scholarly journals The Recovery of Valuable Metals from Ocean Polymetallic Nodules Using Solid-State Metalized Reduction Technology

Minerals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 20 ◽  
Author(s):  
Feng Zhao ◽  
Xunxiong Jiang ◽  
Shengdong Wang ◽  
Linyong Feng ◽  
Da Li
Keyword(s):  
Solid State ◽  
Magnetic Separation ◽  
Ferrous Metal ◽  
Mineral Resources ◽  
Metal Extraction ◽  
Metallic State ◽  
Ferrous Metals ◽  
Polymetallic Nodules ◽  
Valuable Metals ◽  
Pre Treatment

Ocean polymetallic nodules are oxide ores rich in Ni, Co, Cu, and Mn, which are valuable metals found in deep-sea mineral resources. Such non-ferrous metals do not exist in isolation, and producing concentrates using conventional mineral separation techniques is challenging without pre-treatment. We propose an effective, environmentally-friendly recovery technology combined with solid-state metalized reduction treatment and magnetic separation to recycle these metals from ocean polymetallic nodules. We conducted single-factor tests to investigate the effects of additives, anthracite dosage, duration, and reduction temperature on metal recovery and to obtain optimal operating parameters. We found that valuable metals in ocean polymetallic nodules may be selectively reduced to a metallic state. Only a fraction of Mn was reduced to metal. The reduced metals were recovered to concentrates using magnetic separation. More than 80% of these metals were concentrated to magnetic concentrates with mass ratios of 10–15%. The recovery rates of Ni, Co, Cu, Mn, and Fe in concentrates were optimum at 86.48%, 86.74%, 83.91%, 5.63%, and 91.46%, respectively, when using CaF2 4%, anthracite 7%, SiO2 dosage 5%, and FeS 6% at 1100 °C for 2.5 h. This approach to non-ferrous metal extraction using conventional hydrometallurgical processes could be a step toward practical industrial-scale techniques for the recovery of metals from polymetallic nodules.

Marine Authigenic Deposits Mineral - New Fields for the Development of Rare Earth Resources

2011 ◽  
Vol 291-294 ◽  
pp. 1748-1751
Author(s):  
Ying Zhang ◽  
Chang Shui Liu ◽  
Lian Feng Gao ◽  
Zhen Guo Zhang ◽  
Peng Zhang
Keyword(s):  
Rare Earth ◽  
Rare Earth Metals ◽  
Mineral Resources ◽  
Resource Depletion ◽  
Polymetallic Nodules ◽  
Growth History ◽  
Valuable Metals ◽  
The World ◽  
Development And Utilization ◽  
Rare Earth Mineral

Rare earth metals are an important strategic resource. Due to scarce reserves, and large consumer demand, it is facing the crisis of resource depletion. Marine are the largest deposits sites in the world. In the long growth history, marine autogenic sedimentary mineral, such as polymetallic nodules, crusts with large quantities, not only contain the enrichment of Mn, Fe, Co, Cu, Ni and other valuable metals, but also contain extremely rare earth elements (REE) in the crust. Thus, in the process of developing marine mineral resources, Mn, Fe, Co, Cu, Ni and other metals are used, while it is possible for the development and utilization of the associated rare earth mineral. Marine may become a new field of rare earth resources development.

X-ray fluorescence sorting of non-ferrous metal fractions from municipal solid waste incineration bottom ash processing depending on particle surface properties

2019 ◽  
Vol 38 (2) ◽  
pp. 111-121 ◽  
Author(s):  
Kerstin Pfandl ◽  
Bastian Küppers ◽  
Stefanie Scheiber ◽  
Gerhard Stockinger ◽  
Johannes Holzer ◽  
...  
Keyword(s):  
Stainless Steel ◽  
Ferrous Metal ◽  
Precious Metals ◽  
Waste Incineration ◽  
Residual Fraction ◽  
Chemical Analyses ◽  
Municipal Solid Waste Incineration ◽  
X Ray ◽  
Ferrous Metals ◽  
Pre Treatment

