57 wt %–78.60 wt %), Al2O3 (12.69 wt %–16.32 wt %), and K2O + Na2O (8.85 wt %–10.44 wt %) and A/CNK ratios from 0.94–1.21, is mainly peraluminous, high-K calc-alkaline I-type granite and is relatively rich in LILEs (large ion lithophile elements, e.g., Th, Rb, U and K) and HFSEs (high field strength elements, e.g., Hf and Zr) and relatively poor in Sr, Ba, P, Ti and Nb. The zircon εHf(t) values range from 1.90 to 6.90, indicating that the magma source materials were mainly derived from the juvenile lower crust and experienced mixing with mantle materials. Given the regional structural evolution history, we conclude that the ore-forming magma originated from lower crust that had thickened and delaminated is the result of the subduction of the Paleo–Pacific Ocean. Following delamination, the lower crustal material entered the underlying mantle, where it was partially melted and reacted with mantle during ascent. The deposit formed at a time of transition from post-orogenic compression to extension following the subduction of the Paleo–Pacific Ocean.


2021 ◽  
Author(s):  
Qianwen Huang ◽  
Yongjiang Liu ◽  
Johann Genser ◽  
Franz Neubauer ◽  
Sihua Yuan ◽  
...  

<p>The pre-Mesozoic basements in the Eastern Alps overprinted by the Variscan and alpine metamorphism (Neubauer and Frisch, 1993), which still remained the pre-Variscan tectonic evolution evidences. Many of these basements left away from their lithospheric roots due to large-scale tectonic activities (von Raumer et al., 2001), whereas their origin and tectonic history can be recorded by detailed geochemistry and geochronology. Here we present a study on the Schladming Complex, one part of Silvretta-Seckau nappe system in Austroalpine Unit, that located in the northern part of Alps to discuss their ages, origin, and tectonic relationship with the Proto-Tethys Ocean.</p><p>The Schladming Complex basement mainly comprises biotite-plagioclase gneiss, hornblende-gneiss, mica-schists, together with some amphibolites, orthogneisses, paragneisses, metagabbro and migmatites, which covered by sequence of metasedimentary (Slapansky and Frank, 1987). It underwent the medium- to high-grade metamorphism during the Variscan event and is overprinted by the greenschist facies metamorphism during the Alpine orogeny (Slapansky and Frank, 1987).</p><p>Granodioritic gneisses (539~538 Ma) and fine-grained amphibolite (531±2 Ma) in the basement represent a bimodal magmatism. Geochemical data show that the granodioritic gneisses belong to A<sub>2</sub>-type granite and originated from the lower crust, while the fine-grained amphibolites have an E-MORB affinity and the magma origined from the lithospheric mantle and contaminated by the arc-related materials. The data implies that the Schladming Complex formed in a back-arc rift tectonic setting in the Early Cambrian.</p><p>A medium-grained amphibolite gives an age of 495±5 Ma, exhibits ocean island basalt-like geochemical features and zircons positive εHf(t) values (+5.3~+10.9) indicating that the medium-grained amphibolite derived from a depleted mantle source. The monzonite granitic gneiss and plagioclase gneiss yields ages of 464±4 Ma for and 487±3 Ma, respectively. The monzonite granitic gneiss derived from the mixing of melts derived from pelitic and metaluminous rocks. The protolith of plagioclase gneiss is aplite, which has positive εHf(t) values of +5.9~+7.9, indicating it derived from the lower crust sources. The monzonite granitic gneiss and plagioclase gneiss exhibit S-type and I-type geochemical features, respectively. They are geochemically similar to the volcanic arc granite.</p><p>In summary, our data presents record of the Cambrian to Ordovician magmatism in the Schladming Complex, which provided new evidence of tectonic evolution history between Proto-Tethys and Gondwana. According to the data, we proposed that a series of rift developed in the northern margin of Gondwana during 540-530 Ma, the rifts continually expanded into a back-arc ocean in ~490 Ma and was closed around 460 Ma with S-type granitic magma intruded.</p><p><strong>References</strong></p><p>Neubauer, F., Frisch, W. 1993. The Austroalpine metamorphic basement east of the Tauern window.  In: Raumer, J. von & Neubauer, F. (eds.): Pre-Mesozoic Geology in the Alps. Berlin (Springer), pp. 515–536.</p><p>von Raumer, J., Stampfli, G., Borel, G., Bussy, F., 2001. Organization of pre-Variscan basement areas at the north-Gondwanan margin. International Journal of Earth Sciences 91, 35-52.</p><p>Slapansky, P., Frank, W. 1987. Structural evolution and geochronology of the northern margin of the Austroalpine in the northwestern Schladming crystalline (NE Tadstädter Tauern). In: Flügel, H. W. & Faupl, P. (eds.), Geodynamics of the Eastern Alps, pp. 244-262.</p>


