scholarly journals A Trace C2H2 Sensor Based on an Absorption Spectrum Technique Using a Mid-Infrared Interband Cascade Laser

Micromachines ◽  
2018 ◽  
Vol 9 (10) ◽  
pp. 530 ◽  
Author(s):  
Ye Mu ◽  
Tianli Hu ◽  
He Gong ◽  
Ruiwen Ni ◽  
Shijun Li

In this study, tunable diode laser absorption spectroscopy (TDLAS) combined with wavelength modulation spectroscopy (WMS) was used to develop a trace C2H2 sensor based on the principle of gas absorption spectroscopy. The core of this sensor is an interband cascade laser that releases wavelength locks to the best absorption line of C2H2 at 3305 cm−1 (3026 nm) using a driving current and a working temperature control. As the detected result was influenced by 1/f noise caused by the laser or external environmental factors, the TDLAS-WMS technology was used to suppress the 1/f noise effectively, to obtain a better minimum detection limit (MDL) performance. The experimental results using C2H2 gas with five different concentrations show a good linear relationship between the peak value of the second harmonic signal and the gas concentration, with a linearity of 0.9987 and detection accuracy of 0.4%. In total, 1 ppmv of C2H2 gas sample was used for a 2 h observation experiment. The data show that the MDL is low as 1 ppbv at an integration time of 63 s. In addition, the sensor can be realized by changing the wavelength of the laser to detect a variety of gases, which shows the flexibility and practicability of the proposed sensor.

2021 ◽  
Vol 16 (2) ◽  
pp. 222-229
Author(s):  
Lin Feng ◽  
Jian Wang ◽  
Chao Ding

Tunable diode laser absorption spectroscopy (TDLAS) technology is adopted herein to detect fire gas produced in the early stage of the fire. Based on this technology, a fire warning detection system with multiple lasers and detectors is proposed. Multiple drivers input laser’s temperature and injected current data, making its output wavelength consistent with the measured gas’ absorption peak wavelengths in absorption spectroscopy. Multiple light beams are coupled to the same optical fiber. After the light beams pass through the long optical path absorption cell filled with fire gas, the beams are separated by a converter. The signals are demodulated by different detectors and further analyzed for fire warnings. After the fire warning system’s design, the system’s various hardware modules are designed, including the light source module, TDLAS controller, gas chamber module, photoelectric detector, and data collection. When the temperature remains unchanged, the output wavelength is linearly related to the injected current. When the injected current remains unchanged, the output wavelength is linearly related to the operating temperature. With a semiconductor laser’s injected current of 40 mA, the initial temperature of 38.6 °C, and the output wavelength of 1578.16 nm, the output wavelength increases continuously as the temperature increases. The harmonic signal amplitude after gas absorption is positively correlated with the measured gas concentration, indicating that the second harmonic signals can estimate the fire gas concentration.


2014 ◽  
Vol 986-987 ◽  
pp. 1523-1526
Author(s):  
Hui Jie Zheng ◽  
Wei Quan

An experimental technique was designed to measure the gas number density distribution of alkali vapor by tunable diode laser absorption spectroscopy. The measurement method was developed by scanning multiple gas absorption lines and fitting the experiment data with Lorentz profile to obtain the density. A discretization strategy of the equation for absorption lines is also present here as well as a constrained liner least-square fitting method. A simulation model was set up to reconstruct the two-dimensional distribution of number density and the feasibility of the reconstruction was verified. In the end, this work demonstrates the calculation error of the acquired number density and the distribution. The results indicated that the error would be no more than 5% if the measurement error is less than 9%.


Author(s):  
Avishek Guha ◽  
Ingmar Schoegl

Temperature and concentration distributions of a simulated flame were reconstructed with the help of computer tomography and tunable diode laser absorption spectroscopy (TDLAS). Reconstructions were based on the simulated numerical values of temperature and concentration of a stationary flame. Integrated absorption measurements along the line-of-sight (LOS) across the flames due to absorption by water vapor (H2O) in the near infra-red (NIR) region, specifically the 6930–6940 cm−1 range, were simulated to obtain the projection values for tomography. Spectroscopic parameters for the absorptions transitions, such as line-strengths, transition wavenumbers, collisional broadening coefficients and coefficients for their temperature dependency were selected from the HITRAN 2004 database. Simulated LOS data are inverted using a multiplicative algebraic reconstruction technique (MART), which are known to outperform traditional filtered back projection methods for cases with limited numbers of views. Based on spatially resolved reconstructions of spectroscopic data, temperature and concentration distributions are calculated using the wavelength modulation spectroscopy with second harmonic detection (WMS-2f) technique. A parametric study based on the number of views, orientation of views and number of rays per view required by the ART is performed in order to assess requirements for an acceptable reconstruction.


Sensors ◽  
2018 ◽  
Vol 18 (10) ◽  
pp. 3216 ◽  
Author(s):  
Shuanke Wang ◽  
Zhenhui Du ◽  
Liming Yuan ◽  
Yiwen Ma ◽  
Xiaoyu Wang ◽  
...  

This paper presents a mid-infrared dimethyl sulfide (CH3SCH3, DMS) sensor based on tunable laser absorption spectroscopy with a distributed feedback interband cascade laser to measure DMS in the atmosphere. Different from previous work, in which only DMS was tested and under pure nitrogen conditions, we measured DMS mixed by common air to establish the actual atmospheric measurement environment. Moreover, we used tunable laser absorption spectroscopy with spectral fitting to enable multi-species (i.e., DMS, CH4, and H2O) measurement simultaneously. Meanwhile, we used empirical mode decomposition and greatly reduced the interference of optical fringes and noise. The sensor performances were evaluated with atmospheric mixture in laboratory conditions. The sensor’s measurement uncertainties of DMS, CH4, and H2O were as low as 80 ppb, 20 ppb, and 0.01% with an integration time 1 s, respectively. The sensor possessed a very low detection limit of 9.6 ppb with an integration time of 164 s for DMS, corresponding to an absorbance of 7.4 × 10−6, which showed a good anti-interference ability and stable performance after optical interference removal. We demonstrated that the sensor can be used for DMS measurement, as well as multi-species atmospheric measurements of DMS, H2O, and CH4 simultaneously.


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