A heavy non-ferrous metal fraction (< 50 mm) of municipal solid waste incineration bottom ashes from wet-mechanical treatment was separated by screening, magnetic separation and eddy-current separation into ferrous metals, non-ferrous metals and residual sub-fractions. The non-ferrous metal fractions were divided and subjected to (i) a washing process, (ii) dry abrasion and (iii) no mechanical pre-treatment to study the effect of resulting different surface properties on a subsequent X-ray fluorescence sorting into precious metals, zinc, copper, brass, stainless steel and a residual fraction. The qualities of the X-ray fluorescence output fractions were investigated by chemical analyses (precious metal fraction and the residual fraction), pyrometallurgical tests and subsequent chemical analyses of the metals and slags produced by the melting processes (zinc, copper, brass and stainless steel fraction). Screening directs brass and stainless steel primarily into the coarser fractions, while copper and residual elements were rather transferred into the finer fractions. X-ray fluorescence sorting yielded zinc, copper, brass, stainless steel and precious metals fractions in marketable qualities. Neither a negative nor a positive impact of mechanical pre-treatment on the composition of these fractions was identified. Solely the yield of the brass fraction in the grain size 16–20 mm decreased with increasing mechanical pre-treatment. The pre-treatment also had no impact on yield and quality of the products of pyrometallurgical tests.

A New Biohydrometallurgical Method for Processing of Deep-Sea Mineral Resources

2009 ◽  
Author(s):  
Yasuhiro Konishi ◽  
Norizoh Saitoh ◽  
Takashi Ogi
Keyword(s):  
Deep Sea ◽  
Mineral Resources ◽  
Environmentally Friendly ◽  
Sulfide Minerals ◽  
Experimental Results ◽  
Metal Extraction ◽  
Valuable Metals ◽  
Oxide Minerals ◽  
Hydrothermal Sulfides

This paper concentrates on the application of a biohydrometallurgical method for processing deep-sea mineral resources. Bioleaching technologies developed for terrestrial sulfide minerals now can be applied for metal extraction from deep-sea hydrothermal sulfides. However, little attention has been given to the bioleaching of terrestrial oxide minerals. A potentially attractive bioleaching system using the Fe(III)-reducing bacterium has recently been proposed for manganese crusts and nodules. Experimental results obtained from these systems demonstrate that bioleaching is an economical and environmentally friendly processing avenue to recover valuable metals from deep-sea mineral resources.

A Comprehensive Recovery of Copper-Iron Experimental Research in the Copper Smelting Slag

2014 ◽  
Vol 926-930 ◽  
pp. 4197-4200 ◽  
Author(s):  
Xing Ke Shang ◽  
Zhuo Yue Lan ◽  
Qi Fu Zhang ◽  
Ting Ting Li
Keyword(s):  
Magnetic Separation ◽  
Experimental Research ◽  
Mineral Resources ◽  
Closed Circuit ◽  
Copper Smelting ◽  
Copper Concentrate ◽  
Iron Concentrate ◽  
Valuable Metals ◽  
Smelting Slag ◽  
Comprehensive Recovery

With the depletion of mineral resources, more attention is paid on the secondary resources to recover valuable metals. In this paper, a research is carried out to recover copper and iron from copper smelting slag by flotation and magnetic separation. The influence of grinding fineness and collectors on flotation of copper are investigated. A copper concentrate is obtained by flotation and an iron concentrate is obtained by magnetic separation in the closed circuit flowsheet. The copper concentrate contains 18.86% Cu with a recovery of 72.36%, and the iron concentrate contains 52.24% Fe with a recovery of 70.87%.