Minerals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 106
Author(s):  
Xing-Yuan Li ◽  
Jing-Ru Zhang ◽  
Chun-Kit Lai

Jiangxi Province (South China) is one of the world’s top tungsten (W) mineral provinces. In this paper, we present a new LA-ICP-MS zircon U-Pb age and Hf isotope data on the W ore-related Xianglushan granite in northern Jiangxi Province. The magmatic zircon grains (with high Th/U values) yielded an early Cretaceous weighted mean U-Pb age of 125 ± 1 Ma (MSWD = 2.5, 2σ). Zircon εHf(t) values of the Xianglushan granite are higher (−6.9 to −4.1, avg. −5.4 ± 0.7) than those of the W ore-related Xihuanshan granite in southern Jiangxi Province (−14.9 to −11.2, avg. −12.5 ± 0.9), implying different sources between the W ore-forming magmas in the northern and southern Jiangxi Province. Compiling published zircon geochemical data, the oxygen fugacity (fO2) of the late Yanshanian granitic magmas in Jiangxi Province (the Xianglushan, Ehu, Dahutang, and Xihuashan plutons) were calculated by different interpolation methods. As opposed to the W ore-barren Ehu granitic magma, the low fO2 of the Xianglushan granitic magma may have caused W enrichment and mineralization, whilst high fO2 may have led to the coexistence of Cu and W mineralization in the Dahutang pluton. Additionally, our study suggests that the absence of late Mesozoic Cu-Mo mineralization in the Zhejiang, Jiangxi, and Anhui Provinces (Zhe-Gan-Wan region) was probably related to low fO2 magmatism in the Cretaceous.


2002 ◽  
Vol 39 (9) ◽  
pp. 1425-1440 ◽  
Author(s):  
Bernard Bingen ◽  
Joakim Mansfeld ◽  
Ellen MO Sigmond ◽  
Holly Stein

Recent models suggest that Laurentia and Baltica were contiguous during the Mesoproterozoic and shared a long-lived active continental margin, subsequently reworked during the Grenvillian orogeny. Around 1.25 Ga, the geological record is dominated by dyke-swarm intrusion, continental rift basin formation, A-type felsic magmatism, and arc – back-arc basin development. It points to a dominantly extensional tectonic regime over most of the craton and the Grenvillian margin, suggesting a retreating subduction boundary at that time. In the westernmost allochthonous domain of the Sveconorwegian Orogen, southern Norway, the Sæsvatn–Valldal supracrustal sequences are interpreted as rift or pull-apart basins. They formed at and after 1.27 Ga, in a continental setting, at the margin of Baltica. This interpretation is based on geological, geochemical, and new secondary ion mass spectrometry (SIMS) zircon U–Pb data. A subvolcanic quartz porphyry at the base of the Sæsvatn sequence yields a 1275 ± 8 Ma intrusion age. Metarhyolite samples in the lower part of the sequences yield equivalent extrusion ages of 1264 ± 4 Ma (Sæsvatn sequence) and 1260 ± 8 Ma (Valldal sequence). The metarhyolite units are overlain by sequences of metabasalt and metasandstone. An angular unconformity between the metarhyolites and overlying rocks is locally observed and possibly reflects rift tectonics during formation of the basin. A sample of arkosic metasandstone at the top of the exposed Sæsvatn sequence yields a few Archaean detrital zircon grains and a large spectrum of 2.2–1.2 Ga Proterozoic grains. These data point to a varied continental provenance and constrain sedimentation to later than 1211 ± 18 Ma.


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