Study of the Effect of Crude Oils on the Metallic Corrosion

2018 ◽  
Vol 5 (1) ◽  
pp. 43-54
Author(s):  
Suresh Aluvihara ◽  
Jagath K Premachandra
Keyword(s):  
Crude Oil ◽  
Sulfur Content ◽  
Salt Content ◽  
Ferrous Metal ◽  
Relative Weight ◽  
Oil Refining ◽  
Crude Oils ◽  
Hardness Tester ◽  
Corrosion Rates ◽  
Ferrous Metals

Corrosion is a severe matter regarding the most of metal using industries such as the crude oil refining. The formation of the oxides, sulfides or hydroxides on the surface of metal due to the chemical reaction between metals and surrounding is the corrosion that  highly depended on the corrosive properties of crude oil as well as the chemical composition of ferrous metals since it was expected to investigate the effect of Murban and Das blend crude oils on the rate of corrosion of seven different ferrous metals which are used in the crude oil refining industry and investigate the change in hardness of metals. The sulfur content, acidity and salt content of each crude oil were determined. A series of similar pieces of seven different types of ferrous metals were immersed in each crude oil separately and their rates of corrosion were determined by using their relative weight loss after 15, 30 and 45 days. The corroded metal surfaces were observed under the microscope. The hardness of each metal piece was tested before the immersion in crude oil and after the corrosion with the aid of Vicker’s hardness tester. The metallic concentrations of each crude oil sample were tested using atomic absorption spectroscopy (AAS). The Das blend crude oil contained higher sulfur content and acidity than Murban crude oil. Carbon steel metal pieces showed the highest corrosion rates whereas the stainless steel metal pieces showed the least corrosion rates in both crude oils since that found significant Fe and Cu concentrations from some of crude oil samples. The mild steel and the Monel showed relatively intermediate corrosion rates compared to the other types of ferrous metal pieces in both crude oils. There was a slight decrease in the initial hardness of all the ferrous metal pieces due to corrosion.

A breakthrough method for the recycling of spent lithium-ion batteries without pre-sorting

2021 ◽  
Author(s):  
Jialiang Zhang ◽  
Guoqiang Liang ◽  
Cheng Yang ◽  
Juntao Hu ◽  
Yongqiang Chen ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
Mineral Resources ◽  
Low Grade ◽  
Valuable Metals

Inspired by the process of "metallurgy first and then beneficiation" for disposing low-grade and complex mineral resources, we proposed a breakthrough method to recover valuable metals from spent entire lithium-ion...

scholarly journals Towards Iron-Titanium Oxide Nanostructures from Ecuadorian Black Mineral Sands

Minerals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 122
Author(s):  
Karina J. Lagos ◽  
Bojan A. Marinkovic ◽  
Alexis Debut ◽  
Karla Vizuete ◽  
Víctor H. Guerrero ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Titanium Oxide ◽  
Low Cost ◽  
Mineral Resources ◽  
Added Value ◽  
Secondary Phases ◽  
Hydrothermal Route ◽  
Oxide Nanostructures ◽  
Transmission Electron ◽  
Pre Treatment

Ecuadorian black mineral sands were used as starting material for the production of iron-titanium oxide nanostructures. For this purpose, two types of mineral processing were carried out, one incorporating a pre-treatment before conducting an alkaline hydrothermal synthesis (NaOH 10 M at 180 °C for 72 h), and the other prescinding this first step. Nanosheet-assembled flowers and nanoparticle agglomerates were obtained from the procedure including the pre-treatment. Conversely, nanobelts and plate-like particles were prepared by the single hydrothermal route. The nanoscale features of the product morphologies were observed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) analyses. The ilmenite and hematite molar fractions, within the ilmenite-hematite solid solution, in the as-synthetized samples were estimated by Brown’s approach using the computed values of unit-cell volumes from Le Bail adjustments of X-ray powder diffraction (XRPD) patterns. The resulting materials were mainly composed of Fe-rich ilmenite-hematite solid solutions (hematite molar contents ≥0.6). Secondary phases, which possibly belong to lepidocrocite-like or corrugated titanate structures, were also identified. The current study demonstrated the feasibility of employing Ecuadorian mineral resources as low-cost precursors to synthesize high-added-value nanostructures with promising applications in several fields.

scholarly journals Application of a cashew-based oxime in extracting Ni, Mn and Co from aqueous solution

2021 ◽  
Vol 8 (1) ◽  
Author(s):  
Chi M. Phan ◽  
Son A. Hoang ◽  
Son H. Vu ◽  
Hoang M. Nguyen ◽  
Cuong V. Nguyen ◽  
...  
Keyword(s):  
Organic Phase ◽  
Extraction Efficiency ◽  
Acidic Solution ◽  
Lithium Ion ◽  
Metal Extraction ◽  
Economic Potential ◽  
Cashew Nut ◽  
Valuable Metals ◽  
Loaded Organic Phase ◽  
Cashew Nut Shell

Abstract Background Cashew nut shell is a by-product of cashew (Anacardium occidentale) production, which is abundant in many developing countries. Cashew nut shell liquor (CNSL) contains a functional chemical, cardanol, which can be converted into a hydroxyoxime. The hydroxyoximes are expensive reagents for metal extraction. Methods CNSL-based oxime was synthesized and used to extract Ni, Co, and Mn from aqueous solutions. The extraction potential was compared against a commercial extractant (LIX 860N). Results All metals were successfully extracted with pH0.5 between 4 and 6. The loaded organic phase was subsequently stripped with an acidic solution. The extraction efficiency and pH0.5 of the CNSL-based extractant were similar to a commercial phenol-oxime extractant. The metals were stripped from the loaded organic phase with a recovery rate of 95% at a pH of 1. Conclusions Cashew-based cardanol can be used to economically produce an oxime in a simple process. The naturally-based oxime has the economic potential to sustainably recover valuable metals from spent lithium-ion batteries. Graphic abstract

scholarly journals Food Waste-Assisted Metal Extraction from Printed Circuit Boards: The Aspergillus niger Route

2021 ◽  
Vol 9 (5) ◽  
pp. 895
Author(s):  
Carlotta Alias ◽  
Daniela Bulgari ◽  
Fabjola Bilo ◽  
Laura Borgese ◽  
Alessandra Gianoncelli ◽  
...  
Keyword(s):  
Solid State ◽  
Aspergillus Niger ◽  
Food Waste ◽  
Solid State Fermentation ◽  
Printed Circuit Boards ◽  
Electronic Waste ◽  
Metal Extraction ◽  
Circuit Boards ◽  
Printed Circuit ◽  
Waste Printed Circuit Boards

A low-energy paradigm was adopted for sustainable, affordable, and effective urban waste valorization. Here a new, eco-designed, solid-state fermentation process is presented to obtain some useful bio-products by recycling of different wastes. Urban food waste and scraps from trimmings were used as a substrate for the production of citric acid (CA) by solid state fermentation of Aspergillus niger NRRL 334, with a yield of 20.50 mg of CA per gram of substrate. The acid solution was used to extract metals from waste printed circuit boards (WPCBs), one of the most common electronic waste. The leaching activity of the biological solution is comparable to a commercial CA one. Sn and Fe were the most leached metals (404.09 and 67.99 mg/L, respectively), followed by Ni and Zn (4.55 and 1.92 mg/L) without any pre-treatments as usually performed. Commercial CA extracted Fe more efficiently than the organic one (123.46 vs. 67.99 mg/L); vice versa, biological organic CA recovered Ni better than commercial CA (4.55 vs. 1.54 mg/L). This is the first approach that allows the extraction of metals from WPCBs through CA produced by A. niger directly grown on waste material without any sugar supplement. This “green” process could be an alternative for the recovery of valuable metals such as Fe, Pb, and Ni from electronic waste.

Pilot-scale plant study on solid-state metalized reduction–magnetic separation for magnesium-rich nickel oxide ores

2017 ◽  
Vol 169 ◽  
pp. 99-105 ◽  
Author(s):  
Baozhong Ma ◽  
Weijiao Yang ◽  
Peng Xing ◽  
Chengyan Wang ◽  
Yongqiang Chen ◽  
...  
Keyword(s):  
Solid State ◽  
Nickel Oxide ◽  
Magnetic Separation ◽  
Pilot Scale
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